The atmospheric boundary layer structure over the open and ice-covered Baltic Sea: in situ measurements compared to simulations with the regional model REMO

The regional model REMO, which is the atmospheric component of the coupled atmosphere–ice–ocean–land climate model system BALTIMOS, is tested with respect to its ability to simulate the atmospheric boundary layer over the open and ice-covered Baltic Sea. REMO simulations are compared to ship, radiosonde, and aircraft observations taken during eight field experiments. The main results of the comparisons are: (1) The sharpness and strength of the temperature inversion are underestimated by REMO. Over open water, this is connected with an overestimation of cloud coverage and moisture content above the inversion. (2) The vertical temperature stratification in the lowest 200 m over sea ice is too stable. (3) The horizontal inhomogeneity of sea ice concentration as observed by aircraft could not be properly represented by the prescribed ice concentration in REMO; large differences in the surface heat fluxes arise especially under cold-air advection conditions. The results of the comparisons suggest a reconsideration of the parameterization of subgrid-scale vertical exchange both under unstable und stable conditions.     

Optimal planning and operation of irrigation systems under water resource constraints in Oman considering climatic uncertainty

In this contribution, we introduce a stochastic framework for decision support for optimal planning and operation of water supply in irrigation. This consists of (1) a weather generator for simulating regional impacts of climate change on the basis of IPCC scenarios, (2) a tailor-made evolutionary optimization algorithm for optimal irrigation scheduling with limited water supply, (3) a mechanistic model for simulating water transport and crop growth in a sound manner, and (4) a kernel density estimator for estimating stochastic productivity, profit, and demand functions by a nonparametric method. As a result of several simulation/optimization runs within the framework, we present stochastic crop-water production functions (SCWPF) for different crops which can be used as a basic tool for assessing the impact of climate variability on the risk for the potential yield for specific crops and specific agricultural areas. A case study for an agricultural area in the Al Batinah region of the Sultanate of Oman is used to illustrate these methodologies. In addition, microeconomic impacts of climate change and the vulnerability of the agro-ecological system are discussed.     

Petrographic and geochemical evidence for hydrothermal evolution of the North Deposit,Mt Tom Price,Western Australia

High-grade iron mineralisation (>65%Fe) in the North Deposit occurs as an E-W trending synclinal sheet within banded iron formation (BIF) of the Early Proterozoic Dales Gorge Member and consists of martite-microplaty hematite ore. Three hypogene alteration zones between unmineralised BIF and high-grade iron ore are observed: (1) distal magnetite-siderite-iron silicate, (2) intermediate hematite-ankerite-magnetite, and (3) proximal martite-microplaty hematite-apatite alteration zones. Fluid inclusions trapped in ankerite within ankerite-hematite veins in the hematite-ankerite-magnetite alteration zone revealed mostly H₂O–CaCl₂ pseudosecondary and secondary inclusions with salinities of 23.9±1.5 (1, n=38) and 24.4±1.5 (1, n=66) eq.wt.% CaCl₂, respectively. Pseudosecondary inclusions homogenised at 253±59.9°C (1, n=34) and secondary inclusions at 117±10.0°C (1, n=66). The decrepitation of pseudosecondary inclusions above 350°C suggests that their trapping temperatures are likely to be higher (i.e. 400°C). Hypogene siderite and ankerite from magnetite-siderite-iron silicate and hematite-ankerite-magnetite alteration zones have similar oxygen isotope compositions, but increasingly enriched carbon isotopes from magnetite-siderite-iron silicate alteration (–8.8±0.7, 1, n=17) to hematite-ankerite-magnetite alteration zones (–4.9±2.2, 1, n=17) when compared to the dolomite in the Wittenoom Formation (0.9±0.7, 1, n=15) that underlies the deposit. A two-stage hydrothermal-supergene model is proposed for the formation of the North Deposit. Early 1a hypogene alteration involved the upward movement of hydrothermal, CaCl₂-rich brines (150–250°C), likely from the carbonate-rich Wittenoom Formation (¹³C signature of 0.9±0.7, 1, n=15), within large-scale folds of the Dales Gorge Member. Fluid rock reactions transformed unmineralised BIF to magnetite siderite-iron silicate BIF, with subsequent desilicification of the chert bands. Stage 1b hypogene alteration is characterised by an increase in temperature (possibly to 400°C), depleted ¹³C signature of –4.9±2.2 (1, n=17), and the formation of hematite-ankerite-magnetite alteration and finally the crystallisation of microplaty hematite. Late Stage 1c hypogene alteration involved the interaction of low temperature (~120°C) basinal brines with the hematite-ankerite-magnetite hydrothermal assemblage leaving a porous martite-microplaty hematite-apatite mineral assemblage. Stage 2 supergene enrichment in the Tertiary resulted in the removal of residual ankerite and apatite and the weathering of the shale bands to clay.Editorial handling: B. Lehmann     

Conversion of carbonaceous material to graphite within the Greywacke Zone of the Eastern Alps

Morphology and reflectance of carbonaceous material (CM) in Late Carboniferous metasediments of the eastern Greywacke Zone (Eastern Alps) indicate a mixture of vitrinite, grainy textured and lamellar shaped particles. As imaged by high-resolution atomic-force microscopy, vitrinite and the grainy textured particles show mesophase structures which can be described as facetted nanocrystals within the carbon matrix. High-resolution transmission electron microscopy has revealed two types of microtextures representing different degrees of graphitization. The first type is characterized by elongated ring-shaped microtextures, whereas the second type is characterized by graphite lamellae and polygonal flakes with long-range ordered aromatic layers. In spite of the heterogeneity of the CMs, the geographical distribution of quantitative metamorphic parameter (Raman spectra parameter, X-ray diffraction pattern, microscopic reflectance) suggests a graphitization process which is promoted by advective heat transport during post-collisional processes. In a tentative pressure-time path, Late Cretaceous thrusting results in a turbostratic ordering of the aromatic layer. Ordering to long-range ordered aromatic layers was achieved during the Late Cretaceous-Paleogene exhumation of mid-crustal rocks beneath the eastern Greywacke Zone.     

