Evidence for focused hot fluid flow within the Britannia Field, offshore Scotland, UK

Fluid inclusion and scanning electron microscope‐cathodoluminescence evidence indicates focused hot, saline, diagenetic fluid flow within the Eastern Flank of the Britannia Field, offshore Scotland, UK. The fluid was sourced from the Andrew Salt Dome, 10 km to the east. The fluids, which promoted quartz cementation of the upper zones within the field, were up to ～30°C hotter and had salinities up to ～10 wt% NaCl equivalent higher than fluids from lower in the reservoir section. During diagenesis hot saline fluids migrated westwards as part of a radiating ‘diagenetic front’ from the Andrew Salt Dome. Structural dip associated with the Eastern Flank of the Fladen Ground Spur impeded the westward movement of the diagenetic fluid. The quartz cements from the upper and lower reservoir zones can be distinguished by morphology. In the upper zones the quartz cements have well‐developed macro‐crystalline zoning and heterogeneous luminescence across the grain. In the lower zones, the cements are much less developed, unzoned and very weakly luminescent. The diagenetic fluids were primarily focused into Zone 45 within the upper reservoir. Furthermore, within the Main Platform Area the most prolific producing zone is Zone 45, indicating the importance of this interval as a permeable flow unit during both diagenetic and production timescales. Within the Eastern Flank, the quartz overgrowths have a major impact on reservoir permeability and thus well productivity. The overgrowths are most extensive in the originally clean sandstones with low clay content. Clay in optimum volumes (5–10%) can inhibit nucleation of the damaging quartz overgrowths without having a detrimental effect on pore connectivity. These observations provide a predictive concept for use in the search for relative reservoir sweetspots within the degraded Eastern Flank.     

Trace-element composition and zoning in clinopyroxene- and amphibole-group minerals: Implications for element partitioning and evolution of carbonatites

The present work is a first comprehensive study of the trace-element composition and zoning in clinopyroxene- and amphibole-group minerals from carbonatites, incorporating samples from 14 localities worldwide (Afrikanda, Aley, Alnö, Blue River, Eden Lake, Huayangchuan, Murun, Oka, Ozernaya Varaka, Ozernyi, Paint Lake, Pinghe, Prairie Lake, Turiy Mys). The new electron-microprobe data presented here significantly extend the known compositional range of clinopyroxenes and amphiboles from carbonatites. These data confirm that calcic and sodic clinopyroxenes from carbonatites are not separated by a compositional gap, instead forming an arcuate trend from nearly pure diopside through intermediate aegirine–augite compositions confined to a limited range of CaFeSi₂O₆ contents (15–45 mol%) to aegirine with < 25 mol% of CaMgSi₂O₆ and a negligible proportion of CaFeSi₂O₆. A large set of LA-ICPMS data shows that the clinopyroxenes of different composition are characterized by relatively low levels of Cr, Co and Ni (≤ 40 ppm) and manifold variations in the concentration of trivalent lithophile and some incompatible elements (1–150 ppm Sc, 26–6870 ppm V, 5–550 ppm Sr, 90–2360 ppm Zr, and nil to 150 ppm REE), recorded in some cases within a single crystal. The relative contribution of clinopyroxenes to the whole-rock Rb, Nb, Ta, Th and U budget is negligible. The major-element compositional range of amphiboles spans from alkali- and Al-poor members (tremolite) to Na–Al-rich Mg- or, less commonly, Fe-dominant members (magnesiohastingsite, hastingsite and pargasite), to calcic–sodic, sodic and potassic–sodic compositions intermediate between magnesio-ferrikatophorite, richterite, magnesioriebeckite, ferri-nyböite and (potassic-)magnesio-arfvedsonite. In comparison with the clinopyroxenes, the amphiboles contain similar levels of tetravalent high-field-strength elements (Ti, Zr and Hf) and compatible transition elements (Cr, Co and Ni), but are capable of incorporating much higher concentrations of Sc and incompatible elements (up to 500 ppm Sc, 43 ppm Rb, 1470 ppm Sr, 1230 ppm Ba, 80 ppm Pb, 1070 ppm REE, 140 ppm Y, and 180 ppm Nb). In some carbonatites, amphiboles contribute as much as 25% of the Zr + Hf, 15% of the Sr and 35% of the Rb + Ba whole-rock budget. Both clinopyroxenes and amphiboles may also host a significant share (~ 10%) of the bulk heavy-REE content. Our trace-element data show that the partitioning of REE between clinopyroxene (and, in some samples, amphibole) and the melt is clearly bimodal and requires a revision of the existing models assuming single-site REE partitioning. Clinopyroxenes and amphiboles from carbonatites exhibit a diversity of zoning patterns that cannot be explained exclusively on the basis of crystal chemistry and relative compatibility of different trace-element in these minerals. Paragenetic analysis indicates that in most cases, the observed zoning patterns develop in response to removal of selected trace elements by phases co-precipitating with clinopyroxene and amphibole (especially magnetite, fluorapatite, phlogopite and pyrochlore). With the exception of magnesiohastingsite–richterite sample from Afrikanda, the invariability of trace-element ratios in the majority of zoned clinopyroxene and amphibole crystals implies that fluids are not involved in the development of zoning in these minerals. The implications of the new trace-element data for mineral exploration targeting REE, Nb and other types of carbonatite-hosted rare-metal mineralization are discussed.     

