Role of microorganisms in oceanic anoxic events (OAEs)

The accumulation of organic matter (OM) during oceanic anoxic events (OAEs) that took place in the Mesozoic may reflect different biogeochemical pathways and feedbacks related to palaeoenvironmental changes. It originates from a combination of nutrient cycling, metal concentrations and position of the chemocline and/or pycnocline controlling biological production. Because ocean stagnation cannot induce euxinia, an expanded oxygen minimum zone (OMZ) associated with upwelling and improved hydrological cycles is more commonly accepted. In some depositional settings, it permitted the evolution of anoxia/dysoxia to euxinia (sulphidic waters). The latter is recorded by the presence of anoxygenic phototrophs and involved denitrification, anaerobic oxidation of methane and sulphate reduction. In order to better constrain different OAE palaeoenvironments, models are suggested here that show the evolution from main microbial communities thriving through the water column to bacterial and more complex microbial mats. Therefore, microbial processes have a key role in OM production and metabolization. They directly influence the position of the chemocline. Detailed study of the OM preserved in black shales will be key to understanding OAEs.     

Hydrological and geotechnical investigations of mass movements in an equatorial city (Yaoundé, Cameroon)

In the present study, mass movements (landslide and mudslide) bound to a gully located at Mendong, a suburb of Yaoundé in Cameroon were examined using hydrological, geotechnical and geomorphological observations. The data indicate that water is an important causative factor of mass movements in the area studied. In fact, the water flow (waste water and runoff) provokes the saturation of materials at the slope foot. These materials lose their mechanical qualities and some deep ruptures generate landslide. During the rainy season, when the cumulative rainfall is more than 200 mm, these landslides are accompanied by mudslides that generate disturbances on the infrastructure situated around the gully and farther downstream. The economic and environmental damages resulting from the Mendong mass movements are considerable, such as degradation of the topography, losses in farm land, transportation and downstream sedimentation in a pond situated at the slope foot, loss of life and damage to the economy. All this calls for a multidisciplinary and integrated approach to hazard assessment and risk mitigation, which included data collection and interpretation, growing public and authority awareness, and preventing or reducing runoff and waste water flows by proper management and drainage.     

Mexico’s coasts: Half-way to sustainability

Sustainability was estimated through a Sustainable Capacity Index defined as the combination of three aspects (state of the environment, quality of life of the human population, and pressure applied by human activities), used as a guideline for the differentiation of sustainability situations. We identified five different municipality groups, in terms of sustainability, as well as two thresholds, beyond which sustainable capacity was not present: below the sustainable capacity lower threshold, close to the sustainable capacity threshold, optimum situation, close to the sustainable capacity higher threshold, and above the sustainable capacity higher threshold. In general Mexico was found to be in an apparent balanced situation, in the sense that it is not overweighed around extreme values, the majority of the coastal municipalities falling in the optimum sustainable situation, within the cross comparison, characterized by medium coastal cities. We can conclude that Mexico has reached a critical point where it has to decide about the direction its coastal development has to take, since our results suggest that Mexican’s municipalities are half way to sustainability. The ideal situation would be that the optimum situation would maintain its actual low pressure with high state, but could increase its quality of life. This work provided a rapid monitoring and cross comparison tool for an estimation of the sustainable situation of Mexico’s coasts, repeatable in time, and in phase with the recent national coastal zone management principles and strategies.     

Pan-African metamorphic evolution in the southern Yaounde Group (Oubanguide Complex,Cameroon) as revealed by EMP-monazite dating and thermobarometry of garnet metapelites

Garnet-bearing micaschists and paragneisses of the Yaounde Group in the Pan-African Central African Orogenic Belt in Cameroon underwent a polyphase structural evolution with the deformation stages D₁–D₂, D₃ and D₄. The garnet-bearing assemblages crystallized in course of the deformation stage D₁–D₂ which led to the formation of the regional main foliation S₂. In X_Ca–X_Mg coordinates one can distinguish several zonation trends in the garnet porphyroblasts. Zonation trends with increasing X_Mg and variably decreasing X_Ca signalize a garnet growth during prograde metamorphism. Intermineral microstructures provided criteria for local equilibria and a structurally controlled application of geothermobarometers based on cation exchange and net transfer reactions. The syndeformational P–T path sections calculated from cores and rims of garnets in individual samples partly overlap and align along clockwise P–T trends. The P–T evolution started at ～450 °C/7 kbar, passed high-pressure conditions at 11–12 kbar at variable temperatures (600–700 °C) and involved a marked decompression toward 6–7 kbar at high temperatures (700–750 °C). Th–U–Pb dating of metamorphic monazite by electron microprobe (EMP-CHIME method) in eight samples revealed a single period of crystallization between 613 ± 33 Ma and 586 ± 15 Ma. The EMP-monazite age populations between 613 ± 33 Ma enclosed in garnet and 605 ± 12 Ma in the matrix apparently bracket the high temperature–intermediate pressure stage at the end of the prograde P–T path. The younger monazites crystallized still at amphibolite-facies conditions during subsequent retrogression. The Pan-African overall clockwise P–T evolution in the Yaounde Group with its syndeformational high pressure stages and marked pressure variations is typical of the parts of orogens which underwent contractional crustal thickening by stacking of nappe units during continental collision and/or during subduction-related accretionary processes.     

