A study of the 2.5–25 μm spectrum of H2O ice

We present new absorbance spectra of the 3-, 6- and 12-μm features of amorphous and crystalline H₂O ice obtained between 10 and 140 K. Three sets of measurements have been made. In series I, the ice film was initially deposited on to a CsI substrate at 10 K and successive spectra were then obtained at intermediate temperatures as the ice was warmed up to 140 K. The second set, series II, comprises spectra for ice films deposited and measured at temperatures between 10 and 140 K. In the third set of measurements, series III, spectra were obtained for an ice film deposited at 140 K and then at intermediate temperatures as the film was cooled down to 10 K. The series I and II results show that the ice undergoes an amorphous-to-crystalline phase transition in the 110–120 K range. The 3- and 12-μm bands have similar trends in full width at half-maximum (FWHM) and opposite peak wavelength shifts. The temperature behaviour of the 6-μm band is different, as no clear phase transition temperature can be discerned from its FWHM and peak wavelength position data. In the series III spectra the peak wavelength positions and FWHM of the three bands remain relatively constant, thus demonstrating the stability of the crystalline phase against thermal cycling. A comparison between the laboratory results and astronomical spectra suggests that the identification of the librational band of H₂O ice in OH 231.8 + 4.2 may be incorrect.     

Geomorphological evolution and sediment stratigraphy of numerically simulated alluvial fans

When a sediment laden river reaches a flat basin area the coarse fraction of their sediment load is deposited in a cone shaped structure called an alluvial fan. In this article we used the State Space Soil Production and Assessment Model (SSSPAM) coupled landform–soilscape evolution model to simulate the development of alluvial fans in two- and three-dimensional landforms. In SSSPAM the physical processes of erosion and armouring, soil weathering and sediment deposition were modelled using state-space matrices, in both two and three dimensions. The results of the two-dimensional fan showed that the fan grew vertically and laterally keeping a concave up long profile. It also showed a downstream fining of the sediments along the fan profile. Both of these observations are in agreement with available literature concerning natural and experimental fan formations. Simulations with the three-dimensional landform produced a fan with a semicircular shape with concave up long profiles and concave down cross profiles which is typical for fans found in nature and ones developed in laboratory conditions. During the simulation the main channel which brings sediment to the fan structure changed its position constantly leading to the semicircular shape of the fan. This behaviour is similar to the autogenic process of ‘fanhead trenching’ which is the major mechanism of sediment redistribution while the fan is developing. The three-dimensional fan simulation also exhibited the downstream fining of sediments from the fan apex to the peripheries. Further, the simulated fan also developed complex internal sediment stratification which is modelled by SSSPAM. Currently such complex sediment stratification is thought to be a result of allogenic processes. However, this simulation shows that, such complex internal sediment structures can develop through autogenic processes as well. © 2020 John Wiley & Sons, Ltd.     

Analysis and survival of amino acids in Martian regolith analogs

Abstract— We have investigated the native amino acid composition of two analogs of Martian soil, JSC Mars‐1 and Salten Skov. A Mars simulation chamber has been built and used to expose samples of these analogs to temperature and lighting conditions similar to those found at low latitudes on the Martian surface. The effects of the simulated conditions have been examined using high‐performance liquid chromatography (HPLC). Exposure to energetic ultraviolet (UV) light in vacuum appears to cause a modest increase in the concentration of certain amino acids within the materials, which is interpreted as resulting from the degradation of microorganisms. The influence of low temperatures shows that the accretion of condensed water on the soils leads to the destruction of amino acids, supporting the idea that reactive chemical processes involving H₂O are at work within the Martian soil. We discuss the influence of UV radiation, low temperatures, and gaseous CO₂ on the intrinsic amino acid composition of Martian soil analogs and describe, with the help of a simple model, how these studies fit within the framework of life detection on Mars and the practical tasks of choosing and using Martian regolith analogs in planetary research.     

