Benthic microbial mats: a possible major component of organic matter accumulation in the Lower Aptian oceanic anoxic event

Oceanic anoxic events (OAEs) throughout the Cretaceous were periods of high organic carbon burial leading to drawdown of atmospheric carbon dioxide and lowering of bottom-water oxygen concentration, thereby enhancing the preservation of organic matter (OM). Two dynamic depositional models have been proposed for these events in the Tethyan domain: one is based on strong thermohaline stratification and low surface productivity, the other on high surface productivity with intensified deep-water circulation. Here, we propose another explanation for the concentration of OM, derived essentially from microscopical observations (scanning electron microscope and transmission electron microscope) in the organic-richest interval of an Early Aptian OAE in central Italy (OAE1a or Selli level, 116 Ma). This high-resolution microscopical study of OM highlights benthic microbial mats as the possible source of organic-rich samples where amorphous OM is the major organic constituent. These mats could be more common in OAE black shales than previously thought.     

Volume and surface sources due to laterally varying boundaries of elastic homogeneous layers

Summary. Various methods have been applied to solve propagation problems in media composed of homogeneous layers, the boundaries of which have slight lateral variations. In this paper, volume sources, introduced in a previous paper to describe the effects of lateral irregularities, are replaced by an equivalent body force and by surface sources concentrated on the irregular boundaries. The surface sources we find are similar to those obtained by Kennett for a two-dimensional structure and we generalize his results to a three-dimensional structure and to the case when an external body force is present.     

Al speciation in tropical podzols of the upper Amazon Basin: A solid-state Al MAS and MQMAS NMR study

In the upper Amazon Basin, aluminum previously accumulated in lateritic formations is massively remobilised in soils by podzolization and exported in waters. We have investigated the speciation of aluminum in the clay-size fractions of eight horizons of waterlogged podzols lying in a depression of a plateau. The horizons illustrate the main steps involved in the podzolization of laterites. They belong to eluviated topsoil A horizons and illuviated subsoil Bhs, Bh and 2BCs horizons of weakly and better-expressed podzols located at the margin and centre of the depression. For the first time, aluminum speciation is quantitatively assessed in soils by spectroscopic methods, namely FTIR, ²⁷Al magic angle spinning (MAS) and multiple-quantum magic angle spinning (MQMAS), nuclear magnetic resonance (NMR). The results thus obtained are compared to chemical extraction data.Solid-state ²⁷Al MAS NMR spectra enable to distinguish Al bound to organic compounds from that incorporated in secondary mineral phases detected by FTIR. MQMAS experiments additionally show that both chemical shifts and quadrupolar constants are distributed for Al nuclei linked with organic compounds. Similar amounts of chelated Al are obtained from NMR spectra and chemical extractions. The study enables to highlight three major steps in the fate of aluminum. (i) Aluminum is first released by mineral weathering, feeds complexing sites of organic matter and accumulates in subsurface Bhs horizons of weakly expressed podzols (acidocomplexolysis). (ii) Complexes of aluminum with organic matter (Al-OM) then migrate downwards in sandy horizons of better-expressed podzols and accumulate at depth in less permeable 2BCs horizons. (iii) The minor amounts of aluminum present in the 2BCs horizon of the downslope podzol show that aluminum is eventually exported towards the river network, either complexed with organic matter or as Al³⁺ ions after desorption from organic compounds, due to decreasing pH or biodegradation of organic ligands. The direct spectroscopic determination of Al-speciation during the formation of podzolic soils opens new perspectives to trace metal loads in the rivers of the upper Amazon Basin.     

Seismic evidence for stepwise thickening of the crust across the NE Tibetan plateau

We performed a receiver function analysis on teleseismic data recorded along two 550 km-long profiles crossing the northeastern Tibetan plateau. Results from time to depth migration, grid-search V_p/V_s determination and simulated annealing inversion of waveforms, reveal that the crust thickens from ∼50 km near the northern edge of the plateau to ∼80 km south of the Jinsha suture in the Qiang Tang block. Crustal thickening occurs in staircase fashion with steps located beneath the main, reactivated sutures. The V_p/V_s ratio, close to the global continental average does not suggest widespread partial melting but rather a more usual separation between an upper felsic and a lower mafic part within the northeastern Tibetan crust.     

Continuous ambient‐vibration monitoring of the arch dam of Mauvoisin

This paper presents the experimental programme and results of a continuous ambient vibrations recording programme carried out on the 250 m arch dam of Mauvoisin. This project follows a series of previous measurements completed for seven different water levels. An automated system was set up on the dam and the ambient vibrations were recorded twice daily for a period of 6 months. Frequency shifts were tracked throughout the testing period and the effects of the varying water level were identified. The results confirmed the behaviour observed in previous ambient‐ and forced‐vibration tests. The added‐mass effects are overcome by the stiffening of the dam due to increasing hydrostatic pressure for lower reservoir levels. This trend is then reversed for higher water levels. Any temperature‐related effects were not identified. The experimental techniques are briefly described and the frequency identification process and its limitations are discussed. Copyright © 2001 John Wiley & Sons, Ltd.     

