Quantitative assessment of gas washing of oils in the Tazhong area of the Tarim Basin,Northwest China

Gas washing has been known in the Tazhong area of the Tarim Basin, but its quantitative assessment has not yet been reported. Here the influence of gas washing fractionation in the area was discussed based on the gas chromatogram data of 68 oils and the results of the mixing experiments of a black oil and a condensate. The results show that the intensity of gas washing fractionation decreased generally from northern to southern part and vertically from deep reservoirs to shallow reservoirs. The gas washing fractionation was mainly controlled by fault systems in this area, with the increase of n-alkane mass depletion positively correlated to the number and scale of faults. Gas washing fractionation appears to have affected the hydrocarbon property, and as a result the diversity of the crude oils is markedly controlled by gas washing. In addition, the occurrence of waxy oil in this area may be resulted from multiple factors including gas washing, mixed filling and migration fractionation. Supported by National Basic Research Program of China (Grant No. 2006CB202303) and the National Natural Science Foundation of China (Grant No. 40672091)     

Chesapeake Bay Plume Morphology and the Effects on Nutrient Dynamics and Primary Productivity in the Coastal Zone

To determine the effects of the Chesapeake Bay outflow plume on the coastal ocean, nutrient concentrations and climatology were evaluated in conjunction with nitrogen (N) and carbon (C) uptake rates during a 3-year field study. Sixteen cruises included all seasons and captured high- and low-flow freshwater input scenarios. Event-scale disturbances in freshwater flow and wind speed and direction strongly influenced the location and type of plume present and thus the biological uptake of N and C. As expected, volumetric primary productivity rates did not always correlate with chlorophyll a concentrations, suggesting that high freshwater flow does not translate into high productivity in the coastal zone; rather, high productivity was observed during periods where recycling processes may have dominated. Results suggest that timing of meteorological events, with respect to upwelling or downwelling favorable conditions, plays a crucial role in determining the impact of the estuarine plume on the coastal ocean.     

From global to local: Testing the potential of cross-scaling in global data sets

The present study investigates the potential of readily available and easily accessible global data sets to understand regional/local level interactions in wetland systems. The biogeographical zones of India were used a base-frame to select three sites. The study well fits the interests of National Wetland Committee of India to investigate and document fundamental information on wetland extent/distribution. The national partnership with SACON represents this interest. SACON commenced the inland wetland inventory module at national scale using geospatial data, although the provincial scale analysis is underway. In addition, the global irrigated area mapping (GIAM-IWMI) project generated multi-scalar spatial outputs for irrigated/rain-fed areas. With the existing information base, a multi-level geospatial analysis using Arc GIS algorithmic modelling was used to derive comprehensive appraisal of wetland systems complementing the data from GIAM and SACON. It was observed that the overlap between the two layers was 58 percent for Gujarat and 10 percent in Tamil Nadu. In Krishna basin the wetland’s cover 1.04 million hectare excluding the rice agro-ecosystem. The difference in the biogeography of the case sites governs the gradient of information derived from both data layers. Additionally, the global lakes and wetlands database (GLWD) database added thematic information on coastal wetlands. In summary we describe the cross-scaling the global data layers to compliment the regional/national level monitoring assignments.     

Simultaneous estimation of cross-validation errors in least squares collocation applied for statistical testing and evaluation of the noise variance components

The cross-validation technique is a popular method to assess and improve the quality of prediction by least squares collocation (LSC). We present a formula for direct estimation of the vector of cross-validation errors (CVEs) in LSC which is much faster than element-wise CVE computation. We show that a quadratic form of CVEs follows Chi-squared distribution. Furthermore, a posteriori noise variance factor is derived by the quadratic form of CVEs. In order to detect blunders in the observations, estimated standardized CVE is proposed as the test statistic which can be applied when noise variances are known or unknown. We use LSC together with the methods proposed in this research for interpolation of crustal subsidence in the northern coast of the Gulf of Mexico. The results show that after detection and removing outliers, the root mean square (RMS) of CVEs and estimated noise standard deviation are reduced about 51 and 59%, respectively. In addition, RMS of LSC prediction error at data points and RMS of estimated noise of observations are decreased by 39 and 67%, respectively. However, RMS of LSC prediction error on a regular grid of interpolation points covering the area is only reduced about 4% which is a consequence of sparse distribution of data points for this case study. The influence of gross errors on LSC prediction results is also investigated by lower cutoff CVEs. It is indicated that after elimination of outliers, RMS of this type of errors is also reduced by 19.5% for a 5 km radius of vicinity. We propose a method using standardized CVEs for classification of dataset into three groups with presumed different noise variances. The noise variance components for each of the groups are estimated using restricted maximum-likelihood method via Fisher scoring technique. Finally, LSC assessment measures were computed for the estimated heterogeneous noise variance model and compared with those of the homogeneous model. The advantage of the proposed method is the reduction in estimated noise levels for those groups with the fewer number of noisy data points.     