Ferruginous thermal spring complexes, northwest Tasmania: evidence that far-field stresses acting on a fracture mesh can open and maintain vertical flow in carbonate terrains

Far-field stress changes in the southern Australian plate since 5 Ma have produced significant areas of uplift and seismicity. In northwest Tasmania, there is evidence that this stress reorientation to maximum horizontal NW?CSE stress has influenced meteoric-derived thermal (15?C20°C) discharge patterns of confined karstic aquifers, by placing pre-existing NW-trending faults/fractures into a dilated state or a critically stressed state. Previous studies have shown that spring discharge has operated continuously for at least 65,000 years, and has transported large volumes of solutes to the surface to be deposited as mounds of calcite-goethite-silica up to 7 m high. The thermal spring chemistry at one site, Mella, is consistent with descent to at least 1.2?C1.5 km, although the hinterland within 50 km is less than 500 m elevation. Thermal spring chemistry is consistent with most of the deep water?Crock interaction occurring in low-strontium Smithton Dolomite. While some of this water is discharged at springs, some instead intersects shallow zones of NE-fracture-controlled rock (2?×?4 km in area) with karstic permeability where, although confined and subject to a NE-directed hydraulic gradient, it circulates and cools to ambient temperature, with only minor mixing with other groundwaters.     

Influence of regional structure on the development and quality of the Upper Elkhorn no. 2 coal bed, eastern Kentucky

The Upper Elkhorn No. 2 coal bed (Middle Pennsylvanian Breathitt Formation) in eastern Kentucky exhibits thickness and coal quality trends which suggest that peat deposition was contemporaneous with tectonism. The coal thickens and has high vitrinite and low ash and sulfur content the Belfry anticline in Pike Country. T in the vicinity of the Floyd Country channel, a basement trough. In both cases other Pennsylvanian coals exhibit similar trends, suggesting that the penecontemporaneous tectonism persisted at least through a portion of the Carboniferous.     

Tectonic significance of syn-rift sediment packages across the Gabon-Cabinda continental margin

