http://www.sciencedirect.com/science/article/pii/S1674987113000881

Granitod batholiths of I-type features(mostly granodiorites and tonalites),and particularly those forming the large plutonic associations of active continental margins and intracontinental collisional belts,represent the most outstanding magmatic episodes occurred in the continental crust.The origin of magmas,however,remains controversial.The application of principles from phase equilibria is crucial to understand the problem of granitoid magma generation.An adequate comparison between rock compositions and experimental liquids has been addressed by using a projected compositional space in the plane F(Fe t Mg)eAnorthiteeOrthoclase.Many calc-alkaline granitoid trends can be considered cotectic liquids.Assimilation of country rocks and other not-cotectic processes are identifed in the projected diagram.The identifcation of cotectic patterns in batholith implies high temperatures of magma segregation and fractionation(or partial melting)from an intermediate(andesitic)source.The comparison of batholiths with lower crust granulites,in terms of major-element geochemistry,yields that both represent liquids and solid residues respectively from a common andesitic system.This is compatible with magmas being formed by melting,and eventual reaction with the peridotite mantle,of subducted mélanges that are fnally relaminated as magmas to the lower crust.Thus,the off-crust generation of granitoids batholiths constitutes a new paradigm in which important geological implications can be satisfactorily explained.Geochemical features of Cordilleran-type batholiths are totally compatible with this new conception.     

Reaction overstepping and re-evaluation of peak P‒T conditions of the blueschist unit Sifnos,Greece: implications for the Cyclades subduction zone

ABSTRACT

Equilibrium thermodynamic modelling, quartz in garnet (QuiG) Raman geobarometry, and modelling of garnet nucleation at overstepped conditions were applied to three garnet-bearing blueschists from a 1.5 km-long transect across the eclogite-blueschist unit in Sifnos, Greece, in order to evaluate the accuracy of P?T conditions calculated via equilibrium thermodynamics. QuiG barometry uses the Raman shift of quartz inclusions in garnet to estimate the pressure of garnet nucleation and is independent of chemical equilibrium. Garnet nucleation temperatures were estimated by determining the stability field of the palaeo-assemblage inferred from garnet inclusion suites on mineral assemblage diagrams calculated in the MnNCKFMASH system and on temperatures obtained from Zr in rutile thermometry. These conditions were then compared to P?T conditions calculated at the equilibrium garnet isograd, and the method of intersecting isopleths. The P?T conditions calculated with intersecting garnet isopleths over- and underestimated the temperature of nucleation in samples SPH99-1a and SPH99-7, respectively, whereas they significantly underestimated nucleation pressure in SPH99-5. Nucleation of garnet in SPH99-1a at 12 kbar and ~484°C requires overstepping of ~6 kbar and a reaction affinity of 2.2 kJ mol^?1 O. SPH99-5 requires overstepping of ~8 kbar with garnet reaction affinities of at least 2.0 kJ mol^?1 O at 15 kbar and ~520°C. SPH99-7 requires overstepping of approximately 15 kbar and affinities of about 2.0–2.4 kJ mol^?1 O at ~23 kbar and ~530°C. The geotherms calculated from SPH99-7 (~6.7°C km^?1) and SPH99-5 (9.8°C km^?1) are in accordance with previous studies. The geotherm calculated from SPH99-1a, however, is warmer (11.3°C km^?1), and could reflect changes in the rate of subduction or differences in structural position within the down-going slab. The 10 kbar pressure difference between SPH99-7 and SPH99-1a can be explained by thrusting and accretion of thin slices of underplated wedge material facilitated by slab rollback and gravitational collapse.     

Disaster risk perception in urban contexts and for people with disabilities: case study on the city of Iquique (Chile)

Natural Hazards - About 15% of the world’s population suffers from some kind of disability. In addition to experiencing high rates of poverty, exclusion and lack of access to education,...     

