Fractional Crystallization and Liquid Immiscibility Processes in the Alkaline-Carbonatite Complex of Juqui (So Paulo, Brazil)

The Juqui circular intrusion, which is Cretaceous in age (130–135Ma), crops out in the Precambrian gneissic basement in Brazilover an area of 14 km2. It consists of olivine clinopyroxen-itecumulates (with minor olivine gabbros) in the northeastern sector(74 vol.%), whereas ijolites-melteigites-urtites (4%) and nephelinesyenites with minor essexites and syenodiorites (21%) outlinesubannular concentric patterns with an Mg-carbonatite core (1%), in the southwestern part of the complex. Petrographical, bulk rock, and mineral compositional trendsindicate that the origin of the complex can be largely accountedfor by shallow-level fractional crystallization of a carbonatedbasanitic parental magma. Such a magma was generated deep inthe subcontinental lithosphere by low-degree partial meltingof a garnet-phlogopite peridotite source. Mass-balance calculations in agreement with field volume estimatespermit definition of several fractionation stages of the magmaticevolution under nearly closed-system conditions, with inwarddevelopment of zonally arranged side-wall cumulates. These stagesinvolved: (1) fractionation from basanite to essexite magma(liquid fraction F = 33–5%) by crystallization of olivineclinopyroxenite plus minor olivine alkali gabbro cumulates;(2) derivation of the least differentiated mafic nepheline syenite(F = 5–5 %) from essexitic magma by subtraction of a syenodioriteassemblage; (3) exsolution of a carbonatite liquid (5%) froma CO₂-enriched mafic nepheline syenite magma, which also underwentcontinuous fractionation giving rise to ijolite-melteigite-urtitecumulates. The proportion of cumulus clinopyroxene and biotiteand intercumulus nepheline and alkali feldspar in these lastrocks, as well as the absence of alkalis in carbonatite, maybe attributed, at least in part, to loss of alkali-rich hydrousfluids released during and after the unmixing formation of thetwo conjugate liquids. The KD values determined for Mg-carbonatite/nepheline syeniteare lower (1–4–2–9) for light rare earth elements(LREE) than for REE from Eu to Yb (4–6–7–8),in contrast to recent experimental results (Hamilton et al.,1989). A possible explanation is that Juquia Mg-carbonatiterepresents an alreadydifferentiated magma, which underwent extensivefractionation of LREE-enriched calcite. In this way, the highvariability of K₀ REE patterns observed in several alkaline-carbonatitecomplexes can also be accounted for. The remarkably constant initial ⁸⁷Sr/⁸⁶Sr ratios (mostly between0–7052 and 0–7057) support the interpretation ofthe intrusion as having been generated by fractrional crystallizationand liquid immiscibility from a common parental magma. Iligherisotopic ratios (0–7060–0–7078), found mainlyin dykes and in the border facies of the intrusion, may be dueto contamination by the gecissic basement.     

Circannual Cycle and Oxygen Consumption in Eudendrium glomeratum (Cnidaria, Anthomedusae): Studies on a Shallow Water Population

Abstract. The oxygen consumption of Eudendrium glomeratum was measured monthly, throughout the period of active presence of the species in the field, to obtain indications on its physiological condition in the different phases of the cycle. Sets of one hundred polyps were assayed in the laboratory under normothermic (according to field temperature: 14–19°C) and hyperthermic conditions (22–25°C). The different response to identical temperatures at the extremes of the cycle, together with a differential ability to face stressful conditions in the same periods, suggests that other factors, besides temperature, regulate the seasonal cycle of Eudendrium glomeratum.     

Phytoplankton of the Barents Sea at the Polar Front in Spring

Oceanology - This paper describes the comprehensive studies of phytoplankton carried out in April 2018 in the northwestern Barents Sea, in the Polar Front region (74.8°–76.2° N), at...     

Seasonal soil water storage changes beneath central Amazonian rainforest and pasture

Evaporation and infiltration were compared for tropical rainforest and pasture, near to Manaus, Brazil from October 1990 to February 1992 using measurements of soil water storage over a depth of 2 m. The soil is a clayey oxisol of low water available capacity. In both of the dry seasons studied, the maximum change in soil water storage in the forest was 154 mm and in the pasture it was 131 and 112 mm. Similar behaviour of the soil water reservoir below forest and pasture in the wet season implied that differences in evaporation and drainage were small. In the dry season, soil water storage behaviour in the upper metre of the soil was similar but there were marked differences in the second metre. The pasture took up little water from below 1.5 m but the forest appeared to utilise all of the available water in the 2 m profile in both seasons.

The water balance of the 2 m profile showed that the pasture evaporation rate was equal to that of the forest until storage had decreased 80 mm from the maximum. There was then a decline in pasture evaporation rate to 1.2 mm day⁻¹ as the storage decreased by a further 50 mm. In contrast, the forest uptake rate remained above 3.5 mm day⁻¹ until storage had decreased 140 mm from the maximum (within 15 mm of the extraction limit), before declining abruptly to less than 1.5 mm day⁻¹. There was strong evidence that the forest was able to abstract water from depths greater than 3.6 m.

Spatial variability of soil water storage was significantly greater beneath the pasture than beneath the forest, particularly following rainfall events in the dry season. This was largely the result of redistribution of rainfall as local surface runoff. There was no evidence of redistribution or runoff in the forest.     

