The stability of UO2OH+ and UO2[HPO4]2−2 complexes at 25°C

The cumulative association constant (β₂) for the geochemically important aqueous complex UO₂[HPO₄]^2?₂ has been determined by potentiometric titration in Na₂HPO₄-UO₂(NO₃)₂ solutions in the pH range 3.9–4.7, at ionic strengths below 0.024 molal with the Newton-Raphson method used to compute β₂ from the chemical analytical data. Based on 25 measurements we obtain logβ₂ = 18.3 ± 0.2 at 25°C. From the same experiments we compute that the association constant of UO₂OH⁺ is 8.9 ± 0.1, in disagreement with the value of 8.3 ± 0.3 for this constant given by Baes and Mesmer (1976).     

Cyclostratigraphy and high-frequency carbon isotope fluctuations in Upper Cretaceous shallow-water carbonates, southern Italy

Abstract A detailed carbon isotope study has been carried out on a Santonian (Upper Cretaceous) carbonate platform succession that crops out at Monte Sant'Erasmo (southern Italy). Previous centimetre‐scale studies on this succession have shown that high‐frequency eustatic changes, resulting from the Earth's orbital fluctuations, controlled the hierarchical organization of the depositional and early diagenetic features in elementary cycles, bundles (groups of three to five elementary cycles) and superbundles (groups of three or four bundles). The elementary cycles, which correspond to single beds, suggest a control caused by Earth's precession; the bundles and superbundles record the short (≈ 100 kyr) and long (≈ 400 kyr) eccentricity periodicity respectively. The δ¹³C signal of the Monte Sant'Erasmo succession is cyclic in nature and may be considered to be a reliable proxy for the sedimentary evolution (and related sea‐level history) of the analysed sequence. The carbon isotope cyclicity is recorded at bundle and superbundle level, but it is not evident at the scale of the elementary cycles, at least with the sampling interval used in this study. Spectral analysis of the δ¹³C record shows two main peaks corresponding to the short‐ and long‐eccentricity periodicity, whereas the precession signal is not evident in the power spectrum. In addition, lithofacies analysis shows that, in each bundle (and superbundle), higher C isotope values occur in sediments characterized by marine cements, whereas lower values are normally found in more restricted deposits overprinted by early meteoric diagenesis. Early diagenesis, driven by periodic sea‐level fluctuations, developed in either shallow‐subtidal (marine diagenesis) or subaerial‐exposed (meteoric overprint) sedimentary environments and directly influenced the carbon isotope signature. As a consequence, the δ¹³C record at Monte Sant'Erasmo reflects high‐frequency climatic oscillations controlling both environmental and early diagenetic changes. The long‐term isotopic record is similar to that of contemporaneous pelagic sections in England and elsewhere in Italy. It is concluded that the δ¹³C signature of shallow‐water carbonates, such as those of Monte Sant'Erasmo, offers great potential for correlation with coeval sections, including those of the pelagic realm.     

The use of damage functionals in earthquake engineering: A comparison between different methods

The behaviour of the EPP-SDOF model under seismic actions is analysed herein by different ‘damage functionals’ to define collapse under cyclic loading. In particular, the damage functionals based on the concept of maximum ductility and dissipated plastic energy are first compared. Afterwards the methods of Banon and Veneziano, Park and Ang and the linear cumulative law of plastic fatigue are reviewed and extensively analysed. Comparisons in the case of simple cyclic histories and in terms of acceleration collapse spectra are carried out with reference to significant earthquake records. In particular, it is shown in which cases the damage functionals of Banon and Veneziano, Park and Ang and the linear cumulative law of plastic fatigue, completely defined by the value of a single parameter, degenerate in the limit methods of ductility or dissipated energy and in which cases they provide similar results.     

