Relationships between volcano distribution, crustal structure, and P-wave tomography: an example from the Abu Monogenetic Volcano Group, SW Japan

Achieving an understanding of the nature of monogenetic volcanic fields depends on identification of the spatial and temporal patterns of volcanism in these fields, and their relationships to structures mapped in the shallow crust and inferred in the deep crust and mantle through interpretation of geophysical data. We investigate the spatial and temporal distributions of volcanism in the Abu Monogenetic Volcano Group, Southwest Japan, and compare these distributions to fault and seismic data in the brittle crust, and P-wave tomography of the crust and upper mantle. Essential characteristics of the volcano distribution are extracted by a nonparametric kernel method using an algorithm to estimate anisotropic bandwidth. Overall, E-W elongate smooth modes in spatial density are identified that are consistent with the spatial extent of P-wave velocity anomalies in the lower crust and upper mantle, supporting the idea that the spatial density map of volcanic vents reflects the geometry of a mantle diapir. While the number of basalt eruptions decreased after 0.2 Ma, andesite eruptions increased and overall volume eruption rate is approximately steady-state. Estimated basalt supply to the lower crust is also constant. This observation and the spatial distribution of volcanic vents suggest stability of magma productivity and essentially constant two-dimensional size of the source mantle diapir since 0.46 Ma.     

Chemical characteristics of chromian spinel in plutonic rocks: Implications for deep magma processes and discrimination of tectonic setting

We summarize chemical characteristics of chromian spinels from ultramafic to mafic plutonic rocks (lherzolites, harzburgites, dunites, wehrlites, troctolites, olivine gabbros) with regard to three tectonic settings (mid‐ocean ridge, arc, oceanic hotspot). The chemical range of spinels is distinguishable between the three settings in terms of Cr# (= Cr/(Cr + Al) atomic ratio) and Ti content. The relationships are almost parallel with those of chromian spinels in volcanic rocks, but the Ti content is slightly lower in plutonics than in volcanics at a given tectonic environment. The Cr# of spinels in plutonic rocks is highly diverse; its ranges overlap between the three settings, but extend to higher values (up to 0.8) in arc and oceanic hotspot environments. The Ti content of spinels in plutonics increases, for a given lithology, from the arc to oceanic hotspot settings by mid‐ocean ridge on average. This chemical diversity is consistent with that of erupted magmas from the three settings. If we systematically know the chemistry of chromian spinels from a series of plutonic rocks, we can estimate their tectonic environments of formation. The spinel chemistry is especially useful in dunitic rocks, in which chromian spinel is the only discriminating mineral. Applying this, discordant dunites cutting mantle peridotites were possibly precipitated from arc‐related magmas in the Oman ophiolite, and from an intraplate tholeiite in the Lizard ophiolite, Cornwall.     

Bioaccumulation of nitroarenes in bivalves at Osaka Bay, Japan

This paper reports for the first time the detection and occurrence of nitroarenes (NPAHs) in marine organisms. Mussels and oysters collected from Osaka Bay, Japan, had total NPAHs concentrations that ranged from 2380 to 24,688 pg/g dry and 2672 to 25,961 pg/g dry, respectively. Relatively higher concentrations were detected in sampling sites located near the central district and suburbs of Osaka City implying that the most probable sources of NPAHs in the two bivalves are exhaust gases and smokes emitted by automobiles and industrial plants. Bivalves had relatively higher residues of 1-nitronaphthalene, 2-nitronaphthalene, 3-nitrophenanthrene, and 9-nitrophenanthrenes. Residues of 2-nitrofluorene, 1-nitropyrene, 4-nitropyrenes, and 6-nitrochrysene were much lower compared to nitronaphthalenes and nitrophenanthrenes. Inter-species differences was only observed for 2-nitronaphthalene with oysters exhibiting significantly higher residues than mussels.     

10Be in marine sediments

The depth profile of the long-lived radionuclide¹⁰Be in a marine sediment recovered in the vicinity of the Samoan Islands has been precisely assayed with a highly sensitive needle-type gas counter. The obtained irregular pattern of¹⁰Be concentrations with depths ranging from 4.7 to 0.3 dpm/kg dry sediment is interpreted as being due to dilution of¹⁰Be by volcanic eruptions in the past.     

