Study of occurrence states and precipitation mechanism of tellurium in Huangtun Au -Cu -bearing breccia pipe in Luzong Basin,Anhui, eastern ChinaSCIEI北大核心CSCD

隐爆角砾岩筒型金(铜)矿床作为重要的金矿床类型,常伴生关键金属碲的矿化,然而对于此类矿床中碲的分布、分配特征及沉淀机制研究仍较为薄弱。黄屯矿床是长江中下游成矿带近年来发现的最为典型的隐爆角砾岩筒型金铜矿床,伴生有大量的碲化物产出。本文在详细的野外地质工作和岩相学观察基础上,发现碲在矿床中发生了显著富集。通过对黄屯矿床不同蚀变类型矿石及主要富碲矿物开展全岩及微区地球化学分析,明确了碲的分布、分配特征以及初步讨论了碲的沉淀机制。黄屯矿床成矿阶段从早到晚可划分为钠钙硅酸盐、钾硅酸盐、绿泥石-碳酸盐和伊利石-蒙脱石阶段,在不同深度形成了相应的蚀变带,并发育有不同强度的金铜矿化。黄屯矿床伴生的碲储量约有118.71t,平均品位为5.3g/t,达到中型规模,具备重要的综合利用价值。钾硅酸盐蚀变带碲的分布比例最高,占总储量约92.37%,平均品位约为9.6g/t。钾硅酸盐蚀变带内约有89%~99%的碲呈独立矿物,主要以微米级、纳米级的碲铋矿包体的形式分布在黄铁矿中,剩余部分则以类质同象的形式赋存在黄铁矿和黄铜矿内。减压沸腾引起流体温度骤降导致硫化物沉淀,和沸腾过程中释放大量气相H_(2)S,共同导致流体的f(Te_(2))/f(S_(2))比值升高,可能是黄屯矿床中碲沉淀富集的主要机制。     

Discovery of scandium enrichment and its geological significance in the Dawanshan Neoproterozoic metamorphic basalts from the Mouding area in Central Yunnan Province,ChinaSCIEI北大核心CSCD

钪(Sc)是世界各国竞相争夺的关键金属矿产资源之一。滇中牟定大弯山变质玄武岩厚度>36.5m,出露面积0.5km^(2),形成时代为新元古代南华纪(781.3±1.9Ma)。本文对该变质玄武岩开展了全岩地球化学分析、全自动矿物分析(TESCAN TIMA)观测、NPPM薄片区域面扫和单矿物原位LA-ICPMS分析等研究,结果显示变质玄武岩全岩Sc含量为47.0×10^(-6)~97.9×10^(-6),平均含量为69.1×10^(-6),钪氧化物(Sc_(2)O_(3))平均含量为106×10^(-6),变质玄武岩空间Sc矿化特征稳定,具有形成钪矿资源的潜力。同时,变质玄武岩共伴生有钛和铁矿化,全岩TiO_(2)含量为2.57×10^(-2)~6.13×10^(-2),平均为4.25×10^(-2);TFe含量为13.3×10^(-2)~23.7×10^(-2),平均为17.7×10^(-2)。Sc可能存在类质同象和离子相两种赋存形式,类质同象形式Sc主要赋存于钛铁矿和金红石矿物中,钛铁矿中Sc含量为70.0×10^(-6)~168×10^(-6),平均值为108×10^(-6);金红石中Sc含量高达297×10^(-6);而磁铁矿、黑云母等矿物中Sc含量较低,均低于全岩Sc含量,对全岩Sc矿化贡献较小。牟定大弯山Sc矿化与以往报道侵入岩及其风化壳中Sc矿化在富集特征、赋存岩性和载体矿物等方面不同,是变质火山岩中新发现的Sc矿化信息,显示了较好的找矿潜力,对Sc资源勘查和研究具有重要指示意义。     