The tectonic development of a continental margin is recorded in the stratigraphic successions preserved along and across the margin in terms of stratal relationships (e.g., onlap, downlap, truncation), lithofacies, biostratigraphy, and paleo-water depths. By using these observations coupled to a kinematic and flexural model for the deformation of the lithosphere, we have elucidated the tectonic significance of the preserved stratigraphy that comprises the Gabon-Cabinda margin of west Africa. Two hinge zones, an Eastern and Atlantic, formed along the Gabon-Cabinda margin in response to three discrete extensional events occuring from Berriasian to Aptian time. The Eastern hinge zone demarcates the eastern limit of a broadly distributed Berriasian extension that resulted in the formation of deep anoxic, lacustrine systems as evidenced by the silts and shales of the Sialivakou and lower Djeno Formations and the regressive packages of the upper Djeno Formation. Approximately 1.5 to 2 km of asymmetric footwall uplift was induced across the Eastern hinge zone in response to the mechanical unloading of the lithosphere during this first phase of rifting. In contrast, the Atlantic hinge, located approximately 90 km west of the Eastern hinge, marks the eastern limit of a second phase of extension that began in the Hauterivian. Footwall uplift and rotation exposed earlier syn-rift and pre-rift sediments to at least wavebase causing varying amounts of erosional truncation across the Atlantic hinge zone along much of the Gabon-Cabinda margins. We interpret the thickness variations of reworked clastic sediment of this age (e.g. the Melania Formation) between the hinge zones as indicative of variations in the degree of uplift and erosional truncation of the Atlantic hinge. For example, the absence of Melania Formation across the Congo margin implies that uplift of the Atlantic hinge was relatively minor compared to that across the Cabinda and Gabon margins, the latter being characterized by significant thicknesses of Melania Formation (or equivalent). Material eroded from the Cabinda and Gabon Atlantic hinge zone may in part account for the thick wedge of sediment deposited seaward of the Gabon-Cabinda Atlantic hinge (the Erva Formation). Our modelling suggests that this wedge of reworked elastics represents deposition by along-axis gravity flows within a deep water (≈2 km) environment. A third and final phase of extension in the late Barremian-early Aptian was responsible for breaching the continental lithosphere to form the ocean/continent boundary and thus the installation of open marine conditions. Elsewhere, the environments will tend to be marginal marine to brackish, depending on the efficiency of the Atlantic hinge zone to act as a barrier to marine enchroachment. This third rift phase reactivated both the Eastern and Atlantic hinge0zones thereby creating accomodation for the Marnes Noires Formation (and equivalent) source rock deposition between the hinges and the Falcão source rock equivalent seaward of the Atlantic hinge. Two possible scenarios exist for the lateral distribution of the Marnes Noires Formation. If the reactivated rift flank topography across the Atlantic hinge was significant, then sedimentation would be restricted between the hinge zones within discrete lacustrine settings (e.g., Congo margin). Alternatively, if hinge zone uplift was relatively minor, then a coral-rimmed archipelago may have developed parallel to the margin with restricted communication across the Atlantic hinge zone (e.g., Cabinda margin). In this latter scenario, dilution of the Marnes Noires source rocks by terrigenous input from the eroding Atlantic hinge zone should be relatively minor thereby enhancing source rock quality. Furthermore, potential marine upwelling outboard of the Atlantic hinge zone is likely the cause for the production and accumulation of organic-rich material associated with the Falcão source rock of the Kwanza basin. By late Aptian time, the remaining accomodation between the hinge zones was partially filled by across- and along-axis prograding deltaic systems of the Argilles Vertes and Tchibota Formations. The progradation and interaction of the Argilles Vertes depositional lobes resulted in the formation of residual paleo-relief. Subsequent marine incursions and flooding of this paleo-relief led to the development of basal conglomerates (the Chela ‘lag’ unconformity) grading upward into fine-grained sands and evaporites. Consequently, an inverse relationship should exist betweeb evaporite thickness (in particular, the lower members) and the thickness of the underlying Argilles Vertes and Tchibota Formations. Variations in Loeme evaporite thickness is a consequence of stratigraphic and structural control with salt instability influencing local variability.Our modelling suggests the occurrence of two distinct evaporite sequences on the Congo margin, an earlier evaporite deposited seaward (west) of the Atlantic hinge during the second and third rift phases and the late Aptian Loeme Formation deposited between the hinge zones. An evaporite sequence seaward of the Atlantic hinge is inferred on the basis of extensive diapirs and salt tectonic structures observed in seismic data. In order to match the distribution and thickness of the observed post-salt stratigraphy across the basin, however, we require large paleowater depths west of the Atlantic hinge during the later Aptian. The existence of large paleowater depths precludes the formation of thick evaporite sequences within the outer basin. Consequently, we propose that the evaporites seaward of the Atlantic hinge were formed during the syn-rift development of the margin and are not contemporaneous with the post-rift Loeme salts deposited between the hinge zones. This double salt hypothesis is consistent with observations from the conjugate Brazilian margin.     

Demethylated hopanes in crude oils and their applications in petroleum geochemistry

Analyses of some Australian crude oils show that many contain varying concentrations of A/ B-ring demethylated hopanes. These range from C₂₆ to C₃₄ and have been identified from their retention times and mass spectral data as 17α(H)-25-norhopanes. Comparison of hopane and demethylated hopane concentrations and distributions in source-related, biodegraded oils suggests that demethylated hopanes are biotransformation products of the hopanes. Further, it appears that the process occurs at a late stage of biodegradation, after partial degradation of steranes has occurred. Demethylated hopanes are proposed as biomarkers for this stage of severe biodegradation. The presence of these compounds in apparently undegraded crude oils is thought to be due to the presence of biodegraded crude oil residues which have been dissolved by the undegraded crude oil during accumulation in the reservoir sands. The timing of hopane demethylation, relative to the degradation of other compounds, has been assessed and the progressive changes in crude oil composition with increasing extent of biodegradation have been identified. The use of demethylated hopanes as maturity parameters for severely biodegraded crude oils, and the applicability of established biomarker maturity parameters to such oils, are also discussed.     

