Generation of homologous porphyrins under simulated geochemical conditions

Crude oils generally contain at least one symmetrical homologous series of porphyrins, which is usually centered at m/e 476 (DPEP) or m/e 478 (etioporphyrin). Simulated geochemical conditions in the present study resulted in decarboxylations and alkylations which ultimately led to the synthesis of homologous porphyrins from a single porphyrin. In several series of closed tube experiments, mesoporphyrin IX dimethylester (MPDME) was mixed with a variety of constituents including benzene, acetic acid, propionic acid, water and clay; the experiments were performed at temperatures between 135°C and 400°C at time intervals up to 80 days. Dealkylation, alkylation, hydrolysis, decarboxylation and metallation products were observed. An unsymmetrical homologous series of porphyrins was produced from MPDME. The dominant mass was m/e 478 (corresponding to a double deoarboxylation). Dealkylation products in multiples of 14 amu below the m/e 478 peak comprised the other members of the series. Cu-MPDME also produced homologous porphyrins. These, however, exhibited symmetry about the dominant members, similar to the symmetry found for the porphyrins of most petroleums and oil shales.     

Some things old, some things new: The spatial representations and politics of change of the peak oil relocalisation movement

Despite continued uncertainty about the physical realities and political, economic and social implications of peak oil, combined concerns about oil scarcity, climate change and globalisation has spawned an energetic relocalisation movement dedicated to achieving a comprehensive reduction in oil dependency through community-scale initiatives. This paper uses a discourse approach to examine the emergence, geographical spread and practices of the Transition Network, a UK-originated relocalisation movement now involving 186 local initiatives in the UK and other countries. We trace the movement’s drawing upon, and innovation from, discourses and techniques used by other grassroots environmental movements to promote a spatial representation of peak oil as an inevitable and geographically undiscriminating problem, and its use of addiction metaphors and participatory techniques to promote personal and community-scale energy descent initiatives as a viable and necessary alternative to globalisation. We also analyse the spatial representations and techniques used in the Network’s “rhizomic” spread across multiple localities around the world and embedding in communities where relocalisation initiatives are established. We conclude by examining the future challenges these spatial constructions of peak oil pose for the relocalisation movement.     

Sustainability of transhumance grazing systems under socio-economic threats in Langtang,Nepal

The decline or loss of traditional social- ecological systems may induce adverse effects to the societies and ecosystems. Transhumance, the recurring and seasonal movement of grazing livestock, is increasingly constrained by a numbers of factors including policy, land use and soeio-economic changes in Nepal. To explore how these changes have affected the transhumance, this study investigated transhumance at the Langtang valley in central Nepal. The specific objectives of this study were to determine the herd size and composition, spatial-temporal patterns and to identify the major drivers of the system and the system changes. Data were collected from field study comprising semi-structured interviews with the herders, focus group discussions, key informants survey, and observations of rangeland and livestock management systems. The study revealed that the transhumanee system in the Langtang is influenced by two types of drivers. In one hand, traditional practices are contributing to the sustainability of the system. On the other hand, the grazing patterns and adaptive responses are strongly influenced by changes in government policies, socioeconomic and cultural transformation, livestock productivity, markets, rangeland conditions and climate change. The findings of this study help with the development and implementation of transhumance management policy for the sustainability.     

The contribution of faint blue galaxies to the submillimetre counts and background

Observations in the submillimetre (submm) waveband have recently revealed a new population of luminous sources. These are proposed to lie at high redshift and to be optically faint because of their high intrinsic dust obscuration. The presence of dust has been previously invoked in optical galaxy count models which use the Bruzual & Charlot evolution models with an exponential τ =9 Gyr star formation rate (SFR) for spirals, and these fit the count data well from U to K . We now show that by using either a 1/ λ or Calzetti absorption law for the dust and re-distributing the evolved spiral galaxy ultraviolet (UV) radiation into the far-infrared (FIR), these models can account for all of the 'faint' ( 1 mJy) 850-μm galaxy counts, but fail to fit 'bright' ( 2 mJy) sources, indicating that another explanation for the submm counts may apply at brighter fluxes, e.g., quasi-stellar objects (QSOs) or ultraluminous infrared galaxies (ULIRGs). We find that the main contribution to the faint, submm number counts is in the redshift range 0.5< z <3, peaking at z ≈1.8. The above model, using either dust law, can also explain a significant proportion of the extragalactic background at 850 μm, as well as producing a reasonable fit to the bright 60-μm IRAS counts.     

SEARCHING METHODS FOR RAPID GRID INTERPOLATION*

A widely used method for grid interpretation from a set of discrete sample points is based on the inverse distanceweighted model. This method requires the identification of k-nearest sample points for each grid point, probably the most time-consuming portion of the grid interpolation process. Three searching methods for identifying the k-nearest sample points are discussed and compared. Two of these methods were consistenty faster without sacrificing accuracy than the brute-force searching method, and one method was from one to over 90 times faster than the brute-force searching method.     

Late Holocene changes in ultraviolet radiation penetration recorded in an East Antarctic lake

Late Holocene changes in the ultraviolet radiation (UVR) penetration in a lake in the Larsemann Hills (East Antarctica) were reconstructed using sediment core proxies based on fossil pigments (scytonemins and its derivatives) and siliceous microfossils. The influence of changes in lake depth on the UVR proxy was excluded by applying a correction, based on the non-linear relation between modern scytonemin concentrations and lake depth in a regional reference data set, and the record of past lake depths inferred using a diatom based transfer function in the sediment core. Results showed four well-defined maxima in the UVR proxy during the last 1600–1800 years, centred around 1820–1780, 1580–1490, 790–580 and 680–440 AD. Several mechanisms may account for these observed changes in UVR penetration, including past variability in cloud cover, atmospheric turbidity, ozone column depth, snow cover on the lake ice, DOM concentrations and lake-ice thickness and transparency resulting from temperature fluctuations. Although some gaps remain in our knowledge of scytonemin production in relation to the limnology of Antarctic lakes, the results highlight the importance and potential of the sediments in these highly transparent water bodies as archives of changes in past UVR receipt at the Earth’s surface.     

Mapping the magnetosphere of PSR B1055−52

We present a geometric study of the radio and γ-ray pulsar B1055−52 based on recent observations at the Parkes radio telescope. We conclude that the pulsar's magnetic axis is inclined at an angle of 75° to its rotation axis and that both its radio main pulse and interpulse are emitted at the same height above their respective poles. This height is unlikely to be higher or much lower than 700 km, a typical value for radio pulsars.
It is argued that the radio interpulse arises from emission formed on open fieldlines close to the magnetic axis which do not pass through the magnetosphere's null (zero-charge) surface. However, the main pulse emission must originate from fieldlines lying well outside the polar cap boundary beyond the null surface, and farther away from the magnetic axis than those of the outer gap region where the single γ-ray peak is generated. This casts doubt on the common assumption that all pulsars have closed, quiescent, corotating regions stretching to the light cylinder.