Zircon saturation revisited: temperature and composition effects in a variety of crustal magma types

Hydrothermal experiments in the temperature range 750–1020°C have defined the saturation behavior of zircon in crustal anatectic melts as a function of both temperature and composition. The results provide a model of zircon solubility given by: In D_Zr^zircon/melt= ?3.80?[0.85(M?1)]+12900/T where D_Zr^zircon/melt is the concentration ratio of Zr in the stoichiometric zircon to that in the melt, T is the absolute temperature, and M is the cation ratio (Na + K + 2Ca)/(Al · Si). This solubility model is based principally upon experiments at 860°, 930°, and 1020°C, but has also been confirmed at temperatures up to 1500°C for M = 1.3. The lowest temperature experiments (750° and 800°C) yielded relatively imprecise, low solubilities, but the measured values (with assigned errors) are nevertheless in agreement with the predictions of the model.For M = 1.3 (a normal peraluminous granite), these results predict zircon solubilities ranging from ～ 100 ppm dissolved Zr at 750°C to 1330 ppm at 1020°C. Thus, in view of the substantial range of bulk Zr concentrations observed in crustal granitoids (～ 50–350 ppm), it is clear that anatectic magmas can show contrasting behavior toward zircon in the source rock. Those melts containing insufficient Zr for saturation in zircon during melting can have achieved that condition only by consuming all zircon in the source. On the other hand, melts with higher Zr contents (appropriate to saturation in zircon) must be regarded as incapable of dissolving additional zircon, whether it be located in the residual rocks or as crystals entrained in the departing melt fraction. This latter possibility is particularly interesting, inasmuch as the inability of a melt to consume zircon means that critical geochemical “indicators” contained in the undissolved zircon (e.g. heavy rare earths, Hf, U, Th, and radiogenic Pb) can equilibrate with the contacting melt only by solid-state diffusion, which may be slow relative to the time scale of the melting event.     

Asthenospheric parameters of dipping plate regions by magnetotelluric investigations

The multifrequency resolving capability of the electromagnetic surface impedance parameter, employed in magnetotelluric investigations, has been examined for an upper mantle model incorporating (1) a deep-seated lithosphere-asthenosphere boundary and (2) preferred orientations of olivine crystals in the lithosphere, usually associated with the subducting plate boundary zones. Numerical results display the quantitative errors in the resolution of various anisotropic and dipping plate conditions. It is found that (1) conductivity anisotropy, particularly with higher dips, causes a significant dispersion in the impedance values and higher resolving power, and (2) variations in the geometrical/physical parameters are reflected predominantly in the phase component of the surface impedance. The study has relevance to the understanding of the electrical nature of materials, its relationship with physical properties and associated geothermal and seismic activities in the dipping plate regions.     

Domain wall formation in minerals: I. theory of twin boundary shapes in Na-feldspar

Domains of triclinic Na-feldspar which are a direct consequence of structural strain are investigated theoretically. The following conclusions are arrived at. Only two types of twin walls are created by spontaneous strain, namely the Albite- and Pericline twin walls. If intersections occur, rounded corners are predicted. Any third domain wall close to such an intersection must bend into an S-shape. Narrow domains between two twin walls tend to become needle-shaped close to the intersection with a further, perpendicular, twin wall. The combination of the elastic stiffness coefficients c ₄₄ c ₆₆-c ₄₆ ² is expected to become small at temperatures near to the transition temperature. In the same temperature interval elastic fluctuations occur; their amplitudes and propagation directions are given.     

Dissolution kinetics of fosteritic olivine at 90-150 °C including effects of the presence of CO2

The steady state dissolution rate of San Carlos olivine [Mg_1.82Fe_0.18 SiO₄] in dilute aqueous solutions was measured at 90, 120, and 150 °C and pH ranging from 2 to 12.5. Dissolution experiments were performed in a stirred flow-through reactor, under either a nitrogen or carbon dioxide atmosphere at pressures between 15 and 180 bar. Low pH values were achieved either by adding HCl to the solution or by pressurising the reactor with CO₂, whereas high pH values were achieved by adding LiOH. Dissolution was stoichiometric for almost all experiments except for a brief start-up period. At all three temperatures, the dissolution rate decreases with increasing pH at acidic to neutral conditions with a slope of close to 0.5; by regressing all data for 2 ? pH ? 8.5 and 90 °C ? T ? 150 °C together, the following correlation for the dissolution rate in CO₂-free solutions is obtained: