Nutrient enrichments and phytoplankton growth in the surface waters of the Louisiana Bight

Nitrate concentrations have increased twofold in the Mississippi River during the past three decades. The increased nitrogen loading to the Louisiana shelf has been postulated as a factor leading to eutrophication and the subsequent development of hypoxia west of the Mississippi River delta. While ratios of nitrogen:phosphorus and nitrogen:silica are relatively high in surface waters on the western Louisiana shelf, nitrogen has been posed as the ‘limiting’ nutrient in this region. Bioassays were performed with nutrient additions to surface waters collected from the Louisiana shelf to examine the potential for specific nutrient limitation. Experiments were conducted in March and September 1991, and May 1992. The growth responses of natural and cultured phytoplankton populations were determined by measuring the time course of in vivo and 3-(3,4 dichlorophenyl)-1, 1-dimethylurea (DCMU)-induced fluorescence, as well as initial and final chlorophylla concentrations. The results suggest that phosphate and silicate potentially limit phytoplankton growth during the winter-spring, particularly at low salinities. In late summer, in contrast, nitrogen limitation may be prominent at higher salinities.     

Quantification of adamantane in organic media via infrared attenuated total reflection spectroscopy

In the present study, the quantitative determination of the diamondoid compound adamantane in organic solvents via infrared attenuated total reflection (IR-ATR) spectroscopy at unmodified waveguide surfaces was established. Limits of detection (LOD) and quantification (LOQ) of adamantane in dichloromethane, hexane and carbon tetrachloride were determined. Quantitative IR-ATR measurements additionally facilitated the determination of adamantane solubility limit in dichloromethane, hexane and carbon tetrachloride. The developed analytical strategy further enabled the successful detection and quantification of adamantane in crude oil matrices. Consequently, IR-ATR spectroscopy provides a promising strategy for on ship and in situ diamondoid analysis in harsh real world environments.     

Prosperity and the New Economy in Canada’s major city regions

Canada’s three large city regions—Montréal, Toronto and Vancouver—have been relatively successful in retaining their Manufacturing bases, while at the same time adding substantial numbers of New Economy job opportunities. Deindustrialization appears to have occurred primarily in the Montréal CMA (Census Metropolitan Area) and in some smaller communities where motor vehicle manufacturing was significant. Growth in New Economy jobs has occurred in the larger CMAs; the smaller urban areas have had little success in attracting these jobs. For the most part, these trends appear to be path dependent: prosperous communities with substantial proportions of New Economy jobs are likely to remain prosperous and to attract more such jobs. The lack of significant correlation between Economic Health and the presence of immigrants, same sex couples, performing and visual artists suggests that local economic development strategies based on these factors may have limited success.     

On Krugman's model of economic geography

This essay evaluates the evolution of Paul Krugman's ideas about economic geography between 1989 and 1996, focusing on the scope and intention of his work. While Krugman's geographical writings have acknowledged diverse research traditions, he has increasingly focused his efforts on formal spatial models that embody the methods of mainstream economic modeling. This emphasis reflects Krugman's view that formal modeling holds the most promise for understanding spatial aspects of urbanization. Krugman's interventions into economic geography have in turn allowed him to develop and articulate his own view of the future of social science: that is, the explanation of self-organizing behaviour should be the focal point of research, and formal modelling is the key means of advancing this agenda.     

Line-of-sight magnetic flux imbalances caused by electric currents

Several physical and observational effects may contribute to the significant imbalances of magnetic flux that are often observed in active regions. We consider an effect not previously treated: the influence of electric currents in the photosphere. Electric currents can cause a line-of-sight flux imbalance because of the directionality of the magnetic field they produce. Currents associated with magnetic flux tubes produce larger imbalances than do smoothly-varying distributions of flux and current. We estimate the magnitude of this effect for current densities, total currents, and magnetic geometry consistent with observations. The expected imbalances lie approximately in the range 0–15%, depending on the character of the current-carrying fields and the angle from which they are viewed. Observationally, current-induced flux imbalances could be indicated by a statistical dependence of the imbalance on angular distance from disk center. A general study of magnetic flux balance in active regions is needed to determine the relative importance of other - probably larger -effects such as dilute flux (too weak to measure or rendered invisible by radiative transfer effects), merging with weak background fields, and long-range connections between active regions.Operated for the National Science Foundation by the Association of Universities for Research in Astronomy.     

