A critical assessment of the analysis and distributions of scytonemin and related UV screening pigments in sediments

High performance liquid chromatography-mass spectrometry has been used to identify the cyanophyta-derived ultraviolet screening pigment scytonemin and its reduced counterpart in an Antarctic lake sediment. The formation of an artefact during the analysis has been demonstrated, enabling the recovery of improved estimates of the scytonemin and reduced scytonemin signals. The overall pigment composition records a primary producer community comprising both oxygenic and anoxygenic photoautotrophs, with variations in the abundance of scytonemin relative to the chlorophylls and carotenoids that are consistent with changes in response to variations in the light regime over time.     

Mass Spectrometry and reverse phase HPLC techniques for the identification of degraded fossil pigments in lake sediments and their application in palaeolimnology

Accurate identification of fossil pigments is essential if they are to be used as biomarker compounds in palaeolimnological studies. In recent years High Performance Liquid Chromatography (HPLC) has greatly enhanced the efficiency with which fossil pigments can be characterised and quantified. Using HPLC, undegraded pigments are typically identified through retention times, absorbance spectra and co-chromatography with authentic reference standards. However, lake sediments may also contain degraded pigments for which there are often no standards, and which may be difficult to identify using HPLC alone. In this study, we submitted HPLC fractions of fossil pigments and pigment derivatives collected from a meromictic lake in south west Tasmania, to a combination of Mass Spectrometry (MS) techniques including Electron Impact (EI) and static Liquid Secondary Ion MS (LSIMS) to identify their molecular ion characteristics and organic chemical composition. Mass Spectrometry permitted the detection of specific mass ions which were used to verify the identity of pigments and their derivatives. These included five carotenoids, chlorophyll a and derivatives, three previously described bacteriochlorophyll c derivatives with molecular weights of 770, 784, and 802, and two undescribed derivatives of bacteriochlorophyll c with molecular weights of 766 and 788. With these improved identifications we speculate on the pathways and modes of pigment degradation in the lake and asses the value of the degraded pigments as biomarkers. The use of MS permitted the identification of a greater number of signature pigments of algal and bacterial communities thus increasing the palaeolimnological value of the sediments. These methods are best applied in fossil pigment studies where there are a large number of unknown pigments and pigment degradation products, and where there are no authentic standards for co-chromatography. Practical suggestions for pigment MS are included in the discussion.     

The potential of using LiDAR and color-infrared aerial imagery for palustrine wetland typology and change

Wetlands are dynamic landscapes and their spatial extent and types can change over time. Mapping wetland locations, types, and monitoring wetland typological changes have important ecological significance. The National Wetlands Inventory data suffer from two problems: the omission error that some wetlands are not mapped, and the out-of-date wetland types in many counties of the United States. To address these two problems, we proposed an automatic wetland classification model for newly mapped (or existing) wetland polygons lacking typological information. The research goals in this study were (1) to develop a nonparametric and automatic rule-based model to assign wetland types to palustrine wetlands using high-resolution remotely sensed data and (2) to quantify wetland typological changes based on the wetland types obtained from the previous step. The model is a direct application of the Cowardin et al. (1979) wetland classification system without modification. The input information for the proposed model includes Light Detection and Ranging (LiDAR)-derived vegetation height and color infrared aerial imagery-derived vegetation spectral information. We tested the model for the palustrine wetlands in Horry County, SC, and analyzed 29,090 palustrine wetland polygons (101,427 ha). The model achieved an overall agreement of 87% for wetland-type classification and showed the dynamics of wetland typological changes. This nonparametric model can be easily applied to other areas where wetland inventory needs updating.     

