Dissolved organic carbon dynamics in two streams draining forested catchments at loch ard,Scotland

Dissolved organic carbon (DOC) was measured at four or eight hour intervals between mid-1989 and mid-1991 in two catchments in west central Scotland. The experimental catchment had been recently clear-felled and the control remained under forest. The amount of DOC varied during individual storm events following the stream hydro-graph. Maximum variations were found in the summer half-year and in the clear-felled catchment. There was also evidence of the exhaustion of DOC in the later events of a sequence. Differences between the catchments were related to catchment characteristics and to land-use change. The reduced magnitude of variation in DOC with discharge in the control stream was due to the influence of a wetland area through which the stream flowed. The mean DOC concentrations were similar in the two streams and annual exports were 15 g m^?2 from the control and 16g m^?2 from the felled catchment. The stream draining the clear-felled catchment had greater high flow DOC concentrations in the summer half-year, probably due to the effect of greater mean summer temperatures on DOC release and of the greater supply of organic debris in the stream channel.     

Spine–sheath polarization structures in four active galactic nuclei jets

We present the results of multifrequency (15 + 8 + 5 GHz) polarization Very Long Baseline Array (VLBA) observations of the three BL Lacertae objects 0745+241, 1418+546 and 1652+398 together with 5-GHz VLBI Space Observatory Programme (VSOP) observations of 1418+546 and 1.6- and 5-GHz VSOP observations of the blazar 1055+018. The jets of all these sources have polarization structure transverse to the jet axis, with the polarization E vectors aligned with the jet along the jet spine and 'sheaths' of orthogonal E vectors at one or both edges of the jet. The presence of polarization aligned with the jet near the 'spine' may indicate that the jets are associated with helical B fields that propogate outward with the jet flow; the presence of orthogonal polarization near the edges of the jet may likewise be a consequence of a helical jet B field, or may be owing to an interaction with the ambient medium on parsec scales. We have tentatively detected interknot polarization in 1055+018 with E aligned with the local jet direction, consistent with the possibility that the jet of this source is associated with a helical B field.     

Reliability assessment of serviceability performance of braced retaining walls using a neural network approach

In urban environments, one major concern with deep excavations in soft clay is the potentially large ground deformations in and around the excavation. Excessive movements can damage adjacent buildings and utilities. There are many uncertainties associated with the calculation of the ultimate or serviceability performance of a braced excavation system. These include the variabilities of the loadings, geotechnical soil properties, and engineering and geometrical properties of the wall. A risk‐based approach to serviceability performance failure is necessary to incorporate systematically the uncertainties associated with the various design parameters. This paper demonstrates the use of an integrated neural network–reliability method to assess the risk of serviceability failure through the calculation of the reliability index. By first performing a series of parametric studies using the finite element method and then approximating the non‐linear limit state surface (the boundary separating the safe and ‘failure’ domains) through a neural network model, the reliability index can be determined with the aid of a spreadsheet. Two illustrative examples are presented to show how the serviceability performance for braced excavation problems can be assessed using the reliability index. Copyright © 2005 John Wiley & Sons, Ltd.     

HIGH POSSIL AND STRATHMORE—A STUDY OF TWO L6 CHONDRITES

High Possil and Strathmore are the first (1804) and last (1917) meteorite falls, respectively, of the three recorded in Scotland. Olivine compositions and total Fe contents in High Possil (Fa_25.2; 21.35 wt %) and Strathmore (Fa_25.3; 20.6 wt %) confirm their classification as L-group chondrites (Mason, 1963), and the presence of abundant plagioclase feldspar shows that both chondrites belong to petrologic type 6. Both chondrites display thermal and mechanical alteration attributable to moderate shock-loading appropriate to facies c (High Possil) and c-d (Strathmore) (Dodd and Jarosewich, 1979). Incipient shock-melting of metal and troilite in both chondrites is the first described from Lc chondrites, and differences in the responses of metallic and silicate minerals to shock-loading are discussed.     

A feasibility study of cosmic microwave radiation via graphite needles

It is pointed out that the total amount of microwave radiation that could possibly be generated by all the graphite needles in space would be considerably smaller than the observed total energy of the cosmic microwave background radiation. The question of relevant optical depth of the cloud containing the needles has been examined. It is found that the optical depth is not sufficiently large for the cloud to radiate like a black body.     

Shear-wave polarizations on a curved wavefront at an isotropic free surface

Summary. We present polarization diagrams of the particle motions at the free surface of an isotropic half-space generated by incident shear waves from a local buried point source. The reflectivity technique is used to calculate synthetic seismograms from which the particle motions are plotted. The particle motions are examined over a range of epicentral distances in a uniform isotropic half-space for different source frequencies and polarization angles, and for different Poisson's ratios. The particle motions due to a curved wavefront possess different characteristics from those generated by plane wavefronts at corresponding incidence angles. A curved wavefront generates a local SP -phase: a P -headwave which propagates along the free surface, and arrives shortly before the direct S -wave. These two arrivals give rise to cruciform particle motions in the sagittal and horizontal planes, which could be misinterpreted as anisotropy-induced shear-wave splitting. An examination of the particle motion in the transverse plane, mutually orthogonal to the sagittal and horizontal planes, can be used to discriminate between isotropic and anisotropic interpretations. The amplitude of the SP -phase is enhanced when it propagates in a low-velocity surface layer overlying the source layer, and may then become the dominant phase on radial-component seismograms. The presence of even a single surface layer may introduce considerable complexity into the seismogram, and we examine the effects of layer thickness, velocity contrast, and source depth on the corresponding polarization diagrams. Reliable information on the source and propagation path characteristics of shear waves from a buried local point source can only be obtained from free-surface records if they are recorded within a very limited epicentral distance range.     

The importance of oxygen isotope provenance in relation to solute content of bulk meltwaters at Imersuaq Glacier,West Greenland

Stable oxygen isotope analysis and measurement of several dissolved cations and anions of bulk meltwater samples have provided information about the hydrochemical environment of the glacial hydrological system at Imersuaq Glacier, an outlet tongue from the Greenland ice‐sheet, West Greenland. The samples were collected at frequent intervals during the period 20–28 July 2000 in a small (<20 L s^?1) englacial meltwater outlet at the glacier margin. The results document the following findings: (i) a marked diurnal variation of δ¹⁸O is related to the composition of oxygen isotope provenances, mainly near‐marginal local superimposed ice and basal up‐sheared ice further up‐glacier; (ii) a relationship is seen between all base cations (Na⁺, K⁺, Ca²⁺, Mg²⁺), SO₄^2? and δ¹⁸O, indicating that solute acquisition is provided by solid–solution contact with the up‐sheared ice—as the relationship with Cl^? is weak the influence of seasalt‐derived solutes is small in the area; (iii) when the melt rate is high, two diurnal maxima of δ¹⁸O values and solute concentrations are measured, and it is suggested that a snow meltwater component is responsible for the second maximum of δ¹⁸O—a short residence time leads to a delayed decrease in ion concentrations. Copyright © 2003 John Wiley & Sons, Ltd.