Assessment of the Pacific decadal oscillation’s contribution to the occurrence of local torrential rainfall in north China

On 21–22 July 2012, torrential rains hit North China, with the daily precipitation record at Beijing station reaching 160.6 mm; this event is named the Beijing 7–21 case. This paper assesses the likelihood of the occurrence of local torrential rains, such as the Beijing 7–21 case, from the perspective of climate variability. In particular, the influence of the Pacific Decadal Oscillation (PDO) is assessed. There were five extreme events, with daily precipitation records equal to or larger than 160.6 mm, at Beijing station during the period 1951–2012; all of these events happened during negative phases of the PDO. The present analysis indicates that precipitation events more extreme than the Beijing 7–21 case should happen more than once per decade during negative phases of the PDO, but only about once every four decades during positive PDO phases. The negative phase of the PDO is found to be associated with a much greater probability of daily records of southerly winds in North China during summer. Strong southerly summer monsoons are deemed favorable for increasing the occurrence of local extreme rainfall over North China.     

Review on physical models of lunar brightness temperature

Brightness temperature is a main index to reflect the energy of microwave radiation of an object. Using lunar brightness temperature data, physical properties of lunar regolith, such as thickness, heat flow and dielectric permittivity, could be interpreted. There are two methods to study brightness temperature distribution of the moon: the first is used to measure lunar brightness temperature by radio observation or spaceborne microwave radiometers, and the second is used to simulate calculation by the physical model. On the basis of the measurements of lunar brightness temperature in the history, this study analyzed the main physical model of lunar brightness temperature, also including its theory and influence factors. The authors concluded that surface and subsurface temperatures of the moon, dielectric properties and layered structure of lunar regolith were the main factors affecting the global brightness temperature of the moon. These factors should be quantified in detail in the future research.     

Stable isotope constraints on the fluid source of hydrothermal breccia pipes in the Tankwa Karoo depocentre,South Africa: Breakdown of authigenic minerals during sill intrusion

The Karoo Basin covers much of South Africa and is an area of prospective shale gas exploration, with the Whitehill Formation the target shale unit. However, the sedimentary succession, including the Whitehill, has been intruded by a series of sills and dykes associated with the Karoo Large Igneous Province (~183 Ma), which are expected to have modified the thermal history of the basin dramatically. Here, we investigate a secondary effect of these intrusions: a series of hydrothermal vent complexes, or breccia pipes, focusing on using O, H, and C isotopes to constrain the origin and evolution of fluids produced during the intrusion of basaltic sills. A cluster of breccia pipes have been eroded down to the level of the Ecca Group at Luiperdskop on the western edge of the Karoo basin; a small isolated pipe of similar appearance crops out 13 km to the east. The Luiperdskop pipes are underlain by a Karoo dolerite sill that is assumed to provide the heat driving fluidization. The pipes consist of fine‐grained matrix and about 8% clasts, on average, of mostly sedimentary material; occasional large rafts of quartzite and dolerite are also present. The presence of clasts apparently from the Dwyka Group is consistent with the depth of formation of the pipes being at, or near, the base of the Karoo Supergroup, between 400 and 850 m below present surface. The presence of chlorite as the dominant hydrous mineral is consistent with an emplacement temperature between 300 and 350°C. The major and trace element, and O‐ and H‐isotope composition of the Tankwa breccias is homogenous, consistent with them being derived from the same source. The δ¹⁸O values (vsVSMOW) of the breccias are relatively uniform (7.1‰–8.7‰), and are similar to that of the country rock shale, and both are lower than expected for shale. The water content of the breccia is between 2.7 and 3.1 wt.% and the δD values range from ?109‰ to ?144‰. Calcite in vesicles has δ¹³C and δ¹⁸O (VSMOW) values of ?4.2‰ and 24.0‰, respectively. The low δD value of the breccia rocks does not appear to be due to the presence of methane in the fluid. Instead, it is proposed that low δD and δ¹⁸O values are the result of the fluid being derived from the breakdown of clay minerals that formed and were deposited at a time of cold climate at ~290 Ma.     

Development mechanism for the landslide at Xinlu Village,Chongqing, China

Due to the continuous and intense rainfall from June 26 to 28, 2016, Xinlu Village in Ganshui Town, Qijiang District, Chongqing, experienced a unitary-slip landslide at approximately UTC+8 19:30 on June 28. This landslide disrupted the Chuan-Qian railway and damaged four residential buildings. To analyze and rehabilitate the landslide, the engineering geology, hydrological conditions, and deformation instability mechanism of this landslide were investigated and comprehensively analyzed based on an in situ survey, geophysical drilling, and a laboratory quick-shearing test. The results show that the landslide is a typical gradual progressive landslide.     

Leachability of trace elements from two stabilized low lime Indian fly ashes

Fly ash is a waste by-product obtained from the burning of coal by thermal power plants for generating electricity. When bulk quantities are involved, in order to arrest the fugitive dust, it is stored wet rather than dry. Fly ash contains trace concentrations of heavy metals and other substances in sufficient quantities to be able to leach out over a period of time. In this study an attempt was made to study the leachabilities of a few selected trace metals: Cd, Cu, Cr, Mn, Pb and Zn from two different types of class F fly ashes. Emphasis is also laid on developing an alternative in order to arrest the relative leachabilities of heavy metals after amending them with suitable additives. A standard laboratory leaching test for combustion residues has been employed to study the leachabilities of these trace elements as a function of liquid to solid ratio and pH. The leachability tests were conducted on powdered fly ash samples before and after amending them suitably with the matrices lime and gypsum; they were compacted to their respective proctor densities and cured for periods of 28 and 180 days. A marked reduction in the relative leachabilities of the trace elements was observed to be present at the end of 28 days. These relative leachability values further reduced marginally when tests were performed at the end of 180 days.