Spectroscopic investigation and theoretical modeling of kaolinite-group minerals and other low-temperature phases

This article summarizes some recent results obtained on the physical properties of environmental minerals, mostly kaolinite-group minerals and Fe- and Al-(hydr)oxides occurring in lateritic soils. The defective structure of these minerals, including impurities, stacking faults and radiation-induced defects, is probed using infrared spectroscopy and electron paramagnetic resonance. Resulting information bears on models of soil formation and transformation mechanisms of minerals in low-temperature environments. We underline the increasing impact of quantum chemical modeling in this field, providing straightforward interpretations of spectroscopic signals and overcoming the limits of fingerprint approaches. Importantly, the first-principles modeling of isotopic fractionation factors provides new links between mineralogical and geochemical investigations of secondary minerals.     

Balloon-borne observations of mid-latitude stratospheric water vapour: comparisons with HALOE and MLS satellite data

We present here in situ measurements obtained between 1991 and 2011 in outer-vortex conditions by the ELHYSA balloon-borne frost-point hygrometer. The frost-point hygrometer profiles are used for comparisons with the satellite data from version 19 (v19) and version 3.3 (v3.3) of the HALogen Occultation Experiment (HALOE) and the Microwave Limb Sounder (MLS) respectively. Potential Vorticity mapping is applied to all data sets to remove contributions of transient tropical intrusions and polar vortex air masses and hence ensure consistent comparisons between the balloon and satellite observations. Our selected balloon in situ observations are too sparse to directly infer mid-latitude stratospheric time series for continuous comparisons with HALOE and MLS records or derive water vapour trends but can be used to validate the satellite data. A mean difference of ?0.83?±?1.58 % (?0.04?±?0.07 ppmv) is obtained between HALOE v19 data and the balloon frost-point observations (with respect to HALOE) over the 30–80 hPa altitude range. The hygrometer-HALOE differences appear time-dependent as already presented in the literature. The mean difference reaches 2.80?±?0.96 % (0.13?±?0.04 ppmv) for MLS v3.3, with MLS systematically wetter than the balloon data reflecting a systematic bias between both datasets. We use our balloon data as reference to provide some information about the HALOE-MLS difference. From post-2000 ELHYSA-HALOE and ELHYSA-MLS comparisons, we find a HALOE-MLS difference matching the expected bias, with MLS v3.3 6.60?±?2.80 % (0.27?±?0.11 ppmv) wetter than HALOE v19. From the results obtained from our balloon-satellite data comparisons, we finally discuss the issue about merging the HALOE and MLS data sets to provide stratospheric water vapour trends.     

Trace elements in magnetite as petrogenetic indicators

We have characterized the distribution of 25 trace elements in magnetite (Mg, Al, Si, P, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Ge, Y, Zr, Nb, Mo, Sn, Hf, Ta, W, and Pb), using laser ablation ICP-MS and electron microprobe, from a variety of magmatic and hydrothermal ore-forming environments and compared them with data from the literature. We propose a new multielement diagram, normalized to bulk continental crust, designed to emphasize the partitioning behavior of trace elements between magnetite, the melt/fluid, and co-crystallizing phases. The normalized pattern of magnetite reflects the composition of the melt/fluid, which in both magmatic and hydrothermal systems varies with temperature. Thus, it is possible to distinguish magnetite formed at different degrees of crystal fractionation in both silicate and sulfide melts. The crystallization of ilmenite or sulfide before magnetite is recorded as a marked depletion in Ti or Cu, respectively. The chemical signature of hydrothermal magnetite is distinct being depleted in elements that are relatively immobile during alteration and commonly enriched in elements that are highly incompatible into magnetite (e.g., Si and Ca). Magnetite formed from low-temperature fluids has the lowest overall abundance of trace elements due to their lower solubility. Chemical zonation of magnetite is rare but occurs in some hydrothermal deposits where laser mapping reveals oscillatory zoning, which records the changing conditions and composition of the fluid during magnetite growth. This new way of plotting all 25 trace elements on 1 diagram, normalized to bulk continental crust and elements in order of compatibility into magnetite, provides a tool to help understand the processes that control partitioning of a full suit of trace elements in magnetite and aid discrimination of magnetite formed in different environments. It has applications in both petrogenetic and provenance studies, such as in the exploration of ore deposits and in sedimentology.     

Accretion and tectono-sedimentary progradation: The Taranto Gulf (Southern Italy)

The geological structures of the eastern Calabrian Apenninic front within the Gulf of Taranto, southern Italy, are compared to those of a convergent margin, using simple criteria such as the origin and volume of the sediment supply, and the relative ratio between sediments carried by the sinking plate and those directly supplied by the overriding margin. Based on this criteria we distinguish four main types of sedimentary accretion occurring at convergent continental margins: (a) Pacific type, (b) Indonesian type, (c) Caribbean type, and (d) Apenninic type.