Age and paragenesis of mineralisation at Coronation Hill uranium deposit,Northern Territory,Australia

Coronation Hill is a U?+?Au?+?platinum group elements deposit in the South Alligator Valley (SAV) field in northern Australia, south of the better known unconformity-style U East Alligator Rivers (EAR) field. The SAV field differs from the EAR by having a more complex basin-basement architecture. A volcanically active fault trough (Jawoyn Sub-basin) developed on older basement and then was disrupted by renewed faulting, before being buried beneath regional McArthur Basin sandstones that are also the main hanging wall to the EAR deposits. Primary mineralisation at Coronation Hill formed at 1607?±?26 Ma (rather than 600–900 Ma as previously thought), and so it is likely that the SAV was part of a single west McArthur Basin dilational event. Most ore is hosted in sub-vertical faults and breccias in the competent volcanic cover sequence. This favoured fluid mixing, acid buffering (forming illite) and oxidation of Fe²⁺ and reduced C-rich assemblages as important uranium depositional mechanisms. However, reduction of U in fractured older pyrite (Pb model age of 1833?±?67 Ma) is an important trap in diorite. Some primary ore was remobilised at 675?±?21 Ma to form coarse uraninite?+?Ni-Co pyrite networks containing radiogenic Pb. Coronation Hill is polymetallic, and in this respect resembles the ‘egress’-style U deposits in the Athabascan Basin (Canada). However, these are all cover-hosted. A hypothesis for further testing is that Coronation Hill is also egress-style, with ores formed by fluids rising through basement-hosted fault networks (U reduction by diorite pyrite and carbonaceous shale), and into veins and breccias in the overlying Jawoyn Sub-basin volcano-sedimentary succession.     

High-resolution precipitation and temperature downscaling for glacier models

The spatial resolution gap between global or regional climate models and the requirements for local impact studies motivates the need for climate downscaling. For impact studies that involve glacier modelling, the sparsity or complete absence of climate monitoring activities within the regions of interest presents a substantial additional challenge. Downscaling methods for this application must be independent of climate observations and cannot rely on tuning to station data. We present new, computationally-efficient methods for downscaling precipitation and temperature to the high spatial resolutions required to force mountain glacier models. Our precipitation downscaling is based on an existing linear theory for orographic precipitation, which we modify for large study regions by including moist air tracking. Temperature is downscaled using an interpolation scheme that reconstructs the vertical temperature structure to estimate surface temperatures from upper air data. Both methods are able to produce output on km to sub-km spatial resolution, yet do not require tuning to station measurements. By comparing our downscaled precipitation (1 km resolution) and temperature (200 m resolution) fields to station measurements in southern British Columbia, we evaluate their performance regionally and through the annual cycle. Precipitation is improved by as much as 30% (median relative error) over the input reanalysis data and temperature is reconstructed with a mean bias of 0.5°C at locations with high vertical relief. Both methods perform best in mountainous terrain, where glaciers tend to be concentrated.     

The long-term stability of engineered landforms of the Ranger Uranium Mine,Northern Territory,Australia: application of a catchment evolution model

There is a need to assess the long-term stability of engineered landforms associated with the rehabilitation of Ranger Uranium Mine, Northern Territory, Australia, as it is a requirement that mill tailings must be contained for periods in excess of 1000 years. The geomorphic model, SIBERIA, is calibrated on hydrologic and erosion data collected by a combination of monitoring and rainfall simulation experiments on the waste rock dumps of Ranger. Preliminary analysis of Ranger's preferred above-grade option suggests that erosion of the order of 7 to 8 m will occur on the structure in a period of 1000 years. This depth of erosion may be sufficient to compromise the integrity of containment. It is shown that SIBERIA has significant advantages over steady-state erosion models. Suggestions are made for the design that will enhance the stability of the structure and extend the structural life of the containment. © 1998 John Wiley & Sons, Ltd.