Microseismicity Induced by Heavy Rainfall Around Flooded Vertical Ore Veins

—?Microseismicity (M?M?M?M??6 were also monitored at a crustal movement monitoring station located several hundred meters from the veins. It was found that the opening of the vertical ore veins primary led to significant strain and tilt, but not to seismicity, because the delay and the longer duration of the seismicity were significant. Most seismic events involve thrusting mechanisms that are consistent with the present stress state of E-W-oriented tectonic compression, but are not consistent with the opening of the deepest ore vein. Interstingly, all the events within a few months of the heavy rainfall occurred near the faults that offset the deepest ore veins, wheareas all those events located away from the deepest ore veins occurred many months after the heavy rainfall. Consequently, the delayed diffusion of water appears to have played a dominant role in reducing rock strength, which led to seismicity in the Ikuno mine.     

Fractal properties of medium and seismoelectric phenomena

Electrokinetic phenomena in a water-porous medium with a fractal structure above percolation threshold are theoretically investigated. Fracture zone with space-variable porosity is considered as a model of an earthquake hypocenter zone in which the electrokinetic current results from fluid filtration in a fractal pore network. A critical exponent of the streaming potential coefficient is found to depend on both the transport critical exponent and correlation length critical exponent. In this model, logarithmic dependence of electric field amplitude E on the earthquake magnitude M is derived which is compatible with the one observed by the VAN group. Without fractal properties, this form of dependence contradicts the empirical data. The electromagnetic field far from the hypocenter is calculated, which leads to the prediction of weak magnetic field variations. To explain the observed amplitude of VAN's Seismic Electric Signals (SES), the electric source must be at a distance of about 10 km from the registration point if the medium is homogeneous. Therefore, some conductive channel(s) are needed to explain the long distance selective SES transmission.     

Distributions of polycyclic aromatic hydrocarbons and alkylated polycyclic aromatic hydrocarbons in Osaka Bay,Japan

Contaminations in sediments by polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs were investigated at 44 sites in Osaka Bay, Japan. Concentrations of total PAHs and alkylated PAHs were in the range 6.40–7800 ng/g dry weights and 13.7–1700 ng/g dry weights, respectively. The PAH concentrations tended to be higher along the shoreline in the vicinities of big ports, industrialized areas, and densely populated regions such as the cities of Osaka and Kobe. The major sources appeared to be pyrogenic or both pyrogenic and petrogenic at most of the sites. PAH concentrations were remarkably high at a site near Kobe, where the concentrations of dibenzo(a,h)anthracene and benzo(g,h,i)perylene exceeded the effects-range-medium concentration and eight PAHs were above the corresponding effects-range-low concentrations. Those PAHs may have been derived from the great fire associated with the large earthquake in 1995.     

Numerical study of the oxidation process of dimethylsulfide in the marine atmosphere

A box model, involving simple heterogeneous reaction processes associated with the production of non-sea-salt sulfate (nss-SO ₄ ^2– ) particles, is used to investigate the oxidation processes of dimethylsulfide (DMS or CH₃SCH₃) in the marine atmosphere. The model is applied to chemical reactions in the atmospheric surface mixing layer, at intervals of 15 degrees latitude between 60° N and 60° S. Given that the addition reaction of the hydroxyl radical (OH) to the sulfur atom in the DMS molecule is faster at lower temperature than at higher temperature and that it is the predominant pathway for the production of methanesulfonic acid (MSA or CH₃SO₃H), the results can well explain both the increasing tendency of the molar ratio of MSA to nss-SO ₄ ^2– toward higher latitudes and the uniform distribution with latitude of sulfur dioxide (SO₂). The predicted production rate of MSA increases with increasing latitude due to the elevated rate constant of the addition reaction at lower temperature. Since latitudinal distributions of OH concentration and DMS reaction rate with OH are opposite, a uniform production rate of SO₂ is realized over the globe. The primary sink of DMS in unpolluted air is caused by the reaction with OH. Reaction of DMS with the nitrate radical (NO₃) also reduces DMS concentration but it is less important compared with that of OH. Concentrations of SO₂, MSA, and nss-SO ₄ ^2– are almost independent of NO _x concentration and radiation field. If dimethylsulfoxide (DMSO or CH₃S(O)CH₃) is produced by the addition reaction and further converted to sulfuric acid (H₂SO₄) in an aqueous solution of cloud droplets, the oxidation process of DMSO might be important for the production of aerosol particles containing nss-SO ₄ ^2– at high latitudes.