兰州第四纪黄土/古土壤序列物源演变: 来自于碳酸盐矿物的证据*

黄土/古土壤的物源研究对于揭示第四纪气候变化和青藏高原隆升历史具有重要意义。本研究以位于黄土高原西部1.4 Ma以来的兰州黄土/古土壤沉积序列为研究对象,基于X射线衍射技术分析了黄土/古土壤中的主要矿物组成,侧重于碳酸盐矿物含量,追溯了兰州黄土/古土壤的直接物源。结果显示: (1)1.4 Ma以来兰州地区黄土/古土壤沉积物的主要直接源区为柴达木盆地沙漠区和阿拉善干旱区。(2)基于二元混合模型计算的潜在原始源区对兰州黄土白云石和总碳酸盐矿物的相对贡献率以及长石与石英比值结果一致支持1.4 Ma以来兰州黄土原始物源发生了多次变化。1.4~1.1 Ma和0.9~0.3 Ma青藏高原东北缘造山带(昆仑山、祁连山)和中亚造山带对兰州黄土的贡献相当,而1.1~0.9 Ma和0.3 Ma以来,中亚造山带对兰州黄土的物源贡献增加,这可能分别是对中更新世气候转型和0.3 Ma以来青藏高原及邻近地区干冷气候增强的响应。1.15 Ma和0.8 Ma兰州黄土/古土壤中高的白云石含量、碳酸盐矿物总含量以及0.8 Ma长石与石英比值的快速升高可能是对“昆黄运动”的响应,进而造成了昆仑山、祁连山对黄土高原物源贡献的增加。     

库车坳陷大北克深井区白垩系储层含盐特征与分布规律#br#

塔里木盆地库车坳陷盐下深部储层是天然气勘探的重要领域,白垩系储层岩盐广泛发育,储层含盐特征的精细表征和评价对该区勘探区带优选具有重要意义.以库车坳陷大北克深井区白垩系砂岩储层７２件岩心样品为研究对象,通过薄片、扫描电镜、能谱分析与QEMSCAN(岩石矿物定量分析)等技术手段,对研究区白垩系砂岩储层的含盐特征、分布规律、形成条件及来源等进行研究.结果表明:岩盐晶体主要赋存在碎屑颗粒间、碎屑颗粒表面和溶蚀孔与裂缝中,呈格架状、晶粒状和团块状集合体等３种赋存状态,不同状态岩盐晶体Na和Cl等元素的原子分数存在差异;岩盐分布规律为,平面上表现出西高东低的特点,垂向上距上覆膏盐岩层越近,岩盐体积分数越高;不同的盐源供给条件、储层埋藏深度、砂岩粒级、分选性等制约岩盐晶体的集合体形态;岩盐来源主要为古近系膏盐类沉积物的溶蚀渗流,也可能与含盐流体沿构造断裂的侧向渗入有关.     

Fracability Evaluation Based on the Three-Dimensional Geological Numerical Simulation of In Situ Stress: Case Study of the Longmaxi Formation in the Weirong Shale Gas Field,Southwestern China

Mathematical Geosciences - Quantitative evaluation of fracability is essential for hydraulic fracturing design, with the distribution of in situ stress being a key parameter. This study focused on...     

A constitutive model for municipal solid waste considering mechanical creep and biodegradation-induced compression

Acta Geotechnica - A constitutive model is developed to describe the stress–strain–time behavior for decomposing municipal solid waste (MSW) within a critical state soil mechanics...     

Eastward subduction of the Indian plate beneath the Indo-Myanmese arc revealed by teleseismic P-wave tomography

The deep structure of the eastward-subducting Indian plate can provide new information on the dynamics of the India-Eurasia collision. We collected and processed waveform data from temporary seismic arrays (networks) on the eastern Tibetan Plateau, seismic arrays in Northeast India and Myanmar, and permanent stations of the China Digital Seismic Network in Tibet, Gansu, Qinghai, Yunnan, and Sichuan. We combined these data with phase reports from observation stations of the International Seismological Center on the Indian plate and selected 124,808 high-quality P-wave relative travel-time residuals. Next, we used these data to invert the 3-D P-wave velocity structure of the upper mantle to a depth of 800 km beneath the eastern segment of the arcuate Himalayan orogen, at the southeastern margin of the Tibetan Plateau. The results reveal a high-angle, easterly dipping subducting plate extending more than 200 km beneath the Indo-Myanmese arc. The plate breaks off at roughly 96°E; its fragments have passed through the 410-km discontinuity (D410) into the mantle transition zone (MTZ). The MTZ beneath the Tengchong volcanic area contains a high-velocity anomaly, which does not exceed the Red River fault to the east. No other large-scale continuous subducted plates were observed in the MTZ. However, a horizontally spreading high-velocity anomaly was identified on the D410 in some regions. The anomaly may represent the negatively buoyant 90°E Ridge plate or a thickened and delaminated lithospheric block experiencing collision and compression at the southeastern margin of the Tibetan Plateau. The Tengchong volcano may originate from the mantle upwelling through the slab window formed by the break-off of the subducting Indian continental plate and oceanic plate in the upper mantle. Low-velocity upper mantle materials on the west side of the Indo-Myanmese arc may have supplemented materials to the Tengchong volcano.     