The nature of the sunspot phenomenon

This paper points out the basic relation between the conversion of thermal energy into convective fluid motion (Alfvén waves when a strong vertical magnetic field is present) and the convective transport of thermal energy. It is shown that heat transport necessarily accompanies convective driving of fluid motion. Convective motions restricted to a layer whose thickness is a small fraction of the local scale height can divert no more than the same fraction of the energy into Alfvén waves. But if the convecting layer extends over many scale heights, then the convective forces may convert more energy into fluid motion than they transport. Hence the creation of a cool sunspot requires convection extending coherently over several scale heights, at least 500 km. This requirement is basically just the familiar thermodynamic efficiency of an ideal heat engine. The calculations establish that convection need not be much less efficient than the ideal.     

Eclipse of radio emission on 7 March, 1970 at 10 cm wavelength from the active region associated with McMath plage 10 618

Radio emission of 10 cm from the whole disk was monitored during the eclipse of 7 March, 1970 by the Aerospace San Fernando Observatory and AFCRL Sagamore Hill Solar Radio Observatory. For both, the active region associated with sunspot 17 774, McMath region 10 618, was occulted. At Sagamore Hill the entire region was occulted. At SFO only the southern half of the sunspot group and the hydrogen plage southeast of the group was occulted. This region produced an importance class 1N flare and 10 cm burst beginning at 1601 UT and was enhanced about 15 flux units above the mean value of 190 units at onset.The Sagamore Hill data indicate the region was about 3.8 and contributed about 0.21 of the total radiation from the disk. The SFO data gave about 5.4 for the size of the southern half of the region and showed that about 0.20 of the total radiation came from there. Radiation came primarily from the hydrogen plage southeast of the major spot of the group. The hydrogen plage northwest of the group did not contribute significantly. Although the small flare occurred in this region, it did not contribute more than 0.04 of the total (0.20 of the active region) at occultation of region 10 618.     

The future of solar physics

The future of solar physics is founded on the existing fundamental unsolved problems in stellar physics. Thus, for instance, the physics of stellar interiors has been called into serious question by the very low-measured neutrino flux. The ⁷¹Ga neutrino detection experiment is the next step in unravelling this mystery. If that experiment should find the expected neutrino flux from the basic p-p reaction in the Sun, then astrophysics is in a difficult situation, because the most likely explanation for the low neutrino flux found in the ³⁷Cl experiment would be an error in our calculation of the opacity or an error in our understanding of the elemental abundances in stellar interiors, with serious implications for present ideas on stellar structure and the age of the galaxy.The new methods of helioseismology, for probing the interior of the Sun, have already found the primordial rapid rotation of the central core. The forthcoming world-wide helioseismology observing network will permit fuller exploitation of the method, promising to provide the first direct sounding of the interior of a star, hitherto known to us only through theoretical inference and the discrepant neutrino emission.The activity of all stars involves much the same phenomena as make up the activity of the Sun. The effects are too complex, and too foreign to the familiar dynamics in the terrestrial laboratory, to be deciphered by theoretical effort alone. It has become clear through the observational and theoretical work of the past decade or two that much of the essential dynamics of the activity of the atmosphere takes place on scales of the order of 10² km. Thus, an essential step in developing the physics of stellar activity will be the Solar Optical Telescope (presently planned by NASA to be launched early in the next decade) to permit a microscopic examination of the surface of the Sun to study the source of the action. The activity and X-ray emission of other stars depend on much the same effects, so that the study is essential to determining the significance of the X-ray emission from other stars.This work was supported in part by the National Aeronautics and Space Administration under grant NGL-14-001-001.     

Anthropogenic trace metals in sediment and settling particulate matter on a high-energy continental shelf (Sydney,Australia)

The anthropogenic contribution of trace metals to settling particulate matter (SPM) and surficial sediments was determined on the high-energy continental shelf adjacent to Sydney, Australia. Settling particulate matter and surficial sediment was collected in the vicinity of a major sewage outfall and at five control sites on the middle shelf (80-100 m water depth). Sediment traps were deployed on 10 occasions for up to 2 weeks during the summer and winter of 1995 and SPM was analyzed for Ag, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn. Cobalt, Fe, Mn and Ni act conservatively in SPM and in sediments regionally and are used as normalizing elements to determine anthropogenic enrichment. Surficial sediments and SPM are enriched in Ag, Cr, Cu, Pb and Zn near a major ocean outfall and at four of the five control sites, although sewage particles contribute < 5% of trace metals in the total sample. Silver is the most sensitive trace metal tracer for establishing the presence of sewage particulate matter. Sewage particulate matter flux near the outfall was estimated using a two end-member mixing model and is below 0.5 g m(-2) day(-1) during all deployment periods. The mean sewage particulate matter flux at sampling locations 30 km and 60 km north of the outfall are <0.13 g m(-2) day(-1) and <0.01 g m(-2) day(-1), respectively, indicating an efficient dispersal of anthropogenic material on this high energy continental shelf.