<Superscript>10</Superscript>Be, <Superscript>18</Superscript>O and radiogenic isotopic constraints on the origin of adakitic signatures: a case study from Solander and Little Solander Islands,New Zealand

Subduction-related Quaternary volcanic rocks from Solander and Little Solander Islands, south of mainland New Zealand, are porphyritic trachyandesites and andesites (58.20–62.19 wt% SiO₂) with phenocrysts of amphibole, plagioclase and biotite. The Solander and Little Solander rocks are incompatible element enriched (e.g. Sr ~931–2,270 ppm, Ba ~619–798 ppm, Th ~8.7–21.4 ppm and La ~24.3–97.2 ppm) with MORB-like Sr and Nd isotopic signatures. Isotopically similar quench-textured enclaves reflect mixing with intermediate (basaltic-andesite) magmas. The Solander rocks have geochemical affinities with adakites (e.g. high Sr/Y and low Y), whose origin is often attributed to partial melting of subducted oceanic crust. Solander sits on isotopically distinct continental crust, thus excluding partial melting of the lower crust in the genesis of the magmas. Furthermore, the incompatible element enrichments of the Solander rocks are inconsistent with partial melting of newly underplated mafic lower crust; reproduction of their major element compositions would require unrealistically high degrees of partial melting. A similar argument precludes partial melting of the subducting oceanic crust and the inability to match the observed trace element patterns in the presence of residual garnet or plagioclase. Alternatively, an enriched end member of depleted MORB mantle source is inferred from Sr, Nd and Pb isotopic compositions, trace element enrichments and εHf ? 0 CHUR in detrital zircons, sourced from the volcanics. ¹⁰Be and Sr, Nd and Pb isotopic systematics are inconsistent with significant sediment involvement in the source region. The trace element enrichments and MORB-like Sr and Nd isotopic characteristics of the Solander rocks require a strong fractionation mechanism to impart the high incompatible element concentrations and subduction-related (e.g. high LILE/HFSE) geochemical signatures of the Solander magmas. Trace element modelling shows that this can be achieved by very low degrees of melting of a peridotitic source enriched by the addition of a slab-derived melt. Subsequent open-system fractionation, involving a key role for mafic magma recharge, resulted in the evolved andesitic adakites.     

Metasomatism and the crystallization of zircon megacrysts in Archaean peridotites from the Lewisian complex,NW Scotland

Zircon megacrysts are locally abundant in 1–40 cm-thick orthopyroxenite veins within peridotite host rocks in the Archaean Lewisian gneiss complex from NW Scotland. The veins formed by metasomatic interaction between the ultramafic host and Si-rich melts are derived from partial melting of the adjacent granulite-facies orthogneisses. The interaction produced abundant orthopyroxene and, within the thicker veins, phlogopite, pargasite and feldspathic bearing assemblages. Two generations of zircon are present with up to 1 cm megacrystic zircon and a later smaller equant population located around the megacryst margins. Patterns of zoning, rare earth element abundance and oxygen isotopic compositions indicate that the megacrysts crystallized from crustal melts, whereas the equant zircon represents new neocryst growth and partial replacement of the megacryst zircon within the ultramafic host. Both zircon types have U–Pb ages of ca. 2464 Ma, broadly contemporaneous with granulite-facies events in the adjacent gneisses. Zircon megacrysts locally form?>?10% of the assemblage and may be associated to zones of localized nucleation or physically concentrated during movement of the siliceous melts. Their unusual size is linked to the suppression of zircon nucleation and increased Zr solubility in the Si-undersaturated melts. The metasomatism between crustal melts and peridotite may represent an analog for processes in the mantle wedge above subducting slabs. As such, the crystallization of abundant zircon in ultramafic host rocks has implications for geochemistry of melts generated in the mantle and the widely reported depletion of high field strength elements in arc magmas.     

重庆城口地区早前寒武系黑色岩系研究:(1)铂族元素成矿潜力评估

重庆城口地区从震旦统到下寒武统发育有丰富的黑色岩系,20世纪末期在该地区黑色岩系中开展了大量的铂族元素(PGE)的找矿工作,但是由于种种原因,关于该地区是否存在PGE矿化异常,还没有得到最终的结论.本次研究在PGE分析方法论证的基础上,进行了大量样品的PGE分析和微量元素分析.主要结论如下①区域上上震旦统槽区和断块区两套黑色岩系在原始的沉积环境和物源供给上有较大的差异,虽然槽区上震旦统的黑色岩系具有和下寒武统黑色岩系相似但强度较低的V-Cu-Y-Mo-U异常,但基本上不具有明显的PGE-Au-Ag异常.②断块区水井沱组黑色岩系和平剖面西段新发现的U-V-Mo-PGE异常可能是今后工作的重点,Pt＋Pd最高达248.9×10-9,局部U-V都达到了工业品位.③槽区巴山组硅质岩四个剖面都揭示了在硅质岩中广泛存在连续的PGE异常,87个碳质硅质岩平均含Pt＋Pd 57.2×10-9,有10个样品Pt Pd》100×10-9,最高达196.5×10-9;大部分碳质硅质岩都具有不同程度的V-Cu-Y-Mo-Tl-U组合异常,V都达到了独立矿床的品位要求,其中猪草河、燕子河等剖面还存在厚度较大的富矿地段,特别是燕子河剖面,局部还存在REE＋Y的高异常,值得深入研究.④城巴地区下寒武统黑色岩系存在广泛的PGE异常,但没有达到PGE的矿化要求,建议加强该地区的钒矿和铀矿勘探研究,PGE可以综合评价.     