K‐feldspar alteration to gel material and crystallization of glauconitic peloids with berthierine in Cretaceous marine sediments—sedimentary implications (Prebetic Zone,Betic Cordillera,SE Spain)

Glauconitic peloids from a Hauterivian condensed level in a hemipelagic unit of the Internal Prebetic (Los Villares Formation, eastern Betic Cordillera) have been studied by X‐ray diffraction (XRD), optical microscopy, scanning electron microscopy (SEM) and high‐resolution transmission electron microscopy (HRTEM) and analytical electron microscopy (AEM). The sediments forming the condensed level are characterized by abundant spherical to ovoid green glauconite peloids with radial cracks. Quartz, feldspar and muscovite are also abundant, whereas calcium phosphate is rarely detected. XRD analysis of the peloids reveals glauconite and small amounts of berthierine. SEM and HRTEM data show feldspar dissolution features, a Si–Al‐rich gel‐like substance filling K‐feldspar micropores and interlayering of well‐crystallized glauconite and berthierine packets. The last stage of the glauconitization process resulted in conversion of the smectitic precursor. Sedimentary and mineralogical features indicate an autochthonous origin for the glauconite. The depositional environment was a distal, hemipelagic ramp on the Southern Iberian Continental Palaeomargin. Low sedimentation rates lead to sediment condensation in a general transgressive context. The margin was affected by extensional tectonics, creating tilted blocks, resulting in lateral facies changes. The dissolution of K‐feldspars probably occurred after their deposition in the marine environment but predating the glauconitization. An influx of meteoric water is therefore required, probably related to subsurface fluxes from adjacent emergent areas (the higher parts of tilted blocks). Copyright © 2007 John Wiley & Sons, Ltd.     

Validation of present-day regional climate simulations over Europe: LAM simulations with observed boundary conditions

 Nested limited-area modelling is one method of down-scaling general circulation model (GCM) climate change simulations. To give credibility to this method the nested limited-area model (LAM) must be shown to simulate local present-day climate conditions fairly accurately. Here seven different European limited-area models driven by observed boundary conditions (operational weather forecast analyses) are validated against observations, and inter-compared for summer and winter months. Relatively large biases are found. In summer large positive surface air temperature biases are found over southeast Europe. The main reason is deficiencies in the surface hydrological schemes causing an unrealistic drying of the soil. In at least one of the models, most likely several of them, an additional factor is an overestimation of incoming solar radiation. Apart from excessive precipitation in mountainous areas in some models they generally show a negative bias due to the drying and decreased advection from the Atlantic. In winter most models have a positive precipitation bias which seems to be caused by an enhancement of advection from the Atlantic and enhanced cyclone activity. Surface air temperature biases are negative probably due to an underestimation of the incoming longwave radiation. Received: 11 December 1996 / Accepted: 17 March 1997     

Hydrofluoric Acid‐Free Digestion of Geological Samples for the Quantification of Rare Earth Elements by Inductively Coupled Plasma‐Optical Emission Spectrometry

Rare earth elements (REEs) are very important to technological development as well as to geochemical and environmental studies. In this work, hydrofluoric acid (HF) was replaced by condensed phosphoric acid (CPA) in the digestion of geological samples, and the quantification of REEs was performed by inductively coupled plasma‐optical emission spectrometry (ICP‐OES). Six international reference materials (RMs), named DC86318, CGL 111, CGL 124, CGL 126, OKA‐2 and COQ‐1 and three Brazilian ore samples, named Araxá, Catalão and Pitinga were analysed. Only zircon and xenotime, which are potential REE‐bearing minerals, were not completely dissolved. Nevertheless, no REE associated with zircon was detected. The investigated digestion method presented many advantages: It was relatively fast (3 h), avoided fluoride precipitation, it was less hazardous because handling diluted H₃PO₄ is safer than HF, NH₄F or NH₄HF₂ aqueous solutions, it preserved the quartz fittings of the measurement equipment and the final solution contained lower levels of total dissolved solids than those produced by the fusion method.     

Correction to: Numerical Analysis of Infiltration in One‑Dimensional Unsaturated Soil–Geotextile Column

Geotechnical and Geological Engineering -