River channel response to short-term human-induced change in landscape connectivity in Andean ecosystems

The drainage basin of the Deleg River (88 km²), located in the southern Ecuadorian Andes, was studied to assess the geomorphic and hydrologic response of a fluvial system to human-induced environmental change in its contributing area. Historical data on land use, channel morphology and sedimentology were collected, based on a spatial analysis of aerial photographs (1963–1995) and a field survey (2002). Analysis of channel cross-sectional profiles and sedimentological data revealed a major change in morphology and sedimentology of the Deleg River during the past four decades: (i) the active river channel narrowed by over 45%, (ii) the riverbed incised on average by over 1.0 m and (iii) the median grain size of the bed surface decreased from 13.2 cm to 4.7 cm. The spatial pattern of land cover within the Deleg catchment also changed considerably: highly degraded agricultural land in the low-lying areas was abandoned and partially afforested for timber and wood production, whereas secondary upland forest was increasingly cleared for expansion of cropland and pastures. Notwithstanding large changes in the spatial organization of land use within the catchment, the overall land use did not change significantly during the past four decades. This suggests that the response of the Deleg River to land-use change not only depends on the overall land-use change, but also on the spatial pattern of land-use/cover change within the catchment. Although forestation and regeneration of bare gully slopes and floors throughout the catchment only represented a minor part of the total land-use change, these land-use/cover changes had a major impact on the hydrological and sediment connectivity in the landscape.     

Water-budget of Upper Lake Constance: An estimation of total supply based on runoff and water level variations

An inflow-outflow model of the Upper Lake Constance has been adapted to fit the discharge data from the outletSeerhein at Constance. In order to perform mass balances the supplies and runoffs of the lake were calculated from 1961 at 1991.Three decades worth of results show no trend in annual supply patterns, aside from annual and seasonal fluctuations. When compared to earlier results, one finds slightly greater annual runoffs into the Seerhein of approximately 5%.     

An estimate of water mass transformation in the southern Weddell Sea

Bottom water formation changes the characteristics of water masses entering the southern part of the Weddell Sea through atmosphere-ice-ocean interaction in which both sea and shelf ice play an important role. Modified water, in particular Weddell Sea Bottom Water, recirculates in the west. By comparing the in- and outflowing water masses we have estimated transformation rates on the basis of a data set obtained during the Winter Weddell Gyre Study from September to October 1989. This consisted of a salinity-temperature-depth (CTD) section carried out by R/V “Polarstern” from the northern tip of the Antarctic Peninsula to Kapp Norvegia and data from three current meter moorings maintained from 1989 to 1990 in the eastern boundary current off Kapp Norvegia. Because of the lack of sufficient direct current measurements in the interior and the western boundary current, it was necessary to derive mass transports on the basis of available data combined with physical and geometrical arguments. At the mooring site barotropic currents were measured. They were extrapolated to the interior under the assumption that wind-driven, baroclinic and barotropic current fields are of similar shape. The location of the gyre centre was determined from drifting buoy tracks and geopoten-tial anomaly. A linear current profile from the eastern boundary current to the centre of the gyre was assumed, and the western outflow was determined according to mass conservation. Different assumptions on the transition from the boundary current to the interior and the location of the centre result in a wide range of transports with most likely values between 20 and 56 Sv. The total mass transport was split into individual water masses. Differences between inflow and outflow result in a transformation rate of 3–4 Sv from Winter and Warm Deep Water to Antarctic and Weddell Sea Bottom Water. The net heat and salt transport across the transect implies heat fluxes from the ocean to the atmosphere of 3–10 W m⁻² and ice formation rates of 0.2–0.35 m year⁻¹.     

Chlorophyll in Copepod Faecal Pellets: Changes in Pellet Numbers and Pigment Content during a Declining Baltic Spring Bloom

Abstract. Zooplankton stock as well as faecal pellet numbers were monitored over 2 weeks during May in the central Baltic. Considerable changes in concentrations of chlorophyll and its derivates in copepod faecal pellets as well as in surface sediments were found during this period. The maximum concentration of 1.05 ngchl. a faecal pellet^-1, measured on 12 May, decreased by the end of the month to 0.08 ngchl. a faecal pellet^-1. This decrease was positively correlated with the disappearance of intact diatoms inside faeces. A flux of 1.53mgchl. a -m^-2-day^-1 via faecal pellets was calculated for the deep water layer (60–80 m) in mid May. This decreased to 0.005mgchl. a m^-2 day^-1 by the end of May. Chi. a accounted for up to 10 % of total pigments in samples from the top centimetre of the sediment surface. The means of transportation of faecal pellets as well as their function as a food supply to deeper ecosystems are discussed.