银额盆地哈日凹陷油气成藏条件及成藏模式

近年来,银额盆地哈日凹陷的油气勘探呈现出良好的态势,但对于哈日凹陷油气成藏条件相关研究甚少,已不能满足目前油气勘探开发的需求。本研究基于钻录井、地球物理、分析化验等资料,系统分析哈日凹陷油气成藏的烃源岩、储层、圈闭等条件,总结油气成藏条件配置关系,以期为哈日凹陷的后续油气勘探及地质研究提供依据。哈日凹陷主要发育三套烃源岩,其中银根组烃源岩有机质丰度极高,成熟度较低,有机质类型为Ⅰ-Ⅱ1型;巴二段烃源岩有机质丰度较高,成熟-高成熟,有机质类型为Ⅱ1-Ⅱ2型;巴一段烃源岩有机质丰度中等,成熟-高成熟,有机质类型为Ⅱ1-Ⅱ2型。储层类型为砂（砾）岩常规储层、碳酸质泥岩非常规储层和火山岩储层,且均属于特低孔超低渗储层,其中砂、砾岩储层和灰质泥岩储层物性最好,白云岩储层和火成岩储层次之,目前主力油藏主要集中在砂、砾岩储层和灰质泥岩储层这两种类型中。哈日凹陷主要发育两套岩性圈闭,即巴一段砂岩岩性圈闭和巴二段泥岩岩性圈闭,形成了源内（准）连续成藏模式和近源不连续成藏模式。     

河南嵩县南岭超贫磁铁矿的地质特征与找矿模式

随着国民经济的快速发展,传统的铁矿资源越来越紧缺,迫切需要寻找和开发非传统的铁矿资源。河南嵩县南岭超贫磁铁矿(mFe,其含量为10.20%)品位低,易采易选,性质上可归属于非传统矿产资源。通过对南岭超贫磁铁矿的磁铁矿石、斜长角闪(片)岩化学成分的对比分析,结合矿区地质特征和矿体特征,对矿体进行n(Fe+Al+Ti)-n(Ca+Mg)和w(FeO+Fe2O3+TiO2)-w(Al2O3)-w(MgO)图解分析,结果显示南岭矿区的含磁铁斜长角闪(片)岩和斜长角闪(片)岩是大洋富铁拉斑玄武岩经变质作用而形成的,矿床的成因类型为风化残积型超贫铁矿床。进一步厘定了找矿标志,建立了找矿模式,对寻找南岭型铁矿有一定的借鉴意义。     

深层地热水开采与地面沉降的关系研究

本文根据天津塘沽区深层地沉观测标观测到的地面沉降数据,分析了深层地下热水开采对地面沉降的影响比例.在分析地热水开采引起地面沉降机理的基础上,通过统计回归方法建立了深层孔隙型地热水开采量与地面沉降量的相关模型;提出了进行地热尾水回灌和建立深层沉降监测网以加强综合研究的防治对策.     

水热条件下黄铁矿片、板状晶体的微结构

利用透射电子显微镜(TEM)系统观测了黄铁矿片、板状晶体的微结构,发现在水热条件下生成的黄铁矿片、板状晶体具有正方形、矩形等多种形貌。其中,正方形较多,矩形次之,另可见到一些其他不规则形状。黄铁矿片、板状晶生长完好,未见缺陷。经测定多数四边形片状黄铁矿的两组边分别平行(010)和(100),其生长晶面为(001);个别四边形片状黄铁矿的两组边分别平行(010)和(101),其生长晶面为(101),矩形片状黄铁矿长轴生长方向为001。在水热条件下黄铁矿以多形貌出现,黄铁矿的片、板状晶体多数是沿(001)面生长的结果,(001)为黄铁矿片、板状晶体的主要二维生长面,并沿001方向扩展,构成了二维晶体。     

