Terminal velocities of pure and hydrate coated CO2 droplets and CH4 bubbles rising in a simulated oceanic environment

Understanding the upward motion of CO₂ droplets or CH₄ bubbles in oceanic waters is prerequisite to predict the vertical distribution of the two most important greenhouse gases in the water column after these have been released from the seabed. One of the key parameters governing the fate of droplets or bubbles dissolving into the surrounding seawater as they rise, is the terminal velocity, u_T. The latter is strongly influenced by the ability of both compounds to form skins of gas hydrate, if pressure and temperature satisfy thermodynamic framework conditions. Experimental efforts aiming to elucidate the rise properties of CO₂ droplets and CH₄ bubbles and specifically the influence of hydrate skins open the possibility to obtain a parameterization of u_T applicable to both hydrate-coated and pure fluid particles of CH₄ and CO₂. With the present study, we report on experimentally determined terminal velocities of single CH₄ bubbles released to pressurized and temperature-regulated seawater. Hydrate skins were identified by high bubble sphericities and changed motion characteristics. Based on these experiments as well as published data on the rise of hydrate-coated and pure liquid CO₂ droplets and physical principles previously successfully used for clean bubbles near atmospheric pressures, a new parameterization of u_T is proposed. Model predictions show a good agreement with the data base established from the laboratory-based measurements.     

The Ctenophore,Beroe ovata Bruguière, 1789 – the New Invader in the Ecosystem of the Caspian Sea

Oceanology - In November 2020, the invasive ctenophore Beroe ovata Bruguière, 1789 was recorded in samples of gelatinous zooplankton from the northern and central parts of the Caspian Sea. The...     

Open-system chemical behavior in deep Wilcox Group mudstones,Texas Gulf Coast,USA

Wilcox Group mudstones have been mechanically and geochemically transformed over a temperature range of 20–200 °C. Our research controlled for provenance and age by sampling from five wells, parallel to the paleodepositional axis, all within the Houston delta system. Across the sampled depths, mudstone porosity has been reduced from ∼25 to <10% and bulk mineralogical change as documented by quantitative X-ray diffraction includes decreases in quartz, K-feldspar and kaolinite content whereas illite + illite − smectite, chlorite, and plagioclase increase. These mineral transformations transfer elements at a scale of less than 1 mm from one mineralogical form to another, however, X-ray fluorescence data suggest that among major elements only Al₂O₃ and TiO₂ are fully conserved within the system (trace-element ZrO₂ is also conserved). K₂O has been added to and SiO₂ released from the Wilcox Group mudstones. Cathodoluminescence and secondary electron imaging did not find this SiO₂ locally precipitated. We, therefore, document an open-system geochemical behavior.     

Rational noncompliance and the liquidation of Northeast groundfish resources

The results of a 2007 survey of fishers, managers, scientists, and enforcement officials indicate that noncompliance is a significant problem in the Northeast multispecies groundfish (NEGF) fishery, as it has been for at least 20 years. The percent of total harvest taken illegally is estimated to be 12–24%, which is significantly higher than estimates of 6–14% in the 1980s. Thirty-seven percent of fishers, 61% of fishery managers and 80% of fishery enforcement staff believe that “the combined adverse impact of all violations on the health and manageability of fish resources” is significant, highly significant, or extremely significant. Many fishers believe that illegal fishing will prevent them from ever benefiting from stock rebuilding programs.     

Reproductive cues in Panulirus ornatus

Two experiments were performed to assess the effect of photoperiod and temperature on spawning of Panulirus ornatus. In experiment 1, sexually mature lobsters taken from the wild during summer were held at one of two photoperiods, winter (13 Light: 11 Dark) and summer (14.5 Light:9.5 Dark). Additionally, lobsters were also exposed to either summer (29°C) or winter (24°C) average water temperatures. Spawning was significantly greater when animals were exposed to summer photoperiod than to winter photoperiod, irrespective of temperature. Although a higher percentage of lobsters spawned when placed under a higher temperature, this trend was not statistically significant. In experiment 2, sexually mature lobsters were taken from the wild during winter and exposed to the same two photoperiods as in experiment 1, at a summer equivalent temperature of 29°C. Breeding started earlier and was more successful at the summer photoperiod. Time to first breeding was 17 weeks after exposure to summer photoperiod, compared with less than 1 week in experiment 1, and did not occur until individuals had moulted. Moulting occurred in 81% of lobsters, primarily after an increase in temperature to 29°C. The time between moulting and mating was varied and there was no significant difference in moult frequency between the two experimental photoperiods. After the lobsters had moulted, breeding success was reached earlier if photoperiod was lengthened. Results suggest photoperiod is the primary cue for the onset of gonad maturity and mating activity, with temperature playing a less important role. Physiological rest and possibly a moult may be required between breeding seasons before spawning can occur. Furthermore, temperature may be an important cue for pre‐reproduction moulting.     

Cenozoic tectonics of Amazon Mouth Basin

 The Cenozoic shelf margin of the Amazon Mouth Basin is characterized by a thick prograding prism of siliciclastic sediments. This prism, composed mainly of Upper Miocene and younger sediments, overlies a Lower Tertiary carbonate shelf. Two tectonic–sedimentary models for the area were developed with the aid of new deep-reflection seismic data. Gravitational tectonics dominate the regional geological framework. Tensional stresses are created near the shelf margin, and compressional features dominate at the base of the slope. The morphology of this compressional zone is closely associated with the St. Paul Fracture Zone and the boundary between continental and oceanic crusts. Received: 20 August 1996 / Revision received: 11 June 1998     

Experimental investigations of the effect of cloud-medium modification by salt powders

The results of experimental investigations into the action of polydispersion salt powders on model cloud media are presented. The results of experiments show a considerable positive effect of the modification of convective clouds by salt powders in order to obtain additional precipitation. The introduction of polydispersion salt powder into a forming cloud medium leads to the appearance of large cloud droplets and to the droplet-spectrum broadening. This result is a positive factor for the stimulation of coagulation processes and further precipitation formation. No “overseeding” phenomenon (when, instead of the enlargement of droplets, their sizes decrease and the concentration of cloud droplets increases) is observed at rather high mass concentrations of the introduced powder.     

Microsporidan parasite Thelohania contejeani Henneguy from New Zealand freshwater crayfish

The sporozoan Thelohania contejeani Henneguy (Microsporida: Nosematidae) is recorded from Paranephrops zealandicus (White) for the first time. It is an intracellular parasite invading musculature throughout the crayfish, causing a gradual decrease in locomotor activity, and it may eventually cause the death of the host. Infected crayfish were found in the northern part of Leith Stream, Dunedin, where the infection rate reached a maximum of 20%. This parasite has formerly been recorded only from Northern Europe.