Leaf wax n-alkane δD values of field-grown barley reflect leaf water δD values at the time of leaf formation

Leaf wax n-alkanes from barley (Hordeum vulgare) from a field in Switzerland exhibited changes in δD values on the order of 20‰ over a growing season, while source water (soil water) and leaf water varied by 40‰. Additionally the seasonal variability in δD values of leaf wax n-alkanes of different barley leaves can only be found across different leaf generations (i.e. leaves that were produced at different times during the growing season) while n-alkane δD values did not vary significantly within a leaf generation. Interestingly, δD values of n-alkanes correlated best with the δD values of leaf water at midday of the sampling day but showed no significant correlation with soil water (e.g. precipitation) δD values. These results provide empirical evidence that leaf wax δD values record leaf water enrichment, and therefore integrate the isotopic effects of precipitation and evapotranspiration. Our results show that leaf wax n-alkane δD values from grasses are ‘locked in’ early during leaf development and hence record the environmental drivers of leaf water enrichment, such as vapor pressure deficit (VPD). Our data have important implications for the interpretation of paleorecords of leaf wax δD. We suggest that leaf wax n-alkane δD values from sedimentary records could be used to estimate changes in the degree of leaf water enrichment and hence VPD.     

Impact of Climate Change on the Regional Hydrology – Scenario-Based Modelling Studies in the German Rhine Catchment

The aim of the study is an impact analysis of global climate change on regional hydrology with special emphasis on discharge conditions and floods. The investigations are focussed on the major part of the German Rhine catchment with a drainage area of approx. 110,000 km². This area is subdivided into 23 subcatchments. In a first step, the hydrological model HBV-D serves to simulate runoff conditions under present climate for the individual subbasins. Simulated, large scale atmospheric fields, provided by two different Global Circulation Models (GCMs) and driven by the emission scenario IS95a (“business as usual”) are then used as input to the method of expanded downscaling (EDS). EDS delivers local time series of scenario climate as input to HBV-D. In a final step, the investigations are focussed on the assessment of possible future runoff conditions under the impact of climate change. The study indicates a potential increase in precipitation, mean runoff and flood discharge for small return intervals. However, the uncertainty range that originates from the application of the whole model chain and two different GCMs is high. This leads to high cumulative uncertainties, which do not allow conclusions to be drawn on the development of future extreme floods.     

European climate of the past 500 years: new challenges for historical climatology

Temperature reconstructions from Europe for the past 500 years based on documentary and instrumental data are analysed. First, the basic documentary data sources, including information about climate and weather-related extremes, are described. Then, the standard palaeoclimatological reconstruction method adopted here is discussed with a particular application to temperature reconstructions from documentary-based proxy data. The focus is on two new reconstructions; January–April mean temperatures for Stockholm (1502–2008), based on a combination of data for the sailing season in the Stockholm harbour and instrumental temperature measurements, and monthly Central European temperature (CEuT) series (1500–2007) based on documentary-derived temperature indices of the Czech Republic, Germany and Switzerland combined with instrumental records from the same countries. The two series, both of which are individually discussed in greater detail in subsequent papers in this special edition, are here compared and analysed using running correlations and wavelet analysis. While the Stockholm series shows a pronounced low-frequency component, the CEuT series indicates much weaker low-frequency variations. Both series are analysed with respect to three different long-period reconstructions of the North Atlantic Oscillation (NAO) and are compared with other European temperature reconstructions based on tree-rings, wine-harvest data and various climate multiproxies. Correlation coefficients between individual proxy-based series show weaker correlations compared to the instrumental data. There are also indications of temporally varying temperature cross-correlations between different areas of Europe. The two temperature reconstructions have also been compared to geographically corresponding temperature output from simulations with global and regional climate models for the past few centuries. The findings are twofold: on the one hand, the analysis reinforces the hypothesis that the index-data based CEuT reconstruction may not appropriately reflect the centennial scale variations. On the other hand, it is possible that climate models may underestimate regional decadal variability. By way of a conclusion, the results are discussed from a broader point of view and attention is drawn to some new challenges for future investigations in the historical climatology in Europe.     

