Doppler radar spectral width broadening due to beamwidth and wind shear

The spectral width observed by Doppler radars can be due to several effects including the atmospheric turbulence within the radar sample volume plus effects associated with the background flow and the radar geometry and configuration. This study re-examines simple models for the effects due to finite beam-width and vertical shear of the horizontal wind. Analytic solutions of 1- and 2-dimensional models are presented. Comparisons of the simple 2-dimensional model with numerical integrations of a 3-dimensional model with a symmetrical Gaussian beam show that the 2-dimensional model is usually adequate. The solution of the 2-dimensional model gives a formula that can be applied easily to large data sets. Analysis of the analytic solutions of the 2-dimensional model for off-vertical beams reveals a term that has not been included in mathematical formulas for spectral broadening in the past. This term arises from the simultaneous effects of the changing geometry due to curvature within a finite beamwidth and the vertical wind shear. The magnitude of this effect can be comparable to that of the well-known effects of beam-broadening and wind shear, and since it can have either algebraic sign, it can significantly reduce (or increase) the expected spectral broadening, although under typical conditions it is smaller than the beam-broadening effect. The predictions of this simple model are found to be consistent with observations from the VHP radar at White Sands Missile Range, NM.     

The Pleistocene history of Wales and the borderland

The Pleistocene rock-stratigraphic record is accorded more or less traditional time-stratigraphic interpretation which was held widely before application of an Irish developmental model in 1960. The following sequence of events are recognised: (1) Complete glaciation, of indeterminate age, which antedated the raised beach interglacial. (2) The raised beach episode which is shown to be the last (Ipswichian) interglacial. (3) The last (Devensian/Weichselian) glaciation, followed by possible readvance in northwest and northeast Wales; prior and subsequent to glaciation periglacial conditions obtained. It is shown that the Irish model, relying heavily as it does on the equation of rock and time stratigraphy, is inapplicable in Wales.     

Extraction and recovery of precious metals from electronic waste printed circuit boards by bioleaching acidophilic fungi

Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes.     

Rare earth elements in the clay fraction of coaliferous sediments of the Arkagalinskoe (Magadan district) and Dolinskoe (Sakhalin Island) coalfields

The study of REE distribution in the clay fraction of sedimentary rocks from two coalfields made it possible to distinguish several types of REE distribution, which correlate with their mineral composition. It is shown that the REE fractionation was related to the mineral reconstruction of the primary clay fraction and some detrital minerals in the course of postsedimentary transformations of rocks during diagenesis, early catagenesis, and beginning of late catagenesis. These transformations were governed by several factors, such as the composition of sediments; hydrochemical features of accumulation environment; the chemical composition, dynamics, and feeding sources of pore solutions; the porosity and permeability of sediments and rocks; and the content of organic matter and its reaction ability.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.