Hydrographic profiling across the East China sea shelf edge by an underwater sliding vehicle with CTD sensors

Temperature, salinity and density structures were observed on Sept. 23 and 24, 1986 at one vertical section across the East China Sea shelf edge by an advanced type of towed vehicle with CTD sensors which was developed by the Japan Marine Science and Technology Center. The vehicle was towed at a speed of 2.5 m s⁻¹ down to 150 m depth and at intervals of 170–500 m width. The observed profile was 50 km long on Sept. 23 and 70 km long on Sept. 24 along the cross-shelf section. An on-ship acoustic Doppler current profiler was simultaneously used to measure current velocities at depths of 20, 50 and 100 m.Interesting features were noticed. Firstly, there was a vertical displacement of pycnoclines at the lower edge of the surface mixed layer accompanied by vertical inversion of the salinity and temperature in the vicinity of the shelf edge. Pycnoclines were displaced upward by 12 m toward the outer edge on Sept. 23 and by 20 m on Sept. 24. On Sept. 23, the salinity inversion took place in a layer 20 m thick and 8 km wide, whereas the temperature inversion took place in a layer 8 m thick and 1.5 km wide. These vertical inversions were probably generated by vertical shear of tidal currents which was observed by the Doppler current profiler. These results throw light on understanding the vertical mixing process of stratified water on the continental shelf edge. Secondly, an intrusion of the shelf water into the Kuroshio water was observed along pycnoclines below the surface mixed layer 60 to 70 m deep in the Kuroshio region outer break. The measurement was successful in showing a horizontal mixing process of the shelf water and the Kuroshio water which could not be found out by standard CTD observations.     

Benzo(a)pyrene in the sediment of Osaka Bay and Keihin Canal and its estimated sources

Benzo(a)pyrene (BP) in the sediment of Osaka Bay were determined. High concentration was found at two stations near the mouth of Shin-Yodo and off Kobe respectively (0.98g g^–1 dry mud basis, 1.1g g^–1). The concentration decreases regularly from the mouth of the river further into the bay. The other supplemental determination was carried on the sediment and the seawater of Keihin Canal. Notable BP concentration of 89g g^–1 was observed in the sediment beneath the effluent outlet of a gasworks. The BP in the sediment near the ironworks was also considerable, while the BP was relatively less in the sediment beneath the effluent outlet of refineries. These data suggest that coke plants working in gasworks or ironworks may be the larger sources of BP than refineries. The results of Osaka Bay coincide with this hypothesis.Cadmium, lead, copper, zinc, nickel, ignition loss and fine sand content were measured from the same sediment samples of Osaka Bay. Cd, Pb, Cu and ignition loss showed the regular distributions which resemble to BP and accordingly, good correlations with BP. No significant correlations were found between BP and Ni, Zn and fine sand content which showed no regular distributions.     

Microcracks induced in granite spheres by projectile impact at velocities ranging from 2.3 to 3.6 km/s

Summary Projectiles were impacted against granite spheres having a diameter of 15 cm at velocities ranging from 2.3 to 3.6 km/s. One target was fractured into a large core fragment and many shell-like fragments. Major cracks which divide the core fragment and many small shell-like fragments were formed along the caustic surface of the reflected shock waves that originated on the target surface. The shape of the caustic surfaces formed in spherical targets is called a cardioid. The other targets suffered impact cratering. They exhibit planar craters with no consicuous raised rim or depression. Microcrack distributions and microscopic effects of impact loading were observed on these targets. The site of extension fractures corresponds to grain boundaries, cleavage planes of biotite and feldspars, and along pre-existing microcracks. Kink bands of biotite were formed at the restricted regions beneath the center of the craters.     

Biological organic carbon export estimated from the annual carbon budget observed in the surface waters of the western subarctic and subtropical North Pacific Ocean from 2004 to 2013