Feasibility of the short ARC adjustment model for precise determinations of the oceanic geoid

A key element in any attempt to achieve a0.1 m precision in geoid representation via satellite altimetry is obtaining an ephemeris of comparable precision, or circumventing this requirement by adjusting the ephemeris in some way, together with the geoid. The first possibility requires extensive satellite tracking and involves an enormous number of adjustable parameters in the long arc approach. The second psssibility allows for a piece-wise treatment of short orbital arcs considered mutually independent, in which slight adjustments of the state vector parameters can compensate for an inherent modeling error. The main question to be answered when pondering the possibility of using the short arc adjustment model in SEASAT-A altimetry reductions is whether or not this method is inherently capable of representing the detailed geoid with0.1 m precision. An analysis of computer simulations provides at least a partial answer to this question by pointing out the necessary conditions in order to achieve the desired precision; under certain favorable circumstances, not described in detail, these conditions could prove to be also sufficient.     

Second-order derivatives in a local frame developed in spheroidal and spherical coordinates

Second-order derivatives of a general scalar function of position (F) with respect to the length elements along a family of local Cartesian axes are developed in the spheroidal and spherical coordinate systems. A link between the two kinds of formulations is established when the results in spherical coordinates are confirmed also indirectly, through a transformation from spheroidal coordinates. IfF becomesW (earth's potential) the six distinct second-order derivatives—which include one vertical and two horizontal gradients of gravity—relate the symmetric Marussi tensor to the curvature parameters of the field. The general formulas for the second-order derivatives ofF are specialized to yield the second-order derivatives ofU (standard potential) and ofT (disturbing potential), which allows the latter to be modeled by a suitable set of parameters. The second-order derivatives ofT in which the property ΔT=0 is explicitly incorporated are also given. According to the required precision, the spherical approximation may or may not be desirable; both kinds of results are presented. The derived formulas can be used for modeling of the second-order derivatives ofW orT at the ground level as well as at higher altitudes. They can be further applied in a rotating or a nonrotating field. The development in this paper is based on the tensor approach to theoretical geodesy, introduced by Marussi [1951] and further elaborated by Hotine [1969], which can lead to significantly shorter demonstrations when compared to conventional approaches.     

In-plane free vibration of supported/free parabolic cables

The free-vibration analysis of parabolic cables fixed at the lower end and free to move in the horizontal direction at the upper end is performed. The dynamic stiffness of such cables is zero at the natural frequencies and this property is used to obtain the governing frequency equation. Double-frequency points at which two consecutive natural frequencies are identical occur for specific values of stiffness parameters. Expressions for the natural modes of vibration and for the contribution of the extensional and inextensional cable resistances to the modal potential energy are given.     

Inverse differentiation pathway by multiple mafic magma refilling in the last magmatic activity of Nisyros Volcano, Greece

Based on detailed field, petrographic, chemical, and isotopic data, this paper shows that the youngest magmas of the active Nisyros volcano (South Aegean Arc, Greece) are an example of transition from rhyolitic to less evolved magmas by multiple refilling with mafic melts, triggering complex magma interaction processes. The final magmatic activity of Nisyros was characterized by sub-Plinian caldera-forming eruption (40?ka), emplacing the Upper Pumice (UP) rhyolitic deposits, followed by the extrusion of rhyodacitic post-caldera domes (about 31–10?ka). The latter are rich in magmatic enclaves with textural and compositional (basaltic–andesite to andesite) characteristics that reveal they are quenched portions of mafic magmas included in a cooler more evolved melt. Dome-lavas have different chemical, isotopic, and mineralogical characteristics from the enclaves. The latter have lower ⁸⁷Sr/⁸⁶Sr and higher ¹⁴³Nd/¹⁴⁴Nd values than dome-lavas. Silica contents and ⁸⁷Sr/⁸⁶Sr values decrease with time among dome-lavas and enclaves. Micro-scale mingling processes caused by enclave crumbling and by widespread mineral exchanges increase from the oldest to the youngest domes, together with enclave content. We demonstrate that the dome-lavas are multi-component magmas formed by progressive mingling/mixing processes between a rhyolitic component (post-UP) and the enclave-forming mafic magmas refilling the felsic reservoir (from 15?wt.% to 40?wt.% of mafic component with time). We recognize that only the more evolved enclave magmas contribute to this process, in which recycling of cumulate plagioclase crystals is also involved. The post-UP end-member derives by fractional crystallization from the magmas leftover after the previous UP eruptions. The enclave magma differentiation develops mainly by fractional crystallization associated with multiple mixing with mafic melts changing their composition with time. A time-related picture of the relationships between dome-lavas and relative enclaves is proposed, suggesting a delay between a mafic magma input and the relative dome outpouring. We also infer that the magma viscosity reduction by re-heating allows dome extrusion without explosive activity.