Ag-rich Tetrahedrite in the El Zancudo Deposit,Colombia: Occurrence,Chemical Compositions and Genetic Temperatures

Chemical compositions of tetrahedrite—Ag-rich tetrahedrite—freibergite solid solutions (Ag-rich tetrahedrite_ss) and homogenization temperatures of fluid inclusions in quartz and carbonates of seventeen samples from nine veins in the El Zancudo deposit, Antioquia, Colombia, were investigated to reveal the origin of silver in Ag-rich tetrahedrite_ss, to derive their crystallization temperatures and to examine the relationship between chemical compositions of Ag-rich tetrahedrite_ss and their crystallization temperatures. The ores consist of arsenopyrite, pyrite, sphalerite, Ag-rich tetrahedrite_ss, galena, boulangerite, andorite, owyheeite, diaphorite, jamesonite, miargyrite, bournonite, chalcopyrite, and electrum. Ag-rich tetrahedrite_ss forms about 10 volume % of the total ores and is one of the most common and widely distributed sulfosalts in this deposit. Ag-rich tetrahedrite_ss is rich in Ag (1.13 to 31.02 wt%) and Sb (22.93 to 29.82 wt%), and poor in As (0.06 to 2.43 wt%), consistent with the reported incompatibilities of Ag and As in Ag-rich tetrahedrite_ss. The Zn/(Zn + Fe)-, Ag/(Ag + Cu)- and Sb/(Sb + As + Bi)-atomic ratios exhibit some variations among the veins. Ag-rich tetrahedrite_ss with higher Ag/(Ag + Cu) ratios coexist with diaphorite, whereas those with lower ratios are not associated with this sulfosalt. Ag-rich tetrahedrite_ss in the assemblages of Ag-rich tetrahedrite_ss+ sphalerite and of Ag-rich tetrahedrite_ss+ bournonite + galena shows no Zn ↔ Fe and Cu ↔ Ag variations between core and rim, respectively, negating the possibility of solid state reaction during cooling. Ag-rich tetrahedrite_ss is thus regarded as primary phase. Homogenization temperatures of primary fluid inclusions in quartz and carbonates co-existing with Ag-rich tetrahedrite_ss define the mineralization temperatures of 134 to 263°C. Independent crystallization temperatures of Ag-rich tetrahedrite estimated based on Zn/(Zn + Fe) and Ag/(Ag + Cu) ratios of the Ag-rich tetrahedrite_ss associated with silver minerals such as miargyrite, andorite and diaphorite using Sack's thermochemical database lie in a range between 170 and ∼250°C. Both results are thus in good agreement.     

Energy balance and evaporation loss of an irrigation reservoir equipped with a suspended cover in a semiarid climate (south‐eastern Spain)

The main objective of this study was to assess the impact of a suspended cover on the evaporation loss of an agricultural water reservoir (AWR). To this aim, a detailed data collection was carried out in a typical AWR located in south‐eastern Spain during 2 consecutive years. During the first year, the reservoir remained uncovered, while during the second year it was covered with a double black polyethylene (PE) shade cloth. On an annual scale, it was observed that the cover can provide a reduction of evaporation loss of 85%. Two approaches, energy balance and mass transfer, were used to analyse the effect of the cover on the evaporation process. Important modifications were observed on the magnitude, sign, annual trend and relative weight of the components of the energy balance. The changes were ascribed to the strong reduction of net radiation and to the substantial weight of the heat storage and sensible heat flux in the energy balance. A relevant finding was the contrast between the patterns of the annual evaporation curve for open‐water and covered conditions. The mass transfer approach allowed discriminating between the wind‐ and radiation‐shelter effects on the evaporation term. The reduction in water‐to‐air vapour deficit was the main factor explaining the high efficiency of the cover, whereas the reduction of the mass transfer coefficient was a modulating factor that accounted for the wind‐shelter effect. Overall, both approaches provided a sound basis to describe and explain the physical mechanisms underlying the high performance of the tested cover. Copyright © 2010 John Wiley & Sons, Ltd.     

Evidence for a sunspot in A.D. 939 in an Arabian Source

It is the purpose of this paper to present evidence concerning the appearance of a sunspot in A.D. 939 observed by Arabs from the Iberian Peninsula. The sunspot record appears in the Arab source known as al-Muqtabis V.     

Sunspot Catalogue of the Valencia Observatory (1920 – 1928)

A sunspot catalogue was maintained by the Astronomical Observatory of Valencia University (Spain) from 1920 to 1928. Here we present a machine-readable version of this catalogue (OV catalogue or OVc), including a quality-control analysis. Sunspot number (total and hemispheric) and sunspot area series are constructed using this catalogue. The OV catalogue data are compared with other available solar data, demonstrating that the present contribution provides the scientific community with a reliable catalogue of sunspot data.     

Quantifying the building stock from optical high-resolution satellite imagery for assessing disaster risk

This study uses high-resolution (HR) satellite imagery to quantify the stock of buildings, referred herein as building stock. The risk assessment requires information on the natural hazards and on the element at risk, that is the building stock in this article. This study combines (1) texture-based image processing to map built-up areas, (2) statistical sampling that allows locating the building samples and (3) photo-interpretation to encoding building footprints. Statistical inference is then used to quantify the building stock per class of building size. Legaspi in the Philippines is used as a case study. The results show that texture-based computer algorithms provide accurate area estimations of the built-up, that the detail of HR imagery allows the mapping of single buildings using photo-interpretation, and that a systematic sampling approach that uses building encoding and built-up maps can be used to quantify the building stock.     

Degradation and Detoxification of Chlorophenols in Continuous‐Flow Fixed‐Bed Aerobic Reactors

An indigenous bacterial strain of Delftia sp. capable of degrading 2,4‐dicholorophenol and an indigenous bacterial community that degrades 2,4,6‐trichlorophenol (TCP) were employed to inoculate continuous down‐flow fixed‐bed reactors. Continuous‐reactors were constructed from PVC employing hollow PVC cylinders as support material. Synthetic wastewater was prepared by dissolving the corresponding chlorophenol in non‐sterile groundwater. Biodegradation was evaluated by spectrophotometry, chloride release, GC, and microbial growth. Detoxification was evaluated by using Daphnia magna as test organism. Delftia sp. was able to remove an average of 95.6% of DCP. Efficiency in terms of chemical oxygen demand (COD) was of 88.9%. The indigenous bacterial community that degrades TCP reached an average efficiency of 96.5 and 91.6% in terms of compound and COD removal, respectively. In both cases stoichiometric removal of chloride and detoxification was achieved. When synthetic wastewater feed was cut off for 7 days, both reactors showed a fast recovery after inflow restarting, reaching average outlet concentration values within 36 h. The promising behavior of the microorganisms and the low cost of the reactors tested allow us to suggest their possible application to remediation processes.