Interactions among metals in the spectrochemical determination of trace amounts of cadmium in marine mussels

The determination of trace amounts of inorganic elements by electrothermal atomic absorption spectrophotometry (ETA-AAS) or inductively coupled plasma atomic emission spectrometry (ICP-AES) suffers from some kinds of interference due to the inorganic fraction of the matrix of many environmental samples. The ratio between a major matrix element and the analyzed trace element plays an important role in the spectrochemical behaviour of the latter. The resulting enhancing or depressing effect also gives rise to severe faults when the well known standard addition method (SAM) is used. The present work shows the interactions due to the presence of elements such as calcium, sodium, potassium, magnesium and iron during the spectrochemical determinations of trace amounts of cadmium in marine mussels. A possible liquid anion exchange extraction is suggested for the analysis of cadmium by ETA-AAS.     

Hypothesis for a submarine landslide and cohesionless sediment flows resulting from a 17th century earthquake-triggered landslide in Quebec,Canada

Textural isotopic and microfossil data from two gravity cores obtained in Saguenay Fjord, Quebec, suggest that a distinctive sandy clay bed was deposited as the result of a major landslide in the Saguenay River basin. Pb-210 dating of the cores indicate that the bed is of similar age to the magnitude 7 earthquake of February 5, 1663. The slide involved sensitive marine clays and may have occurred in two stages. Slide sediments carried into the Saguenay River channel were probably reworked and subsequently transported down the Fjord basin as two distinct cohesionless mass flows. Fine clay laminae that overlie the older mass flow bed record the modulation of depositional processes by tidal currents for several weeks after this event.     

Sea-level, sediment supply and coastal changes: Examples from the coast of Ireland

Sediment supply and pre-existing shoreline morphology are crucial factors in controlling coastal changes due to sea-level rise. Using examples from both southeast and northeast Ireland, it can be shown that sea-level change may trigger a sequence of events which leads to both static and dynamic shoreline equilibrium. Cliff erosion and longshore sediment movement in east Co. Wexford has led to injection of sediment onto the shelf, and the growth, under both wave and tide regimes, of linear offshore shoals. These shoals now control the pattern of shoreline erosion and provide a template for possible stepwise evolution of the coast under any future sea-level rise. In contrast, the nearby coast of south Co. Wexford comprises a series of coarse clastic barriers moving monotonously onshore, via overwash processes. Here the behavior of the barrier is conditioned by the antecedent morphology of both the beach face and stream outlet bedforms. Finally, the rock platform coast of Co. Antrim presents a far more resistant shoreline to incident marine processes, yet even here there is strong evidence of present process control over so-called ‘raised’ platforms and embayments. It is concluded that coastal sediment supply and dynamics, together with coastal morphology and its interaction with waves, present a far more complex variety of sea-level indicators than is normally acknowledged.     

Seasonal Variation in the Biomass of Marine Macrophyta from Greek Coasts

Abstract. The marine plant communities of the littoral zone in different biotopes of the Greek coasts were investigated in 1980-81. Seasonal distribution and variation of marine plant biomass were assessed. The communities of Cystoseira crinita and C. compressa were outstanding with maximum biomass during the summer months. Corallina officinalis and Pterocladia capillacea + Viva rigida communities predominated with maximum biomass in autumn and exhibited a decrease in winter, except in stressed biotopes. The species diversity and productivity of seaweeds along the Greek coasts are interpreted in relation to a number of environmental parameters.     

Experimental study of the fine structure of the wind field near a rough surface

The air-flow velocity field near the water surface is studied in the zone of wind-wave intensification. Caused by a periodic separation of eddies, a nonzero time-averaged value of the wind velocity in the near-water streamline is detected at the leading slope of the wave. The distribution of pressure along the wave with allowance for the vertical velocity shear and disturbances produced by eddies and a periodic deceleration of the viscous layer was calculated with the aid of the Cauchy-Lagrange integral. This procedure made it possible to calculate the growth rate of the wave amplitude, whose value was found to be close to its experimental value at the initial stage of acceleration.     

Simulation of additive transport from the land surface on the basis of experimental data on heat transfer in the atmospheric surface layer

A method is proposed to study the transport of a passive additive in the atmospheric surface layer with the use of the atmospheric transfer function. This method makes it possible to estimate the spatial distribution of the concentration of a passive additive in the atmospheric surface layer from the additive’s surface source without experimentally determining the vertical profile of the transport coefficient or without resorting to various hypotheses for the character of its behavior. The transfer function, which contains the information on the wind-field structure, can be obtained from simple one-point measurements of surface-and air-temperature fluctuations and from subsequent spectral processing of the data. The effects of the wind-velocity profile and turbulence on the spatial distribution of additive concentration are assessed. This method allows one to simplify experiments during development and verification of the models of atmospheric diffusion. This method may also be useful in emergency situations to predict the propagation of hazardous additives.     

On the form of crests in limiting gravity waves

Properties of surface singularities and the form of wave crests of limiting gravity waves in steady-state flows of an ideal liquid are considered by analyzing the kinematic boundary condition. It is shown that, for rotational waves, the angle at the crest can have any value from 0° to 180°, while it has the only value 90° in the case of irrotational waves. Two inferences are made from Bernoulli’s integral and the properties of singularities: (i) the Stokes wave is a rotational wave and (ii) no angular points can appear on the profiles of capillary-gravity and capillary waves.     

Adaptive optimal control of an autonomous underwater vehicle in the dive plane using dorsal fins

In this paper, adaptive control of low speed bio-robotic autonomous underwater vehicles (BAUVs) in the dive plane using dorsal fins is considered. It is assumed that the model parameters are completely unknown and only the depth of the vehicle is measured for feedback. Two dorsal fins are mounted in the horizontal plane on either side of the BAUV. The normal force produced by the fins, when cambered, is used for the maneuvering. The BAUV model considered here is non-minimum phase. An indirect adaptive control system is designed for the depth control using the dorsal fins. The control system consists of a gradient based identifier for online parameter estimation, an observer for state estimation, and an optimal controller. Simulation results are presented which show that the adaptive control system accomplishes precise depth control of the BAUV using dorsal fins in spite of large uncertainties in the system parameters.