The annual flux of biologically produced organic carbon from surface waters is equivalent to annual net community production (NCP) at a steady state and equals the export of particulate and dissolved organic carbon (POC and DOC, respectively) to the ocean interior. NCP was estimated from carbon budgets of salinity-normalized dissolved inorganic carbon (nDIC) inventories at two time-series stations in the western subarctic (K2) and subtropical (S1) North Pacific Ocean. By using quasi-monthly biogeochemical observations from 2004 to 2013, monthly mean nDIC inventories were integrated from the surface to the annual maximum mixed layer depth and corrected for changes due to net air–sea CO₂ exchange, net CaCO₃ production, vertical diffusion from the upper thermocline, and horizontal advection. The annual organic carbon flux at K2 (1.49 ± 0.42 mol m^?2 year^?1) was lower than S1 (2.81 ± 0.53 mol m^?2 year^?1) (p < 0.001 based on t test). These fluxes consist of three components: vertically exported POC fluxes (K2: 1.43 mol m^?2 year^?1; S1: 2.49 mol m^?2 year^?1), vertical diffusive DOC fluxes (K2: 0.03 mol m^?2 year^?1; S1: 0.25 mol m^?2 year^?1), and suspended POC fluxes (K2: 0.03 mol m^?2 year^?1; S1: 0.07 mol m^?2 year^?1). The estimated POC export flux at K2 was comparable to the sum of the POC flux observed with drifting sediment traps and active carbon flux exported by migrating zooplankton. The export fluxes at both stations were higher than those reported at other time-series sites (ALOHA, the Bermuda Atlantic Time-series Study, and Ocean Station Papa).     

Comparison of sinking particles in the upper 200 m between subarctic station K2 and subtropical station S1 based on drifting sediment trap experiments

Drifting sediment trap experiments were conducted during various seasons to elucidate the characteristics of particles sinking through the upper 200 m of the water column in the western Pacific at subarctic station K2 and subtropical station S1. The sinking particle flux increased when primary productivity was high at each station, during June–July at K2 and during February at S1. Biogenic opal (Opal) and CaCO₃ were the major components of the fluxes at K2 and S1, respectively. Contrary to the expectation of a high flux at the eutrophic station K2 and low flux at the oligotrophic station S1, the annual average organic carbon fluxes at 100 m were comparable at both stations: 62.7 mg C m^?2 day^?1 at K2 and 56.1 mg C m^?2 day^?1 at S1. The similarity of the fluxes was perhaps a reflection of the unexpectedly high primary production at S1. At K2, the organic carbon export ratio (organic carbon flux/primary productivity) was significantly and negatively correlated with primary production and tended to decrease with depth. The magnitude of the rate of attenuation of the organic carbon flux with depth was larger at S1 than at K2. This rate of attenuation tended to decrease and increase with primary production at K2 and S1, respectively. The explanation for these patterns may be that the flux of labile organic carbon at relatively shallow depths decreased with increasing primary production at K2, and zooplankton grazing pressure increased with increasing primary productivity at S1.     

Stratigraphic records of tsunamis along the Japan Sea,southwest Hokkaido,northern Japan

The stratigraphy of tsunami deposits along the Japan Sea, southwest Hokkaido, northern Japan, reveals tsunami recurrences in this particular area. Sandy tsunami deposits are preserved in small valley plains, whereas gravelly deposits of possible tsunami origin are identified in surficial soils covering a Holocene marine terrace and a slope talus. At least five horizons of tsunami events can be defined in the Okushiri Island, the youngest of which immediately overlies the Ko‐d tephra layer (1640 AD) and was likely formed by the historical Oshima‐Ohshima tsunami in 1741 AD. The four older tsunami deposits, dated using accelerator mass spectrometry ¹⁴C, were formed at around the 12th century, 1.5–1.6, 2.4–2.6, and 2.8–3.1 ka, respectively. Tsunami sand beds of the 1741 AD and circa 12th century events are recognized in the Hiyama District of Hokkaido Island, but the older tsunami deposits are missing. The deposits of these two tsunamis are found together at the same sites and distributed in regions where wave heights of the 1993 tsunami (Hokkaido Nansei‐oki earthquake, Mw = 7.7) were less than 3 m. Thus, the 12th century tsunami waves were possibly generated near the south of Okushiri Island, whereas the 1993 tsunami was generated towards the north of the island. The estimated recurrence intervals of paleotsunamis, 200–1100 years with an average of 500 years, likely represents the recurrence interval of large earthquakes which would have occurred along several active faults offshore of southwest Hokkaido.     

Does heavy oil pollution induce bacterial diseases in Japanese flounder Paralichthys olivaceus?

As basic research for the effect of heavy oil on the fish immune system, in this study, the number of leukocyte was counted in Japanese flounder Paralichthys olivaceus, after exposure to heavy oil at a concentration of 30 g/8 L for 3 days. To compare the numbers of bacteria in the skin mucus between oil-exposed and control fish, viable bacteria were enumerated by counting colony forming unit (CFU). Compared with 5.79 ± 1.88 × 10⁷ leukocytes/mL in the controls, the exposed fish demonstrated higher counts, averaging 1.45 ± 0.45 × 10⁸ cells/mL. The bacterial numbers of control fish were 4.27 ± 3.68 × 10⁴ CFU/g, whereas they were 4.58 ± 1.63 × 10⁵ CFU/g in the exposed fish. The results suggest that immune suppression of the fish occurred due to heavy oil stressor, and bacteria could invade in the mucus, resulting in the increasing leukocyte number to prevent infectious disease.     

