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991.
Amino acid nitrogen in atmospheric aerosols: Occurrence,sources and photochemical modification 总被引:2,自引:0,他引:2
The presence of amino acids in atmospheric precipitation and aerosols has been noted for many years, yet relatively little is known about these or other nitrogen containing organic compounds in the atmosphere. Marine and continental rainwater analyses indicate that atmospheric aerosols, and subsequently atmospheric precipitation, may contain substantial levels of free and combined amino acids. The most likely source of amino N in the remote marine atmosphere appears to be the injection of proteinaceous material through the action of bursting bubbles at the sea-air interface or the long range transport from terrestrial sources. The capacity of these substrates to undergo photooxidation and photodegradation in the atmosphere to simpler species, such as ammonium ions, carboxylic acids, and for the S containing amino acids, oxidized forms of sulfur, has received little attention from atmospheric chemists. The photochemistry of covalently bound amino groups, particularly as found in peptides and amino acids, is discussed here with the purpose of summarizing what is known of their occurrence and their possible importance to atmospheric chemistry. 相似文献
992.
993.
James Flocks Michael D. Miner David C. Twichell Dawn L. Lavoie Jack Kindinger 《Geo-Marine Letters》2009,29(6):359-378
The barrier-island systems of the Mississippi River Delta plain are currently undergoing some of the highest rates of shoreline
retreat in North America (~20 m/year). Effective management of this coastal area requires an understanding of the processes
involved in shoreline erosion and measures that can be enacted to reduce loss. The dominant stratigraphy of the delta plain
is fluvial mud (silts and clays), delivered in suspension via a series of shallow-water delta lobes that prograded across
the shelf throughout the Holocene. Abandonment of a delta lobe through avulsion leads to rapid land subsidence through compaction
within the muddy framework. As the deltaic headland subsides below sea level, the marine environment transgresses the bays
and wetlands, reworking the available sands into transgressive barrier shorelines. This natural process is further complicated
by numerous factors: (1) global sea-level rise; (2) reduced sediment load within the Mississippi River; (3) diversion of the
sediment load away from the barrier shorelines to the deep shelf; (4) storm-induced erosion; and (5) human alteration of the
littoral process through the construction of hardened shorelines, canals, and other activities. This suite of factors has
led to the deterioration of the barrier-island systems that protect interior wetlands and human infrastructure from normal
wave activity and periodic storm impact. Interior wetland loss results in an increased tidal prism and inlet cross-sectional
areas, and expanding ebb-tidal deltas, which removes sand from the littoral processes through diversion and sequestration.
Shoreface erosion of the deltaic headlands does not provide sufficient sand to balance the loss, resulting in thinning and
dislocation of the islands. Abatement measures include replenishing lost sediment with similar material, excavated from discrete
sandy deposits within the muddy delta plain. These sand bodies were deposited by the same cyclical processes that formed the
barrier islands, and understanding these processes is necessary to characterize their location, extent, and resource potential.
In this paper we demonstrate the dominant fluvial and marine-transgressive depositional processes that occur on the inner
shelf, and identify the preservation and resource potential of fluvio-deltaic deposits for coastal management in Louisiana. 相似文献
994.
A study of an expanding seagrass bed on the south-west coast of British Columbia, Canada involved documentation and explanation of the pattern of expansion of the vegetation as well as documentation and experimental investigation of the accompanying changes in the distribution of infaunal invertebrates. Expansion followed a major environmental change, improved water clarity initiated in 1969 when a causeway blocked access to the site for silty Fraser River water. The original eelgrass (Zostera marina) bed expanded landward over 30 m year−1, probably causing more and more water to be retained in the bed at low tide and thus improving its own habitat. More rapid expansion occurred from 1979–1983 after Z.japonica colonized at the landward edge of the eelgrass bed and in a separate intertidal area. Expansion ceased around 1983 coincident with, but probably independent of, further construction.Burrowing shrimp (Callianassa californiensis) decreased in abundance between 1977 and 1984 in areas where the two seagrasses colonized. Short-term experiment over one summer and fall showed that removal of all shoots allowed adult shrimp and tube worms to colonize the sediment while addition of shoots of Z. japonica by transplanting caused temporary decreases in shrimp abundance. After a few weeks an established shrimp population destroyed the transplants. Among reasonable alternate hypotheses for the decline in Callianassa, the effect of sediment texture can be eliminated, but either direct negative effects of seagrass, i.e. inhibition of the burrowing of adult shrimp or of settlement of juveniles, or indirect effects, i.e. the harboring of more predators of shrimp in seagrass beds, deserve further study. 相似文献
995.
This paper addresses temporal variability in bottom hypoxia in broad shallow areas of Mobile Bay, Alabama. Time-series data
collected in the summer of 2004 from one station (mean depth of 4 m) exhibit bottom dissolved oxygen (DO) variations associated
with various time scales of hours to days. Despite a large velocity shear, stratification was strong enough to suppress vertical
mixing most of the time. Bottom DO was closely related to the vertical salinity gradient (ΔS). Hypoxia seldom occurred when
ΔS (over 2.5 m) was <2 psu and occurred almost all the time when ΔS was >8 psu in the absence of extreme events like hurricanes.
