Palaeoenvironments and site formation processes at the Neolithic lakeside settlement of Dispilio,Kastoria, Northern Greece

Dispilio is a lakeside settlement by the Orestias Lake, Kastoria, northern Greece. The site was inhabited from the Middle Neolithic to the Chalcolithic, with some surface evidence of Bronze Age occupation. Microfacies analysis of the sediments, supported by a suite of environmental indices, has provided detailed paleoenvironmental data and elucidated the main processes involved in the formation of the site and its history of occupation. The settlement was established on the lakeshore, on a shallow sand ridge and a shore marsh. Initially, houses were built on raised platforms above the water. After a major conflagration, a range of depositional microenvironments were established that caused local changes in the sedimentation rate. Therefore, some areas quickly emerged and became dry land, while some others continued to be flooded as part of the transitional supra‐littoral environment. On the dry land, houses were built directly on the ground, whereas in the transitional areas houses continued to be built on raised platforms. Thus, gradually, a mound was formed and further shaped by subsequent lake‐level fluctuations. One of the lake‐level rises is tentatively related to the abandonment of the mound in the Chalcolithic and the development of a hardpan on its surface. There is also evidence of later occupation during the Bronze Age in the form of a few, mostly surface, archaeological remains. © 2010 Wiley Periodicals, Inc.     

Bioconcentration of selected endocrine disrupting compounds in the Mediterranean mussel, Mytilus galloprovincialis

The occurrence of three endocrine disrupting compounds, 4-n-nonylphenol, triclosan and bisphenol A, was investigated in different bivalves originating from the Aegean Sea (Greece). The bioconcentration potential of these compounds was studied using the Mediterranean mussel (Mytilus galloprovincialis). Tissue samples were extracted by sonication. Analysis was performed by gas chromatography-mass spectrometry. According to the field survey results, the average concentrations of 4-n-nonylphenol, triclosan and bisphenol A, were 158, 461 and 404 ng g⁻¹ (dry weight), respectively. During 28 days of exposure at 300 ng L⁻¹, the tissue concentrations of compounds were constantly increased. Steady state was not observed up to the end of the experiment. Kinetic bioconcentration factors varied from 1.7 (4-n-nonylphenol and triclosan) to 4.5 L g⁻¹ (bisphenol A). Following exposure, mussels were relocated to clean water for 28 days. This experiment revealed that depuration rates for all of the target compounds were lower than uptake rates. The biological half-lives of each compound ranged between 12 days (triclosan) and 26 days (bisphenol A).     

Swimming upstream: addressing fossil fuel supply under the UNFCCC

Reducing fossil fuel supply is necessary to meet the Paris Agreement goal to keep warming ‘well below 2°C’, yet the Agreement is silent on the topic of fossil fuels. This article outlines reasons why it is important that Parties to the Agreement find ways to more explicitly address the phasing out of fossil fuel production under the UNFCCC. It describes how countries aiming to keep fossil fuel supply in line with Paris goals could articulate and report their actions within the current architecture of the Agreement. It also outlines specific mechanisms of the Paris Agreement through which issues related to the curtailment of fossil fuel supply can be addressed. Mapping out a transition away from fossil fuels – and facilitating this transition under the auspices of the UNFCCC process – can enhance the ambition and effectiveness of national and international climate mitigation efforts.

Key policy insights

• The international commitment to limit global average temperature increases to ‘well below 2°C’ provides a strong rationale for Parties to the Paris Agreement and the UNFCCC to pursue a phase-down in fossil fuel production, not just consumption.

• Several countries have already made commitments to address fossil fuel supply, by agreeing to phase down coal or oil exploration and production.

• Integrating these commitments into the UNFCCC process would link them to global climate goals, and ensure they form part of a broader global effort to transition away from fossil fuels.

• The Paris Agreement provides a number of new opportunities for Parties to address fossil fuel production.

     

Oxyanion Concentrations in Eastern Sierra Nevada Rivers – 2. Arsenic and Phosphate

