Silver-Bearing and Associated Minerals in El Zancudo Deposit, Antioquia, Colombia

The occurrence and the chemical compositions of ore minerals (especially the silver‐bearing minerals) and fluid inclusions of the El Zancudo mine in Colombia were investigated in order to analyze the genetic processes of the ore minerals and to examine the genesis of the deposit. The El Zancudo mine is a silver–gold deposit located in the western flank of the Central Cordillera in Antioquia Department. It consists mainly of banded ore veins hosted in greenschist and lesser disseminated ore in porphyritic rocks. The ore deposit is associated with extensive hydrothermally altered zones. The ores from the banded veins contain sphalerite, pyrite, arsenopyrite, galena, Ag‐bearing sulfosalts, Pb‐Sb sulfosalts, and minor chalcopyrite, electrum, and native silver. Electrum is included within sphalerite, pyrite, and arsenopyrite, and is also partially surrounded by pyrite, arsenopyrite, sphalerite, and tetrahedrite. Native silver is present in minor amounts as small grains in contact with Ag‐rich sulfosalts. Silver‐bearing sulfosalts are argentian tetrahedrite–freibergite solid solution, andorite, miargyrite, diaphorite, and owyheeite. Pb‐Sb sulfosalts are bournonite, jamesonite, and boulangerite. Two main crystallization stages are recognized, based on textural relations and mineral assemblages. The first‐stage assemblage includes sphalerite, pyrite, arsenopyrite, galena and electrum. The second stage is divided into two sub‐stages. The first sub‐stage commenced with the deposition and growth of sphalerite, pyrite, and arsenopyrite. These minerals are characterized by compositional growth banding, and seem to have crystallized continuously until the end of the second sub‐stage. Tetrahedrite, Pb‐Cu sulfosalts, Ag‐Sb sulfosalt, and Pb‐Ag‐Sb sulfosalts crystallized from the final part of the first sub‐stage and during the whole second sub‐stage. However, one Pb‐Ag‐Sb sulfosalt, diaphorite, was formed by a retrograde reaction between galena and miargyrite. The minimum and maximum genetic temperatures estimated from the FeS content of sphalerite coexisting with pyrite and the silver content of electrum are 300°C and 420°C, respectively. These estimated genetic temperatures are similar to, but slightly higher than the homogenization temperatures (235–350°C) of primary fluid inclusions in quartz. The presence of muscovite in the altered host rocks and gangue suggest that the pH of the hydrothermal solutions was close to neutral. Most of the sulfosalts in this deposit have previously been attributed as the products of epithermal mineralization. However, El Zancudo can be classified as a xenothermal deposit, in view of the low pressure and high temperature genetic conditions identified in the present study, based on the mineralogy of sulfosalts and the homogenization temperatures of the fluid inclusions.     

Sunspot Numbers and Areas from the Madrid Astronomical Observatory (1876 – 1986)

The solar program of the Astronomical Observatory of Madrid started in 1876. Observations were made in this institution to determine sunspot numbers and areas for ten solar cycles. The program was completed in 1986 and the resulting data have been published in various Spanish scientific publications. Four periods of this program (with different observers and instruments) were identified with the aid of the interesting metadata that has been made available. In the present work, the published data were retrieved and digitized. Their subsequent analysis showed that most of these data could be considered reliable given their very high correlation with reference indices (international sunspot number, group sunspot number, and sunspot area). An abrupt change emerged in the sunspots/groups ratio in 1946, which lasted until 1972.     

Major moisture sources for Western and Southern India and their role on synoptic‐scale rainfall events

Although the identification of the moisture sources of a region is of prominent importance to characterize precipitation, the origin and amount of moisture towards the Indian Subcontinent and its relationship with the occurrence of precipitation are still not completely understood. In this article, the origin of the atmospheric water arriving to the Western and Southern India during a period of 5 years (1 January 2000–31 December 2004) is investigated by using a Lagrangian diagnosis method. This methodology computes budgets of evaporation minus precipitation by calculating changes in the specific humidity of thousands of air particles aimed to the study area following the observed winds. During the summer monsoon, the main supply of moisture is the Somali Jet, which crosses the equator by the West Indian Ocean. The recycling process is the main water vapour source in winter. Two additional moisture sources located over northwestern India and the Bay of Bengal are identified. A 30% increase in the moisture flux from the Indian Ocean has been related to the occurrence of strong precipitation in the area, and at the end of the monsoon, the recycling became a significant contribution to the last part of the wet season of Western and Southern India. Copyright © 2011 John Wiley & Sons, Ltd.     

n-Alkan-2-ones in peat-forming plants from the Roñanzas ombrotrophic bog (Asturias, northern Spain)

We determined the distribution of lipids (n-alkanes and n-alkan-2-ones) in present-day peat-forming plants in the Roñanzas Bog in northern Spain. Consistent with the observation of others, most Sphagnum (moss) species alkanes maximized at C₂₃, whereas the other plants maximized at higher molecular weight (C₂₇ to C₃₁). We show for the first time that plants other than seagrass and Sphagnum moss contain n-alkan-2-ones. Almost all the species analysed showed an n-alkan-2-one distribution between C₂₁ and C₃₁ with an odd/even predominance, maximizing at C₂₇ or C₂₉, except ferns, which maximized at lower molecular weight (C₂₁-C₂₃). We also observed that microbial degradation can be a major contributor to the n-alkan-2-one distribution in sediments as opposed to a direct input of ketones from plants.     

Long-term Spatial and Temporal Variations of Aurora Borealis Events in the Period 1700 – 1905

Catalogues and other records of aurora-borealis events were used to study the long-term spatial and temporal variation of these phenomena in the period from 1700 to 1905 in the Northern Hemisphere. For this purpose, geographic and geomagnetic coordinates were assigned to approximately 27?000 auroral events with more than 80?000 observations. They were analyzed separately in three large-scale areas: i) Europe and North Africa, ii) North America, and iii) Asia. There was a clear need to fill some gaps existing in the records so as to have a reliable proxy of solar activity, especially during the 18th century. In order to enhance the long-term variability, an 11-year smoothing window was applied to the data. Variations in the cumulative numbers of auroral events with latitude (in both geographic and geomagnetic coordinates) were used to discriminate between the two main solar sources: coronal mass ejections and high-speed streams from coronal holes. The characteristics of the associated auroras correlate differently with the solar-activity cycle.     

A Note on Solar Cycle Length Estimates

Recently, new estimates of the solar cycle length (SCL) have been calculated using the Zurich Sunspot Number (R_Z) and the Regression-Fourier-Calculus (RFC)-method, a mathematically rigorous method involving multiple regression, Fourier approximation, and analytical expressions for the first derivative. In this short contribution, we show estimates of the solar cycle length using the RFC-method and the Group Sunspot Number (R_G) instead the R_Z. Several authors have showed the advantages of R_G for the analysis of sunspot activity before 1850. The use of R_G solves some doubtful solar cycle length estimates obtained around 1800 using R_Z.