Oxygen balance between vertical mixing and total oxygen demand was considered for bottom water from which oxygen demand and
diffusive oxygen flux were estimated. The estimated decay rates at 20°C ranging between 0.175–0.322 d−1 and the corresponding oxygen consumption as large as 7.4 g O2 m−2 d−1 fall at the upper limit of previously reported ranges. The diffusive oxygen flux and the corresponding vertical diffusivity
estimated for well mixed conditions range between 8.6–9.5 g O2 m−2 d−1 and 2.6–2.9 m2 d−1, respectively. Mobile Bay hypoxia is likely to be associated with a large oxygen demand, supported by both water column and
sediment oxygen demands, so that oxygen supply from surface water during destratification events would be quickly exhausted
to return to hypoxic conditions within a few hours to days after destratification events are terminated. 相似文献
996.
A radiative-conductive model for the prediction of radiation fog 总被引:2,自引:0,他引:2
A conductive-radiative model is used to predict the formation and growth of radiation fog. This is accomplished by solving numerically the heat and mass transport equations in conjunction with an approximate form of the radiative transfer equation. The equations of motion in simplified form are included in the physical system to make use of Blackadar's (1962) formulation of the exchange coefficient of the boundary layer.It is found for a number of hypothetical test cases that the model gives results which appear to represent real physical conditions. One actual situation is tested. Results show that the model reproduces better than qualitatively those parameters which are obtained from routine observations. 相似文献
997.
998.
G. Franz D. Pudlo G. Urlacher U. Haussmann A. Boven K. Wemmer 《International Journal of Earth Sciences》1994,83(3):614-623
Field investigations, K-Ar age determinations and chemical data were used to describe the development of an intraplate volcanic province, the Darfur Dome, Sudan. Magmatism started 36 Ma ago at a small subvolcanic complex (Jebel Kussa) in the center of the dome and was active in the same area between 26 and 23 Ma. Two major volcanic fields (Marra Mountains and Tagabo Hills) developed between 16 and 10 Ma. Volcanism started again at 6.8 Ma with a third volcanic field (Meidob Hills) and at 4.3 Ma in the Marra Mountains and with the reactivation of the center. Activity then continued until the late Quaternary. Having started in the center of the Darfur Dome, volcanism moved in 36 Ma 200 km towards the NNE and 100 km SSW No essential difference in the alkaline magma types (basanitic to phonolitic-trachytic, with different amounts of assimilation of crustal material) in the different fields, was observed. Magmatism is thought to have been produced by a rising mantle plume and volcanism was triggered by stress resolution along the Central African Fault Zone. 相似文献
999.
G. A. Athanasopoulos 《Geotechnical and Geological Engineering》1994,12(2):122-132
Summary A review is presented of conceptual approaches that are currently in use for interpreting the operation of reinforced soil.
The concepts of enhanced confining pressure and of reduced normal tensile strains are found to be closely related to current
experimental and theoretical investigations as well as to the design methodologies available at present for reinforced soil
applications. Focusing on the enhanced confining pressure concept, analytical expressions are developed that allow the estimation
of the value of equivalent confining stress increase when the properties of soil and reinforcement and the state of stresses
acting on a cylindrical reinforced soil element are known. The derived expressions can also be utilized for estimating the
soil-reinforcement friction angle from the results of triaxial tests on cylindrical samples reinforced with horizontal layers
of reinforcement. 相似文献
1000.
Yu-Jie Hao Yun-Sheng Ren Ming-Xin Duan Xuan Zhao Qun Yang Kuang-Yin Tong Chao Li 《Arabian Journal of Geosciences》2016,9(15):655
The Zhengguang deposit, a representative large gold deposit in the Duobaoshan ore field in NE China, is located in the northeast of the Central Asian Orogenic Belt (CAOB). Ore body emplacement was structurally controlled and occurs mainly at the contact zone between the strata of Duobaoshan Formation and an Ordovician diorite stock. The diorite rocks have a close genetic relationship with Au mineralization. Re–Os isotope dating of Au-bearing pyrite yields an isochron age of 506 ± 44 Ma (MSWD = 15). Based on present and previous dating results, it can be concluded that the Zhengguang deposit formed at ~480 Ma. The mineralization time of the Zhengguang deposit is nearly identical to those of the Duobaoshan and Tongshan deposits, indicating they are all derived from the same metallogenic system. The Duobaoshan-style porphyry Cu–Mo mineralization may exist at deeper levels at Zhengguang. The geochemical characteristics of the Zhengguang dioritic rocks presented in this paper are similar to those of bajaitic high-Mg andesite, and the magmas originated from a mantle wedge metasomatized by melts from a subducting oceanic slab at an active continental margin setting. The Ordovician magmatic–metallogenic events in the Duobaoshan ore field were caused by the westward subduction of an oceanic slab located between the Xing’an and Songliao blocks. It is worth pointing out that the Zhengguang deposit is the oldest known Phanerozoic Au deposit in NE China. Further studies of this deposit will improve understanding of the regularity of ore formation and aid mineralization forecast across the Duobaoshan region. 相似文献