Shaking table test of subgrade slope reinforced by gravity retaining wall with geogrids

Gravity retaining wall with geogrids has showed excellent seismic performance from Wenchuan great earthquake. However, seismic damage mechanism of this kind of wall is not sufficiently clear. In view of this, a large shaking table test of the gravity retaining wall with geogrids to reinforce the subgrade slope was carried out, and based on the Hilbert-Huang transform and the marginal spectrum theory, the energy identification method of the slope dynamic failure mode was studied. The results show that the geogrids can effectively reduce displacement and rotation of the retaining wall, and it can effectively absorb the energy of the ground movement when combined with the surrounding soil. In addition, it also reveals the failure development of the gravity retaining wall with geogrids to reinforce the subgrade slope. The damage started in the deep zone near the geogrids, and then gradually extended to the surface of the subgrade slope and other zones, finally formed a continuous failure surface along the geogrids. The analysis results of the failure mode identified by the Hilbert marginal spectrum are in good consistency with the experimental results, which prove that the Hilbert marginal spectrum can be applied to obtain the seismic damage mechanism of slope.

     

塔中地区良里塔格组海平面变化对高频层序和沉积演化的控制

【研究目的】碳酸盐岩地层易受海平面变化影响而发育高频层序,但是反映海平面变化的地化指标的精度不足,导致高频层序对海平面振荡的响应认识不够深入,高频海平面变化对台地边缘礁滩沉积的高频层序和沉积演化的控制尚不明确。【研究方法】论文研究选取塔里木盆地塔中地区某钻井的上奥陶统良里塔格组连续取心资料,通过密集取样开展微相分析和碳、氧同位素测试分析。【研究结果】该井良里塔格组中上部发育7种微相类型,沉积演化分析表明良里塔格组沉积中—晚期,沉积环境由潮坪向生物礁-颗粒滩再到较深水的开阔台地演化。碳、氧同位素测试显示δ¹³C为0.5993‰~1.6228‰（均值1.139‰）,δ¹⁸O值为-8.3608‰~-5.1452‰（均值为-6.790‰）;δ¹³C和δ¹⁸O的振荡变化与微相变化和沉积旋回对应良好。古海洋条件分析表明,良里塔格组沉积时期气候温热,礁、滩体发育层段样品的古温度值最高,代表着高的碳酸盐产率;Z值所反映的古盐度在底部潮坪沉积段最高,在高频旋回的顶部古盐度均明显减小,指示可能存在大气淡水的影响。与塔北地区南缘和巴楚地区的δ¹³C和δ¹⁸O存在一定差异,主要受控于沉积环境和古水深。【结论】良里塔格组中—上部存在至少3个完整的海平面升降变化周期,内部又包括至少2个次级周期;不同级别的海平面振荡主要受古气候变化驱动,并控制了高频层序的发育。海平面先缓慢上升再持续稳定或小规模振荡,是连续厚层的生物碎屑和砂屑颗粒滩沉积发育的有利条件;良里塔格组沉积晚期海平面快速上升,沉积环境向滩间洼地和较深水的开阔台地转变。在高频层序顶部海平面的小规模下降导致的早期岩溶作用是礁滩体储层质量改善的重要因素。     

沧县隆起北部地区地热资源特征及开发潜力

【研究目的】地热资源特征研究及开发潜力分析是开发区域地热资源的重要依据。【研究方法】本文将前人研究成果与最新钻井资料相结合,通过对沧县隆起北部地区地热地质背景、热储分布、地温场特征、水化学资源类型等主要因素进行剖析,建立了该区的地热成藏模式。【研究结果】沧县隆起北部地区是在渤海湾伸展型沉积盆地高大地热流值背景下,由北部燕山裸露区基岩接受的大气降水作为近源补给水源,进入基岩的冷水在深层循环过程中受到深部热源加热增温,沿断裂破碎带和不整合面向上运移富集,形成的以传导型传热机制为主的地热系统。【结论】本区地热资源特点为热储类型多、盖层地温梯度高、补给速度快、资源量巨大。主要表现为：区内分布馆陶组砂岩热储,奥陶系、蓟县系雾迷山组岩溶热储三套主力热水储集层;地温场分布主要受基底构造形态控制,基岩凸起区的平均地温梯度为45℃/km;地下水类型随着埋深的增加由HCO₃-Na、HCO₃·SO₄-Na型水向成熟的Cl-Na型水过渡;本区内三套热储的可采地热资源量为1.67×10¹⁰GJ,折合标煤5.72×10⁸t,年可开采地热资源量可满足供暖面积2亿m²,若在采灌平衡的条件下,沧县隆起北部地区年可采地热资源量为7.06×10⁷GJ,折合标煤2.41×10⁶t,可满足供暖面积0.85亿m²,具有良好的地热市场开发前景。