Investigation of a eutrophic tidal basin: part 1—factors affecting the distribution and biomass of macroalgae

The distribution and biomass of macroalgae, principally Enteromorpha spp., have been estimated in Langstone Harbour, a 19 km² tidal basin in southenrn England. Comprehensive mapping was carried out annually at the time of maximum biomass and monthly mapping of selected areas allowed seasonal changes to be studied. Aerial false-colour photography and ground-level mapping were used for assessing the area and density of cover of macroalgae, but have identified no continuous trends between 1973 and 1982. In nine years, some 48% of the intertidal mudflat has supported >75% macroalgal cover at some stage, but generally only one-third of this potential has been achieved annually. The average peak biomass was determined by a stratified sampling method and varied about a mean of 38.5 g dry weight per square metre and showed significant annual differences. The processes controlling macroalgal growth and distribution reviewed, but, in general, factors other than nutrient availability are effective in determining areas supporting high macroalgal cover in any particular year.     

Responses of marine phytoplankton in iron enrichment experiments in the northern North Sea and northeast Atlantic Ocean

Short-term iron enrichment experiments were carried out with samples collected in areas with different phytoplankton activity in the northern North Sea and northeast Atlantic Ocean in the summer of 1993. The research area was dominated by high numbers of pico-phytoplankton, up to 70,000 ml⁻¹. Maximum chlorophyll a concentrations varied from about 1.0 μg l⁻¹ in a high-reflectance zone (caused by loose coccoliths, remnants from a bloom of Emiliania huxleyi) and about 3.5 μg l⁻¹ in a zone in which the phytoplankton were growing, to about 0.5 μg l⁻¹ in the northeast Atlantic Ocean. From the high-reflectance zone to the northeast Atlantic Ocean, nitrate concentrations increased from 0.5 μM to 6.0 μM. Concentrations of reactive iron in surface water showed an opposite trend and decreased from about 2.6 nM in the high-reflectance zone to <1.0 nM in the northeast Atlantic Ocean. In the research area, no signs of true iron deficiency were found, but iron enrichments in the high-reflectance zone, numerically dominated by Synechococcus sp., resulted in increased nitrate uptake. Ammonium uptake was hardly affected. Strong support for the effect of Fe on cell physiology is given by the increase in the f-ratio. Net growth rates of the phytoplankton (changes in cell numbers over 24 h) were almost unchanged. Phytoplankton collected from the northeast Atlantic Ocean, did not show changes in the nitrogen metabolism upon addition of iron. Net growth rates in these incubations were low or negative, with only slightly higher values with additional iron.     

Geotechnical and geological properties of Mokattam limestones: Implications for conservation strategies for ancient Egyptian stone monuments

Geotechnical and geological properties of limestone samples from the Mokattam Quarry in Cairo, Egypt, were determined in order to provide prior information for the selection of suitable methods for the conservation of stone monuments around Cairo. A commercial chemical consolidant (Wacker OH 100) was applied to fill the pore spaces and to strengthen the weathered rock. Filling of pore spaces was confirmed by the decrease of both porosity and permeability of rock samples after the application of the consolidant. Analysis by mercury porosimeter showed most effective consolidation results for pore spaces from 0.75 to 1.0 µm in diameter, which were those mainly observed in the samples. Ultrasonic velocity did not show any significant evidence but an increase in strength, observed as an increase in the point load index after the consolidation process was completed, confirmed that the filling and consolidation process worked effectively. Point load testing can thus be used in preference when the number of samples available for laboratory testing is limited. From the color analysis, it was shown that there was no noticeable color change after the application of consolidant Wacker OH 100. The combinations of laboratory tests adopted in this study can be applicable to the planning of conservation of other stone monuments.     

Erosion rates and mechanisms of knickzone retreat inferred from 10Be measured across strong climate gradients on the northern and central Andes Western Escarpment

A steep escarpment edge, deep gorges and distinct knickzones in river profiles characterize the landscape on the Western Escarpment of the Andes between ~5°S and ~18°S (northern Peru to northern Chile). Strong north–south and east–west precipitation gradients are exploited in order to determine how climate affects denudation rates in three river basins spanning an otherwise relatively uniform geologic and geomorphologic setting. Late Miocene tectonics uplifted the Meseta/Altiplano plateau (~3000 m a.s.l.), which is underlain by a series of Tertiary volcanic‐volcanoclastic rocks. Streams on this plateau remain graded to the Late Miocene base level. Below the rim of the Meseta, streams have responded to this ramp uplift by incising deeply into fractured Mesozoic rocks via a series of steep, headward retreating knickzones that grade to the present‐day base level defined by the Pacific Ocean. It is found that the Tertiary units on the plateau function as cap‐rocks, which aid in the parallel retreat of the sharp escarpment edge and upper knickzone tips. ¹⁰Be‐derived catchment denudation rates of the Rio Piura (5°S), Rio Pisco (13°S) and Rio Lluta (18°S) average ~10 mm ky^?1 on the Meseta/Altiplano, irrespective of precipitation rates; whereas, downstream of the escarpment edge, denudation rates range from 10 mm ky^?1 to 250 mm ky^?1 and correlate positively with precipitation rates, but show no strong correlation with hillslope angles or channel steepness. These relationships are explained by the presence of a cap‐rock and climate‐driven fluvial incision that steepens hillslopes to near‐threshold conditions. Since escarpment retreat and the precipitation pattern were established at least in the Miocene, it is speculated that the present‐day distribution of morphology and denudation rates has probably remained largely unchanged during the past several millions of years as the knickzones have propagated headward into the plateau. Copyright © 2011 John Wiley & Sons, Ltd.