Prediction of response spectra via real-time earthquake measurements

The development and implementation of an earthquake early warning system (EEWS), both in regional or on-site configurations can help to mitigate the losses due to the occurrence of moderate-to-large earthquakes in densely populated and/or industrialized areas. The capability of an EEWS to provide real-time estimates of source parameters (location and magnitude) can be used to take some countermeasures during the earthquake occurrence and before the arriving of the most destructive waves at the site of interest. However, some critical issues are peculiar of EEWS and need further investigation: (1) the uncertainties on earthquake magnitude and location estimates based on the measurements of some observed quantities in the very early portion of the recorded signals; (2) the selection of the most appropriate parameter to be used to predict the ground motion amplitude both in near- and far-source ranges; (3) the use of the estimates provided by the EEWS for structural engineering and risk mitigation applications.In the present study, the issues above are discussed using the Campania–Lucania region (Southern Apennines) in Italy, as test-site area. In this region a prototype system for earthquake early warning, and more generally for seismic alert management, is under development. The system is based on a dense, wide dynamic accelerometric network deployed in the area where the moderate-to-large earthquake causative fault systems are located.The uncertainty analysis is performed through a real-time probabilistic seismic hazard analysis by using two different approaches. The first is the Bayesian approach that implicitly integrate both the time evolving estimate of earthquake parameters, the probability density functions and the variability of ground motion propagation providing the most complete information. The second is a classical point estimate approach which does not account for the probability density function of the magnitude and only uses the average of the estimates performed at each seismic station.Both the approaches are applied to two main towns located in the area of interest, Napoli and Avellino, for which a missed and false alarm analysis is presented by means of a scenario earthquake: an M 7.0 seismic event located at the centre of the seismic network.Concerning the ground motion prediction, attention is focused on the response spectra as the most appropriate function to characterize the ground motion for earthquake engineering applications of EEWS.     

Seismic performance evaluation of plasterboard partitions via shake table tests

The damage of nonstructural components represents the largest contribution to the economic loss caused by an earthquake. Since nonstructural components are not amenable to traditional structural analysis, full-scale experimental testing is crucial to understand their behaviour under earthquake. For this reason, shaking table tests are performed to investigate the seismic behaviour of plasterboard partitions. A steel test frame is properly designed in order to simulate the seismic effects at a generic building storey. The tests are performed shaking the table simultaneously in both horizontal directions. To investigate a wide range of interstorey drift demand and seismic damage, the shakes are performed scaling the accelerograms at eleven different intensity levels. The tested plasterboard partitions from Siniat exhibit a good seismic behaviour, both in their own plane and out of plane, showing limited damage up to 1.1 % interstorey drift ratio. The correlation between the dynamic characteristics of the test setup and the recorded damage is evidenced. Finally, an interesting comparison between the experimental results and the analytical model is also performed.     

Earthquake early warning feasibility in the Campania region (southern Italy) and demonstration system for public school buildings

We present the results of a feasibility study of an earthquake early warning system (EEWS) for the Campania region (southern Italy) using schools as specific targets. The study considered the seismogenic zones as sources of potential earthquakes for the area, the Italian accelerometric network as the recording network for seismic event occurrence, and the performances of the software platform PRESTo ^Plus for data analysis and processing. We analyze the distribution of lead-times for all possible threatening seismic sources for each municipality in the region under study by extracting the lead-time value corresponding to the 5th, 10th and 25th percentiles of the distributions. We discuss the results for the 5th percentile in order to analyze the worst-case scenario: in the case of a single site, the lead-time is expected to be larger than this value in the 95 % of the cases. Since the population distribution in Campania is uneven and most of the people live nearby the coast, whilst the most destructive earthquakes occur along the Apennine chain, we can conclude that an efficient EEWS can allow most of the schools in the area to undertake some mitigating actions. The testing of the EEWS was carried out in the high school ITIS ‘E. Majorana’, located at Somma Vesuviana, about 80 km from the seismogenic Irpinia region. For this purpose, the Sentinel, an actuator made up of low-cost hardware (i.e., Arduino^®), was developed in close cooperation with students and teachers of the school to receive alert messages from the PRESTo ^Plus platform and warn the school users in case of a seismic event. The EEWS and the Sentinel were successfully tested during some blind drills performed during normal school activities.