Lode–gold mineralization in the Tanami region, northern Australia

The Tanami region of northern Australia has emerged over the last two decades as the largest gold-producing region in the Northern Territory. Gold is hosted by epigenetic quartz veins in sedimentary and mafic rocks, and by sulfide-rich replacement zones within iron formation. Although limited, geochronological data suggest that most mineralization occurred at about 1,805–1,790 Ma, during a period of extensive granite intrusion, although structural relationships suggest that some deposits predate this period. There are three main goldfields in the Tanami region: the Dead Bullock Soak goldfield, which hosts the world-class Callie deposit; The Granites goldfield; and the Tanami goldfield. In the Dead Bullock Soak goldfield, deposits are hosted by carbonaceous siltstone and iron formation where a late (D₅) structural corridor intersects an early F₁ anticlinorium. In The Granites goldfield, deposits are hosted by highly sheared iron formation and are interpreted to predate D₅. The Tanami goldfield consists of a large number of small, mostly basalt-hosted deposits that probably formed at a high structural level during D₅. The D₅ structures that host most deposits formed in a convergent structural regime with σ ₁ oriented between E–W and ENE–WSW. Structures active during D₅ include NE-trending oblique thrust (dextral) faults and ESE-trending (sinistral) faults that curve into N- to NNW-trending reverse faults localized in supracrustal belts between and around granite complexes. Granite intrusions also locally perturbed the stress field, possibly localizing structures and deposits. Forward modeling and preliminary interpretations of reflection seismic data indicate that all faults extend into the mid-crust. In areas characterized by the N- to NW-trending faults, orebodies also tend to be N- to NW-trending, localized in dilational jogs or in fractured, competent rock units. In areas characterized by ESE-trending faults, the orebodies and veins tend to strike broadly east at an angle consistent with tensional fractures opened during E–W- to ENE–WSW-directed transpression. Many of these deposits are hosted by reactive rock units such as carbonaceous siltstone and iron formation. Ore deposition occurred at depths ranging from 1.5 to 11 km from generally low to moderate salinity carbonic fluids with temperatures from 200 to 430°C, similar to lode–gold fluids elsewhere in the world. These fluids are interpreted as the product of metamorphic dewatering caused by enhanced heat flow, although it is also possible that the fluids were derived from coeval granites. Lead isotope data suggest that lead in the ore fluids had multiple sources. Hydrogen and oxygen isotope data are consistent with both metamorphic and magmatic origins for ore fluids. Gold deposition is interpreted to be caused by fluid unmixing and sulfidation of host rocks. Fluid unmixing is caused by three different processes: (1) CO₂ unmixing caused by interaction of ore fluids with carbonaceous siltstone; (2) depressurization caused by pressure cycling in shear zones; and (3) boiling as ore fluids move to shallow levels. Deposits in the Tanami region may illustrate the continuum model of lode–gold deposition suggested by Groves (Mineralium Deposita 28:366–374, 1993) for Archean districts.     

Stratigraphic hierarchy and three-dimensional evolution of an exhumed submarine slope channel system

Submarine slope channel systems have complicated three-dimensional geometries and facies distributions, which are challenging to resolve using subsurface data. Outcrop analogues can provide sub-seismic-scale detail, although most exhumed systems only afford two-dimensional constraints on the depositional architecture. A rare example of an accessible fine-grained slope channel complex set situated in a tectonically quiescent basin that offers seismic-scale, down-dip and across-strike exposures is the Klein Hangklip area, Tanqua-Karoo Basin, South Africa. This study investigates the three-dimensional architecture of this channel complex set to characterise the stratigraphic evolution of a submarine channel-fill and the implications this has for both sediment transport to the deep-oceans and reservoir quality distribution. Correlated sedimentary logs and mapping of key surfaces across a 3 km² area reveal that: (i) the oldest channel elements in channel complexes infill relatively deep channel cuts and have low aspect-ratios. Later channel elements are bound by comparatively flat erosion surfaces and have high aspect-ratios; (ii) facies changes across depositional strike are consistent and predictable; conversely, facies change in successive down depositional dip positions indicating longitudinal variability in depositional processes; (iii) stratigraphic architecture is consistent and predictable at seismic-scale both down-dip and across-strike in three-dimensions; (iv) channel-base-deposits exhibit spatial heterogeneity on one to hundreds of metres length-scales, which can inhibit accurate recognition and interpretations drawn from one-dimensional or limited two-dimensional datasets; and (v) channel-base-deposit character is linked to sediment bypass magnitude and longevity, which suggests that time-partitioning is biased towards conduit excavation and maintenance rather than the fill-phase. The data provide insights into the stratigraphic evolution and architecture of slope channel-fills on fine-grained continental margins and can be utilised to improve predictions derived from lower resolution and one-dimensional well data.     

Stratigraphic evolution of the upper slope and shelf edge in the Karoo Basin, South Africa

The Permian Ecca Group of the Karoo Basin, South Africa preserves an extensive well-exposed siliciclastic basin floor, slope and shelf-edge delta succession. The Kookfontein Formation includes multiple sedimentary cycles that display clinoform geometries and are interpreted to represent the deposits of a slope to shelf succession. The succession exhibits progradational followed by aggradational stacking of deltaic cycles that is related to a change in shelf-edge trajectory, and lies within two depositional sequences. Sediment was transferred to the slope via overextension of deltas onto and over the shelf edge, resulting in failure and re-adjustment of local slope gradients. The depositional facies and architecture of the Kookfontein Formation record the change from a bypass- to accretion-dominated margin, which is interpreted to reflect a decrease in sediment transport efficiency as the slope gradient decreased, slope length increased and shelf-edge trajectory rose. During this time the delivery system changed from point-sourced basin-floor fans fed by slope channels to starved basin-floor with sand-rich slope clinoforms. This is an example of a progradational margin in which the younger slope system is interpreted to be of a different style to the older slope system that fed the underlying sand-rich basin floor fans.