Gas was sampled regionally, including by drilling into faults, in the South Kanto gas-field around Tokyo Bay, Japan. Gas samples were collected from cores in a gas sampling container immediately after drilling. A value of δ
13C
1 = −44.3‰ was obtained for gas in the container and δ
13C
1 = −36.3‰ for seeping gas in a fault zone. However, typical CH
4 in this dissolved-in-water gas-field is mainly depleted in
13C, and δ
13C
1 values range from −66‰ to −68‰ owing to microbial degradation of organic material.
13C-rich CH
4 is so far uncommon in the South Kanto gas-field. Seepages were observed from the surface along the north–south fault zone. The natural gas is stored below the sandstone layer by impermeable mudstone underlying the boundary at a depth of 30 m. Gas seepages were not observed below a depth of 40 m. Gas rises along the fault zone dissolved-in-groundwater up to the shallow region and then separates from the groundwater.
13C-rich CH
4 (adsorbed CH
4) was found to have desorbed from drilled mudstone core samples taken at depths of 1400–1900 m in the main gas-production strata. Similarly,
13C-rich CH
4 was found in black shale overlying the oceanic crust forming part of a sedimentary accretionary prism underling the Tokyo region. It also appears in the spring-water of spa wells, originating at a depth of 1200–1500 m along a tectonic line. Methane generated by microbial degradation of organic material through CO
2 reduction in the South Kanto gas-field mainly originates as biogenic gas mixed with a small amount of
13C-rich CH
4, derived from thermogenic gas without oil components in strata. It is assumed that
12C-rich CH
4 is easily detached from core or pore water through gas production, whereas
13C-rich CH
4 is strongly adsorbed on the surfaces of particles. The
13C-rich CH
4 rises along the major tectonic line or up the 50 m wide normal fault zone from relatively deep sources in the Kanto region.
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