Winter storms in Switzerland North of the Alps 1864/1865–1993/1994

Summary In the framework of the Swiss National Research Program 31 Climate changes and natural disasters the question was brought up whether a global warming of the atmosphere would have an influence on the frequency and/or intensity of the extratropical storms of the Swiss winter season. In order to investigate a possible trend, time series of days with a minimum wind speed estimate or measurement equivalent to Beaufort 7, 8 and 9 were established. The longest being a record of the mesonet station Zürich from the period 1864 until 1993 (130 years). Slightly shorter time series for three additional stations in Northern Switzerland were compiled to control the behavior of the longest record and to verify the observed temporal trend. From the location of the four investigated wind records the observational domain was restricted to the part of Switzerland north of the Alps whereas for further meteorological considerations the whole North-Atlantic-European area was included.A negative regional trend in the number of storm days has been observed during the last century. In particular, the period before 1940 has to be interpreted as windier than the following decades. The duration of a storm event also decreased on average. In spite of an increase in cyclonic westwind situations since about 1960 over Europe, Switzerland was hit by fewer storms during the same period. One explanation could be that the whole westwind belt has moved slightly further north where a deepening of the cyclones was observed in recent times. Switzerland is usually situated at the southernmost edge of the particular storm fields and is therefore less influenced by strong gales. Rare exceptions are the cases when a secondary depression directly hits Central Europe, e.g. as happened in February 1990 (storm Vivian).With 11 Figures     

New high‐resolution age data from the Ediacaran–Cambrian boundary indicate rapid,ecologically driven onset of the Cambrian explosion

The replacement of the late Precambrian Ediacaran biota by morphologically disparate animals at the beginning of the Phanerozoic was a key event in the history of life on Earth, the mechanisms and the time‐scales of which are not entirely understood. A composite section in Namibia providing biostratigraphic and chemostratigraphic data bracketed by radiometric dating constrains the Ediacaran–Cambrian boundary to 538.6–538.8 Ma, more than 2 Ma younger than previously assumed. The U–Pb‐CA‐ID TIMS zircon ages demonstrate an ultrashort time frame for the LAD of the Ediacaran biota to the FAD of a complex, burrowing Phanerozoic biota represented by trace fossils to a 410 ka time window of 538.99 ± 0.21 Ma to 538.58 ± 0.19 Ma. The extremely short duration of the faunal transition from Ediacaran to Cambrian biota within less than 410 ka supports models of ecological cascades that followed the evolutionary breakthrough of increased mobility at the beginning of the Phanerozoic.     

Reconstruction of palaeohydrological conditions in a lagoon during the 2nd Zechstein cycle through simultaneous use of δD values of individual n-alkanes and δ<Superscript>18</Superscript>O and δ<Superscript>13</Superscript>C values of carbonates