Regional-Scale Excess Ar wave in a Barrovian type metamorphic belt, eastern Tibetan Plateau

Laser step heating ⁴⁰Ar/³⁹Ar analysis of biotite and muscovite single crystals from a Barrovian type metamorphic belt in the eastern Tibetan plateau yielded consistent cooling ages of ca. 40 Ma in the sillimanite zone with peak metamorphic temperatures higher than 600°C and discordant ages from 46 to 197 Ma in the zones with lower peak temperatures. Chemical Th‐U‐Total Pb Isochron Method (CHIME) monazite (65 Ma) and sensitive high mass‐resolution ion microprobe (SHRIMP) apatite (67 Ma) dating give the age of peak metamorphism in the sillimanite zone. Moderate amounts of excess Ar shown by biotite grains with ages of 46 to 94 Ma at metamorphic grades up to the high‐grade part of the kyanite zone probably represent incomplete degassing during metamorphism. In contrast, the high‐grade part of the kyanite zone yields biotite ages of 130 to 197 Ma. The spatial distribution of these older ages in the kyanite zone along the sillimanite zone boundary suggests they reflect trapped excess argon that migrated from higher‐grade regions. The most likely source is muscovite that decomposed to form sillimanite. The zone with extreme amounts of excess argon preserves trapped remnants of an ‘excess argon wave’. We suggest this corresponds to the area where biotite cooled below its closure temperature in the presence of an elevated Ar wave. Extreme excess Ar is not recognized in muscovite suggesting that the entrapment of the argon wave by biotite took place when the rocks had cooled down to temperatures lower than the closure temperature of muscovite. The breakdown of phengite during ultrahigh‐pressure (UHP) metamorphism may be a key factor in accounting for the very old apparent ages seen in many UHP metamorphic regions. This is the first documentation of a regional Ar‐wave spatially associated with regional metamorphism. This study also implies that resetting of the Ar isotopic systems in micas can require temperatures up to 600°C; much higher than generally thought.     

A simplified input output relation method using AR model for earthquake wave propagation analysis

This paper introduces a Simplified Input Output Relation Method (SIORM) using multiple-variable autoregression (AR) model which can be used to determine ground wave propagation properties. Using the AR model, a method is developed to establish the basis for the formulation of SIORM. The degree of accuracy of this method is evaluated. SIORM is applied to actual ground acceleration records taken at Minamisuna and Etchujima sites in Japan and its results are discussed in this paper. © 1997 John Wiley & Sons, Ltd.     

Quantitative micro‐X‐ray fluorescence scanning spectroscopy of wet sediment based on the X‐ray absorption and emission theories: Its application to freshwater lake sedimentary sequences

Micro‐X‐ray fluorescence scanning spectroscopy of marine and lake sedimentary sequences can provide detailed palaeoenvironmental records through element intensity proxy data. However, problems with the effects of interstitial pore water on the micro‐X‐ray fluorescence intensities have been pointed out. This is because the X‐ray fluorescence intensities are measured directly at the surfaces of split wet sediment core samples. This study developed a new method for correcting X‐ray fluorescence data to compensate for the effects of pore water using a scanning X‐ray analytical microscope. This involved simultaneous use of micro‐X‐ray fluorescence scanning spectroscopy and an X‐ray transmission detector. To evaluate the interstitial pore water content from the X‐ray transmission intensities, a fine‐grained sediment core retrieved from Lake Baikal (VER99‐G12) was used to prepare resin‐embedded samples with smooth surfaces and uniform thickness. Simple linear regression between the linear absorption coefficients of the samples and their porosity, based on the Lambert–Beer law, enabled calculation of the interstitial pore spaces and their resin content with high reproducibility. The X‐ray fluorescence intensities of resin‐embedded samples were reduced compared with those of dry sediment samples because of: (i) the X‐ray fluorescence absorption of resin within sediment; and (ii) the sediment dilution effects by resin. An improved micro‐X‐ray fluorescence correction equation based on X‐ray fluorescence emission theory considers the instrument's sensitivity to each element, which provides a reasonable explanation of these two effects. The resin‐corrected X‐ray fluorescence intensity was then successfully converted to elemental concentrations using simple linear regression between the data from micro‐X‐ray fluorescence scanning spectroscopy and from the conventional analyzer. In particular, the calculated concentration of SiO₂ over the depth of the core, reflecting diatom/biogenic silica concentration, was significantly changed by the calibrations, from a progressively decreasing trend to an increasing trend towards the top of the core.