Differences in grain growth of calcite: a field-based modeling approach

Normal grain growth of calcite was investigated by combining grain size analysis of calcite across the contact aureole of the Adamello pluton, and grain growth modeling based on a thermal model of the surroundings of the pluton. In an unbiased model system, i.e., location dependent variations in temperature-time path, 2/3 and 1/3 of grain growth occurs during pro- and retrograde metamorphism at all locations, respectively. In contrast to this idealized situation, in the field example three groups can be distinguished, which are characterized by variations in their grain size versus temperature relationships: Group I occurs at low temperatures and the grain size remains constant because nano-scale second phase particles of organic origin inhibit grain growth in the calcite aggregates under these conditions. In the presence of an aqueous fluid, these second phases decay at a temperature of about 350 °C enabling the onset of grain growth in calcite. In the following growth period, fluid-enhanced group II and slower group III growth occurs. For group II a continuous and intense grain size increase with T is typical while the grain growth decreases with T for group III. None of the observed trends correlate with experimentally based grain growth kinetics, probably due to differences between nature and experiment which have not yet been investigated (e.g., porosity, second phases). Therefore, grain growth modeling was used to iteratively improve the correlation between measured and modeled grain sizes by optimizing activation energy (Q), pre-exponential factor (k₀) and grain size exponent (n). For n=2, Q of 350 kJ/mol, k₀ of 1.7×10²¹ mⁿs^–1 and Q of 35 kJ/mol, k₀ of 2.5×10^-5 mⁿs^–1 were obtained for group II and III, respectively. With respect to future work, field-data based grain growth modeling might be a promising tool for investigating the influences of secondary effects like porosity and second phases on grain growth in nature, and to unravel differences between nature and experiment.Editorial responsibility: J. Hoefs     

遵义牛蹄塘组发现的多水硫磷铝石

遵义牛蹄塘组黑色岩系发现的多水硫磷铝石主要产出在Ni-Mo多金属层的微裂隙中，偶尔在多金属层下部的黑色粉砂岩中以脉体形式产出。该矿物结构不稳定，结构中一部分水分子很容易失去，在X射线衍射鉴定时其特征谱线变化较大；在自然条件下存放一定时间后，样品具有稳定的X射线衍射特征。此外，对这些样品进行了红外光谱、热重和差热分析、TEM观测、化学分析和晶胞参数计算，与纤磷铝石进行了对比和讨论。     

Cognate clinopyroxene from Paleogene mantle xenolith-bearing basanite lavas (East Serbia, SE Europe): the role of dissolution of mantle orthopyroxene

The study focuses on clinopyroxene from mantle xenolith-bearing East Serbian basanites and suggests that dissolution of mantle orthopyroxene played an important role in at least some stages of the crystallization of these alkaline magmas. Five compositional types of clinopyroxene are distinguished, some of them having different textural forms: megacrysts (Type-A), green/colourless-cored phenocrysts (Type-B), overgrowths and sieve-textured cores (Type-C), rims and matrix clinopyroxene (Type-D), and clinopyroxene from the reaction rims around orthopyroxene xenocrysts (Type-E). Type-A is high-Al diopside that probably crystallized at near-liquidus conditions either directly from the host basanite or from compositionally similar magmas in previous magmatic episodes. Type-B cores show high ^VIAl/^IVAl≥1 and low Mg# of mostly <75 and are interpreted as typical xenocrysts. Type-C, D and E are interpreted as typical cognate clinopyroxene. Type-D has Mg#<78, Al₂O₃?=?6–13?wt.%, TiO₂?=?1.5–4.5?wt.%, and Na₂O?=?0.4–0.8?wt.% and compositionally similar clinopyroxene is calculated by MELTS as a phase in equilibrium with the last 30?% of melt starting from the average host lava composition. Type-C has Mg#?=?72–89, Al₂O₃?=?4.5–9.5?wt.%, TiO₂?=?1–2.5?wt.%, Na₂O?=?0.35–1?wt.% and Cr₂O₃?=?0.1–1.5?wt.%. This clinopyroxene has some compositional similarities to Type-E occurring exclusively around mantle orthopyroxene. Cr/Al vs Al/Ti and Cr/Al vs Na/Ti plots revealed that Type-C clinopyroxene can crystallize from a mixture of the host basanite magma and 2–20?wt.% mantle orthopyroxene. Sieve-textured Type-C crystals show characteristics of experimentally produced skeletal clinopyroxene formed by orthopyroxene dissolution suggesting that crystallization of Type-C was both texturally and compositionally controlled by orthopyroxene breakdown. According to FeO/MgO^cpx/melt modelling the first clinopyroxene precipitating from the host basanite was Type-A (T?~?1250?°C, p?~?1.5?GPa). Dissolution of orthopyroxene produced decreasing FeO/MgO^melt and crystallization of Type-E and sieve-textured Type-C clinopyroxene (0.3–0.8?GPa and 1200–1050?°C). The melt composition gradually shifted towards higher FeO/MgO^melt ratios precipitating more evolved Type-C and Type-D approaching near-solidus conditions (<0.3?GPa; ~950?°C).