Water samples were collected from the Truckee River-Pyramid Lake system, the Walker River-Walker Lake system, and the Carson River, all located in eastern California and western Nevada, U.S.A., at three different times (i.e., summer 1991, spring 1992, and autumn 1992) over a two year period. The concentrations of As, Na, Cl, PO4, and pH were measured in these river samples and the associated terminal lakes. Arsenic values ranged from below 13 nmol/kg near Truckee, California to 160 nmol/kg at Nixon, Nevada in the Truckee River, from 40 nmol/kg in the headwaters of both West and East Walker Rivers to 270 nmol/kg below Weber Reservoir on the main branch of the Walker River, and from <27 nmol/kg to 234 nmol/kg for the lower Carson River system. Arsenic concentrations in Steamboat Creek (0.91 mol/kg–1.80 mol/kg) in the Truckee River catchment are above the U.S. EPA drinking water maximum contaminant level of 0.67 mol/kg, as are the As concentrations in both Pyramid Lake (1.33 mol/kg–1.57 mol/kg ) and Walker Lake (13.7 mol/kg–18.7 mol/kg). Sources of As for all three rivers include weathering of As-rich rocks and/or regolith and input of high-As geothermal spring waters, both processes primarily, although not exclusively, adding As to the headwater regions of these rivers. Steamboat Hot Springs (29 mol/kg As 54.5 mol/kg), for example, is identified as a source of As to the Truckee River via Steamboat Creek. The high As concentrations in Pyramid and Walker Lakes are likely due to (1) desorption of arsenate from aquatic particulate matter in these high pH waters (9.0 pH 9.5), (2) limited biologic uptake of arsenate, and (3) evaporative concentration of the lake waters. Evaluation of molar PO4}/As ratios of river waters and geothermal spring waters (e.g., Steamboat Hot Springs), indicates that phosphate is substantially enriched in Steamboat Creek as well as the mid to lower reaches of the Walker and Carson Rivers. These regions of each river are dominated by agricultural interests and, additionally, in the case of Steamboat Creek, residential areas and golf courses. Our data strongly imply that phosphate-rich agricultural return flow has likely added P to these streams and, consequently, increased their respective P:As ratios.     

Controls on regional variability in marine pore-water diagenesis below the seafloor in Upper Jurassic–Lower Cretaceous prodeltaic sandstone and shales,Scotian Basin,Eastern Canada

Diagenesis in the uppermost Jurassic to Lower Cretaceous deltaic sandstones and shales of the Scotian Basin is an important control on reservoir quality. Ferruginous zone (sub-oxic) marine pore-water diagenesis controls the initial formation of Fe²⁺-silicates that are the precursors of grain-rimming chlorite that preserves porosity. This study assesses the regional controls on the type of marine pore-water diagenesis by studying the sedimentology, mineralogy, and geochemistry of the retrogradational units and underlying progradational units in parasequences from conventional cores in two wells in different parts of the basin. Coated grains preserve a record of whether marine pore-water diagenesis below the seafloor was dominantly in the ferruginous or sulphidic geochemical zone. Four types of coated grain were distinguished, each with a different mineral paragenesis. Mineralogical and chemical evidence of ferruginous zone diagenesis includes the presence of diagenetic chlorite and siderite, and the correlation of P with Fe or Ti. Pyrite and Fe-calcite are found where the sulphidic zone is more significant than the ferruginous zone. Ferruginous zone diagenesis was common in low-sedimentation rate retrogradational sediments with low organic carbon, and in delta-front turbidites and river-mouth sandstones. Estuarine, tidal flat and prodeltaic facies that are directly supplied by riverine sediments have a lower Fe:Ti ratio than do fully marine shoreface and open shelf facies as a result of input of detrital ilmenite and its alteration products. The relative contribution of colloidal iron (hydr)-oxides appears greater in distal low-sedimentation rate environments. Where large changes in sedimentation rate occurred at ravinement surfaces, the underlying progradational rocks have evidence of ferruginous zone diagenesis, whatever their facies. Rapid upward migration of the pore-water profile resulting from the change in sedimentation rate reduced the time available for mineral products to form in the deeper pore-water zones. This study has shown that the availability of Fe and organic carbon varying in a complex manner in marine deltaic sediments, but that the resulting diagenesis by marine pore-water can be predicted from facies and paleogeographic setting.     

Geochemistry, tectonic setting and metamorphism of mid-triassic volcanic rocks of Greece

Mid-Triassic volcanic rocks are preserved in about eight localities in the nappes of the external Hellenides, and are also widespread in the Pelagonian zone of central Greece. Most have suffered low-grade metamorphism. Immobile trace elements from 35 samples, 80 major element analyses, and pyroxene analyses show that these rocks are the product of an eastward dipping subduction zone. The subducted ocean was perhaps analogous to the Pennine zone of the Alps. The Othris and Pindos ophiolites are probably contemporaneous products of related back-arc extension.Metamorphic mineral assemblages in volcanic rocks of the Phyllite Series of the external Hellenides indicate high-pressure, low-temperature conditions, probably related to a second subduction that occurred prior to the main phase of Hellenide nappe emplacement in the Miocene.     

The relationship between length and width of plutons within the crustal-scale Cobequid Shear Zone, northern Appalachians, Canada

The lengths and widths have been measured for 69 component bodies of composite plutons along the Cobequid Shear Zone. Plutons on major fault strands, those with mylonite zones >0.1 km wide, exhibit evidence of multiple intrusion of magma batches. Small plutons along short faults in stepover zones appear related to rapid emplacement of magma in bodies 1.5–4 km long by 0.1–2 km wide. Such small plutons show low enrichment in incompatible elements in older component bodies, but increasing amounts in younger bodies as a result of progressive magma expulsion from crystal mush during crystallization and shear-enhanced compaction in fault zones. Wider plutons generally occur along longer fault strands accommodating more strain and penetrating deeper into the crust and show enrichment in incompatible elements. The width of the mylonitic fault zone is about 15% of the width of these plutons. The length-to-width ratio of component bodies and composite plutons varies between 2 and 11. The best-fit line describing these data has a slope of 1.056, which implies scaling behavior between plutonism and tectonic processes. Scalar properties of plutonic bodies are similar to those of faults, but scalar relationships observed in component bodies do not apply to composite plutons.     