The Mechanical Coupling of Fluid-Filled Granular Material Under Shear

The coupled mechanics of fluid-filled granular media controls the physics of many Earth systems, for example saturated soils, fault gouge, and landslide shear zones. It is well established that when the pore fluid pressure rises, the shear resistance of fluid-filled granular systems decreases, and, as a result, catastrophic events such as soil liquefaction, earthquakes, and accelerating landslides may be triggered. Alternatively, when the pore pressure drops, the shear resistance of these geosystems increases. Despite the great importance of the coupled mechanics of grain–fluid systems, the basic physics that controls this coupling is far from understood. Fundamental questions that must be addressed include: what are the processes that control pore fluid pressurization and depressurization in response to deformation of the granular skeleton? and how do variations of pore pressure affect the mechanical strength of the grains skeleton? To answer these questions, a formulation for the pore fluid pressure and flow has been developed from mass and momentum conservation, and is coupled with a granular dynamics algorithm that solves the grain dynamics, to form a fully coupled model. The pore fluid formulation reveals that the evolution of pore pressure obeys viscoelastic rheology in response to pore space variations. Under undrained conditions elastic-like behavior dominates and leads to a linear relationship between pore pressure and overall volumetric strain. Viscous-like behavior dominates under well-drained conditions and leads to a linear relationship between pore pressure and volumetric strain rate. Numerical simulations reveal the possibility of liquefaction under drained and initially over-compacted conditions, which were often believed to be resistant to liquefaction. Under such conditions liquefaction occurs during short compactive phases that punctuate the overall dilative trend. In addition, the previously recognized generation of elevated pore pressure under undrained compactive conditions is observed. Simulations also show that during liquefaction events stress chains are detached, the external load becomes completely supported by the pressurized pore fluid, and shear resistance vanishes.     

Bayesian data fusion in a spatial prediction context: a general formulation

In spite of the exponential growth in the amount of data that one may expect to provide greater modeling and predictions opportunities, the number and diversity of sources over which this information is fragmented is growing at an even faster rate. As a consequence, there is real need for methods that aim at reconciling them inside an epistemically sound theoretical framework. In a statistical spatial prediction framework, classical methods are based on a multivariate approach of the problem, at the price of strong modeling hypotheses. Though new avenues have been recently opened by focusing on the integration of uncertain data sources, to the best of our knowledges there have been no systematic attemps to explicitly account for information redundancy through a data fusion procedure. Starting from the simple concept of measurement errors, this paper proposes an approach for integrating multiple information processing as a part of the prediction process itself through a Bayesian approach. A general formulation is first proposed for deriving the prediction distribution of a continuous variable of interest at unsampled locations using on more or less uncertain (soft) information at neighboring locations. The case of multiple information is then considered, with a Bayesian solution to the problem of fusing multiple information that are provided as separate conditional probability distributions. Well-known methods and results are derived as limit cases. The convenient hypothesis of conditional independence is discussed by the light of information theory and maximum entropy principle, and a methodology is suggested for the optimal selection of the most informative subset of information, if needed. Based on a synthetic case study, an application of the methodology is presented and discussed.     

Gold–quartz deposits of the Zhdaninsky ore–placer cluster,eastern Yakutia: Structural control and formation conditions

Gold deposits and occurrences small in reserves and high in Au grade conventionally determine the line of prospecting in terrigenous sequences of the Verkhoyansk–Kolyma region. In this paper, the geological structure of such gold objects is considered with the example of the deposits and prospects making up the Zhdaninsky ore–placer cluster in the Republic of Sakha (Yakuia). From lithological, structural, and mineralogical–geochemical data, the formation conditions of ore-bearing complexes are specified, the geological evolution history of the northern Ol’chan Zone of the Kular–Nera Belt is reconstructed, and the zonal distribution of mineralization within the ore–placer cluster is revealed. The structural–compositional complexes were formed in the following succession: (1) sedimentation at the shelf of the passive margin accompanied by synsedimentation deformations; (2) metagenesis of sediments and the development of bedding-plane intraformational detachments of collision stage D₁ under conditions of tangential compression and accompanied by the formation of carbon dioxide–aqueous metamorphic fluid at a temperature of 300°C and under a pressure of 1.4 kbar; (3) folding and faulting of orogenic stage D₂ with the formation of synkinematic magmatic bodies, metasomatic alteration, and Au-bearig mineral assemblages. Small Au-bearing objects with veined mineralization and high Au grade are localized in structures of stage D₂ transverse to bedding-plane schistosity S₁. They form at the collision stage above intraformational detachment surfaces and are controlled by shear structures of the orogenic stage with misalignment of these deformations. The ore zoning is determined by the distribution of Co and Ni minerals and by variations in the anionic composition of ore (S, As, Sb).     

Mantle(?) xenoliths in the carbonatites of northern Transbaikalia

The composition and nature of high-Cr minerals in lithic clasts from the carbonatites of the Veseloe occurrence, northern Transbaikalia, were considered. In order to determine their source, the Cr-bearing phases were compared with chromite, magnetite, and rutile from ultrabasic rocks, mantle xenoliths, and eclogites. It was suggested that the xenoclasts studied were formed at great depths, whereas the carbonatites were directly derived from the mantle rather than formed by the crustal differentiation of a silicate-carbonate melt.     

X-ray transient sources

The galactic distribution and physical nature of X-ray transient sources is investigated. Two types of transients are considered. The observational data on 41 X-ray transient sources are given, and the average parameters of hard and soft X-ray transients are estimated.