For the first time ¹⁸O and ¹³C values from carbonates and D values of individual n-alkanes were used to reconstruct palaeohydrological conditions in a lagoon at the southern margin of the Central European Zechstein Basin (CEZB). A 12-m core covering the complete Ca2 interval and adjacent anhydrites (A1 and A2) was analyzed for ¹⁸O and ¹³C values of dolomitized carbonates and D values of individual n-alkanes. ¹⁸O_carb values (+2 to +5 vs. VPDB) were strongly influenced by evaporation and temporal freshwater input into the lagoon. The ¹³C_carb values (–1 to +4 vs. VPDB) were controlled mainly by changes in primary production. Both isotopic ratios show an inverse relationship throughout most of the core, contradicting diagenetic alteration, since ¹³C_carb values are not altered significantly during dolomitization. Assuming a temperature range of 35–40 °C in the lagoon, ¹⁸O_carb values of +2.5 to +8 (vs. VSMOW) for the lagoonal water can be reconstructed. The lagoon may have desiccated twice during the Ca2 interval, as indicated by very high ¹⁸O_carb and low ¹³C_carb values, coinciding with increasing amount of anhydrite in the analyzed sample. These events seem to reflect not just local but a regional intra-Ca2 cyclicity. Measured D values of the short-chain n-alkanes, namely n-C₁₆ and n-C₁₈ which are widely used as indicators for photosynthetic bacterial and algal input, reflect the isotopic composition of the lagoonal water. Assuming constant fractionation during incorporation of hydrogen into lipids of –160, an average D value of +70 (vs. VSMOW) can be reconstructed for the lagoonal water, accounting for very arid conditions. The long-chain n-alkanes n-C₂₇, n-C₂₈, n-C₂₉ and n-C₃₀, thought to be derived from the leaf waxes of terrestrial higher plants, were shown to be depleted in D relative to the short-chain alkanes, therefore indicating a different hydrogen source. Terrestrial plants in arid areas mainly use water supplied by precipitation. By using a smaller fractionation of –120 due to evaporation processes in the leaves, reconstructed values vary between –74 and –9 (vs. VSMOW). These values are not indicating extremely arid conditions, implying that the long-chain n-alkanes were transported trough wind and/or rivers into the lagoon at the Zechstein Sea coast. D_water values, reconstructed using the n-C₁₆ alkane and ¹⁸O _water values, independently reconstructed on the same sample using the temperature dependant fractionation for dolomites are good agreement and suggest high amounts of evaporation affecting the coastal lagoon. Altogether, our results indicate that hydrogen isotopic ratios of n-alkanes give information on their origin and are a useful proxy for palaeoclimatic reconstruction.     

Tracer tests and the structure of permeability in the Corallian limestone aquifer of northern England, UK

The Corallian limestone of northern England (UK) is widely exploited for water supplies and exhibits the karstic phenomena of sinking rivers, conduit development and groundwater velocities of several kilometres per day. To test a number of model-derived source protection zones and elucidate contaminant transport mechanisms in the aquifer, three tracer tests were conducted from a set of swallow-holes draining the River Derwent toward public water supply wells in the eastern part of the aquifer. Tracers used included: Enterobacter cloacae (bacteriophage), Photine C (optical brightener), sodium fluorescein (fluorescent dye) and sulphur hexafluoride (dissolved gas), the varying properties of which make them suitable analogues for different types of potential contaminant. Observed tracer transport times and arrival patterns indicate that tracer transport occurs through karstic channels embedded in a network of primary fissures which exert control over tracer concentrations once initial tracer plumes have passed. A dipole flow system is observed between the swallow-holes and the closest abstraction well, whilst previously modelled source protection zones do not accurately reflect either groundwater velocity or those areas of the aquifer supplying the wells. These findings imply that managing such aquifers for potential contamination should rely upon empirical tracer evidence for source-protection zone modelling.     

A computationally efficient approach for estimating high-rate satellite clock corrections in realtime

Realtime satellite clock corrections are usually estimated using undifferenced phase and range observations from a global network. Because a large number of ambiguity parameters must be estimated, the computation is time-consuming. Consequently, only a sparse global network of limited number of stations is processed by most IGS Realtime Analysis Centers with an update rate of 5 s. In addition, it is very desirable to build the capability to simultaneously estimate clock corrections for multi-GNSS constellations. Although the estimation can be sped up by epoch-differenced observations that eliminate ambiguities, the derived clocks can contain a satellite-specific bias that diminishes the contribution of range observations. We introduce a computationally efficient approach for realtime clock estimation. Both the epoch-differenced phase and undifferenced range observations are used together to estimate the epoch-differenced satellite clocks and the initial clock bias for each satellite and receiver. The biased clock corrections accumulated from the estimated epoch-differenced clocks are then aligned with the estimated clock biases and provided as the final clock corrections to users. The algorithm is incorporated into the EPOS-RT software developed at GFZ (GeoForschungsZentrum) and experimentally validated with the IGS global network. The comparison with the GFZ rapid products shows that the accuracy of the clock estimation with the new approach is comparable with that of the undifferenced approach, whereas the computation time is reduced to one-tenth. As a result, estimation of high-rate satellite clocks from a large reference network and tracking satellites of multi-GNSS constellations becomes achievable.