High-resolution unmanned aerial vehicle aeromagnetic surveys for mineral exploration targets

Recent advancements in geophysical exploration have been realized through reliably integrating unmanned aerial vehicle platforms with lightweight, high-resolution magnetometer payloads. Unmanned aerial vehicle aeromagnetic surveys can provide a contemporary data product between the two end-members of coverage and resolution attained using manned airborne and terrestrial magnetic surveys. This new data product is achievable because unmanned aerial vehicle platforms can safely traverse with magnetometer payloads at flight elevations closer to ground targets than manned airborne surveys, while also delivering an increased coverage rate compared to walking conventional terrestrial surveys. This is a promising new development for geophysical and mineral exploration applications, especially in variable terrains. A three-dimensional unmanned aerial vehicle aeromagnetic survey was conducted within the Shebandowan Greenstone Belt, northwest of Thunder Bay, Ontario, Canada, in July 2017. A series of two-dimensional grids (∼500 m × 700 m) were flown at approximate elevations of 35, 45 and 70 m above ground level using a Dà-Jiāng Innovations multi-rotor unmanned aerial vehicle (S900) and a GEM Systems, Inc., Potassium Vapour Magnetometer (GSMP-35U). In total, over 48 line-km of unmanned aerial vehicle aeromagnetic data were flown with a line spacing of 25 m. The collected aeromagnetic data were compared to a regional heliborne aeromagnetic survey flown at an elevation of approximately 85 m above the terrain, with a line spacing of 100 m, as well as a follow-up terrestrial magnetic survey. The first vertical derivative of the gathered unmanned aerial vehicle total magnetic field data was calculated both directly between each of the different flight elevations, and indirectly by calculating the values predicted using upward continuation. This case study demonstrates that low flight elevation unmanned aerial vehicle aeromagnetic surveys can reliably collect industry standard total magnetic field measurements at an increased resolution when compared to manned airborne magnetic surveys. The enhanced interpretation potential provided by this approach also aided in delineating structural controls and hydrothermal fluid migration pathways (a pair of adjacent shear zones) related to gold mineralization on site. These structural features were not clearly resolved in the regional manned airborne magnetic data alone, further demonstrating the utility of applying high-resolution unmanned aerial vehicle aeromagnetic surveys to mineral exploration applications. The conclusions and interpretations drawn from the unmanned aerial vehicle aeromagnetic data, coupled with historical data, were applied to make a new gold mineralization discovery on the site, assayed at 15.7 g/t.     

Probing the Quiet Solar Atmosphere from the Photosphere to the Corona

We investigate the morphology and temporal variability of a quiet-Sun network region in different solar layers. The emission in several extreme ultraviolet (EUV) spectral lines through both raster and slot time-series, recorded by the EUV Imaging Spectrometer (EIS) on board the Hinode spacecraft is studied along with \(\mbox{H}\upalpha\) observations and high-resolution spectropolarimetric observations of the photospheric magnetic field. The photospheric magnetic field is extrapolated up to the corona, showing a multitude of large- and small-scale structures. We show for the first time that the smallest magnetic structures at both the network and internetwork contribute significantly to the emission in EUV lines, with temperatures ranging from \(8\times 10^{4}~\mbox{K}\) to \(6\times 10^{5}~\mbox{K}\). Two components of transition region emission are present, one associated with small-scale loops that do not reach coronal temperatures, and another component that acts as an interface between coronal and chromospheric plasma. Both components are associated with persistent chromospheric structures. The temporal variability of the EUV intensity at the network region is also associated with chromospheric motions, pointing to a connection between transition region and chromospheric features. Intensity enhancements in the EUV transition region lines are preferentially produced by \(\mbox{H}\upalpha\) upflows. Examination of two individual chromospheric jets shows that their evolution is associated with intensity variations in transition region and coronal temperatures.     

Validation of satellite rainfall products for operational flood forecasting: the case of the Evros catchment

An extensive validation of two of the most popular and recently upgraded satellite rainfall products, 3B42 and 3B42RT, was performed over the Evros catchment in southeastern Europe using data recorded from January 2000 to April 2009. For conducting this validation study, the Climate Prediction Center's (CPC) ground data were used. The satellite data products were aggregated to daily time series, remapped to spatial resolution of 0.5°, validated against CPC, and intercompared using a variety of statistical indices and coefficients. After the validation process, all three data sets (CPC, 3B42, and 3B42RT) were separately fed in a statistical rainfall?Crunoff model, in order to predict the five major recorded flood events which occurred in the Evros catchment during the last decade. It has been found that post-calibration with ground data, which is present only in 3B42 product, is a necessity for operational flood forecasting and similar studies conducted in areas at mid-latitudes. Knowledge of rainfall events with small intensities is crucial for estimating the total rainfall height and drastically improves the skill of the satellite product.