Causes of Geochemical Diversity of Carbon Dioxide Water in Crystalline Rock Masses

The problem of the diversity of the geochemical types of carbon dioxide waters (CDW) in petrografically and mineralogically uniform crystalline rock masses is solved with allowance made for the effect of different boundary conditions (physicochemical parameters) on the geochemical effect of interaction in the rock–water system. The formation of the entire geochemical spectrum of CDW in crystalline rock masses is shown to be explicable on the basis of a model of interaction in granite–water systems at different mass ratios of reacting rock (S) and water (L), different temperatures T, and equilibrium concentrations of dissolved CO₂ (P _CO2).     

A canonical theory for short GPS baselines. Part II: the ambiguity precision and correlation

The present contribution is the second of four parts. It considers the precision and correlation of the least-squares estimators of the carrier phase ambiguities. It is shown how the precision and correlation of the double-differenced ambiguities as well as of the widelane ambiguities are effected by the observation weights, by the number of satellites tracked, by the number of observation epochs used, and by the change over time of the relative receiver-satellite geometry. Also the ability of the widelane transformation to decorrelate and to improve the precision is investigated. Received: 16 July 1996 / Accepted: 14 November 1996     

Doppler radar spectral width broadening due to beamwidth and wind shear

The spectral width observed by Doppler radars can be due to several effects including the atmospheric turbulence within the radar sample volume plus effects associated with the background flow and the radar geometry and configuration. This study re-examines simple models for the effects due to finite beam-width and vertical shear of the horizontal wind. Analytic solutions of 1- and 2-dimensional models are presented. Comparisons of the simple 2-dimensional model with numerical integrations of a 3-dimensional model with a symmetrical Gaussian beam show that the 2-dimensional model is usually adequate. The solution of the 2-dimensional model gives a formula that can be applied easily to large data sets. Analysis of the analytic solutions of the 2-dimensional model for off-vertical beams reveals a term that has not been included in mathematical formulas for spectral broadening in the past. This term arises from the simultaneous effects of the changing geometry due to curvature within a finite beamwidth and the vertical wind shear. The magnitude of this effect can be comparable to that of the well-known effects of beam-broadening and wind shear, and since it can have either algebraic sign, it can significantly reduce (or increase) the expected spectral broadening, although under typical conditions it is smaller than the beam-broadening effect. The predictions of this simple model are found to be consistent with observations from the VHP radar at White Sands Missile Range, NM.     

Karst database development in Minnesota: design and data assembly

The Karst Feature Database (KFD) of Minnesota is a relational GIS-based Database Management System (DBMS). Previous karst feature datasets used inconsistent attributes to describe karst features in different areas of Minnesota. Existing metadata were modified and standardized to represent a comprehensive metadata for all the karst features in Minnesota. Microsoft Access 2000 and ArcView 3.2 were used to develop this working database. Existing county and sub-county karst feature datasets have been assembled into the KFD, which is capable of visualizing and analyzing the entire data set. By November 17 2002, 11,682 karst features were stored in the KFD of Minnesota. Data tables are stored in a Microsoft Access 2000 DBMS and linked to corresponding ArcView applications. The current KFD of Minnesota has been moved from a Windows NT server to a Windows 2000 Citrix server accessible to researchers and planners through networked interfaces.     

Helligkeitsschätzungen von 12 quasistellaren Objekten auf photographischen Himmelsaufnahmen

Twelve QSO's have been investigated for variability on plates of the “Sonneberger Himmelsüberwachung”. Besides for 3 C 273 and Ton 616 no variability exceeding the mean error (±0.08 mag for m < 17.0) was found. TON 616 shows variability of 0,4 mag on time scales from hours (1964 Apr. 15) to one year.     

Extraction and recovery of precious metals from electronic waste printed circuit boards by bioleaching acidophilic fungi

Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes.     

Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.     

Prediction of influence of global warming on biological cycle and carbon balance in forest ecosystems of the Volga River Basin

The gradient (ordination) analysis was used to find the tendencies and the rate of changes in discrete parameters of the cycle of forest phytomasses accompanying a growing thermoarid climatic trend. The prognostic estimates of biotic regulation of the carbon cycle by forest biogeocenoses according to the HadCM3 (version A2) climatic scenarios, describing the most powerful coming global warming, are presented.     

Diurnal variation of deep cloud systems over the Indian region using INSAT-1B pixel data

Summary Among the various time scales of deep clouds, diurnal variation is found to be prominent over the tropics. The present study examines the diurnal variation in the number and area cover associated with the cloud systems over the tropical Indian region using INSAT-1B pixel data. Three periods, namely, April–May 1988, July–August 1988, and January–February 1989 are considered. The dependence of diurnal characteristics on the temperature threshold, life duration and size of cloud systems, and land-sea contrast has been explored. The diurnal characteristics of cloud systems living for more than a day have been studied for the first time. It is shown that cloud systems exhibit strong diurnal dependence at the coldest temperature threshold used (201 K). Also, the diurnal variation is more for larger cloud systems and for longer living systems. In general, more deep cloud activity is found from the satellite data during the pre-dawn and early morning hours. Precipitation is enhanced during morning to early noon hours. Further, using data from a recent field experiment, clear evidence of diurnal variation in precipitation over the Bay of Bengal is also presented. Received March 20, 2000/Revised October 3, 2000