Methods developed earlier, based on hydration numbers for individual ionic species, have been extended to the calculation of ionic activity coefficients in aqueous systems of two electrolytes MX and NX2 with a common unhydrated anion (X−). The data required include the mean activity coefficients of MX and NX2 in the mixtures, together with the osmotic coefficient. The procedure is illustrated by a calculation of γNa, γMg, and γCl in a mixture of NaCl and MgCl2 closely approximating the composition of seawater with salinity of 35‰. 相似文献
In inviscid shallow water models currents generated by spatially uniform winds are transient and are eliminated by Rossby and equatorial Kelvin waves excited at the eastern and western coasts, respectively. The inclusion of mixing processes can lead to an entirely different steady state in which currents are present. It is shown that the mixing of heat affects the steady state more than does the mixing of momentum because the waves that are important in the oceanic adjustment are divergent. 相似文献
Small craft (<6·4 m) leeway is determined as a function of the wind speed in the range of 5–20 knots (3·6–10·3 m/sec). Leeway is calculated relative to the surface current by measurement of the separation distance of the small craft from a dyed patch of surface water at sea, using time-sequenced aerial photography. Leeway increases linearly with wind speed for small craft equipped with or without a sea anchor in the wind range studied. Leeway for small craft without sea anchor can be calculated from the equation UL = 0.07 UW + 0.04 where UW is the wind speed at 2 m elevation. Leeway for small craft drifted off the be calculated from the equation ULD = 0·05 UW − 0·12. The small craft drifted off the downwind direction in about 80% of the experiments. The drift angle is variable and difficult to predict. 相似文献
During a recent oceanographical-geophysical survey carried out in the southeastern part of the Gulf of Patras in Western Greece for the construction of an outfall, an active pockmark field was found. The pockmark field was formed in soft layered Holocene silts. The pockmarks are associated with acoustic anomalies attributed to gas-charged sediments. The pockmarks vary in size and shape from 25 to 250 m in diameter and from 0.5 to 15 m in depth and are among the largest and deepest observed in the world.
On July 14th, 1993, during the survey, a major earthquake of magnitude 5.4 on the Richter scale occurred in the area. During the 24 hour period prior to the earthquake the bottom water temperature anomalously increased on three occasions, whilst for a few days after the earthquake it was noted that the majority of the pockmarks were venting gas bublles.
It is considered that the three abrupt sea-water temperature increases were probably the result of upward migrating high-temperature gas bubbles in the water column. It is further suggested that the earthquake was the triggering mechanism and that the gas expulsion was caused by the reduction in the pore volume in the sediments resulting from changes in the stress regime prior to the earthquake. Therefore, it can be suggested that in seismic areas adjacent to pockmark fields, earthquake prediction may be achieved by monitoring the water temperature and/or the rate of gas venting in the pockmark field.
Our analysis indicates that the pockmark field in the Patras Gulf has formed slowly during the Holocene by continuous gas venting, which is periodically being interrupted by short-duration events of enhanced gas seepage triggered by earthquakes. 相似文献
Contamination of seismic reflection records at early times by first-order water reverberations can be especially severe during survey operations over hard and flat sea floors on the continental shelf or in lake environments. A new dereverberation scheme based on two classical techniques — predictive deconvolution and velocity filtering — has been developed to address this problem. The techniques are combined spatially to take advantage of their complementary offset- and time-dependent properties. Stage I of the scheme consists of applying predictive deconvolution at short offset. The data are previously conditioned by a normal moveout correction with the water velocity which restores the periodicity of the reverberations in the offset-time plane and enhances the performance of deconvolution. Stage II of the scheme involves velocity filtering in the common-midpoint domain which is particularly effective at long offset where the moveout difference between primary reflections and reverberations is largest. The dereverberation scheme is well suited for the initial processing of large volumes of data due to the general availability of cost-effective deconvolution and velocity filtering algorithms in seismic processing software packages. Practical implementation issues are illustrated by a field example from the GLIMPCE survey in Lake Superior.Lithoprobe Publication No. 475. 相似文献
In this paper, we describe a unique low frequency underwater sound source called the combustive sound source (CSS). In this device, a combustible gas mixture is captured in a combustion chamber and ignited with a spark. The ensuing combustion produces expanding gases which in turn produce high intensity, low frequency acoustic pulses. With high-speed motion pictures of the CSS event, we relate the motion of the bubble to the acoustic waveform. We also compare the measured first bubble period in the CSS pressure signature with the predictions of the Rayleigh-Willis equation, including the dependence of the radiated acoustic waveform on the volume and depth of the bubble. Measurements of the first bubble period agree with Rayleigh-Willis theory in trend, but not in absolute value. In addition, we discuss the variation of the acoustic output with the fuel/oxygen mixture. Finally, several other factors that affect the acoustic output of CSS are discussed. These include the shape of the CSS combustion chamber, the type of oxidizer and fuel, and the ignition source 相似文献
Abstract. The fauna — including macrofauna, meiofauna, and large ciliates — of floating cyanobacterial mats in a brackish shallow-water area was studied by analysing six 20 cm2 pieces of mat. Although these microbial aggregations were scarcely 1 cm thick, their total meiofauna abundance was about five times as high as in the uppermost 4 cm of the adjacent sediment. The mat fauna was dominated by harpacticoids, although large ciliates, rotifers, nematodes, and oligochaetes were also markedly more abundant than in the sediment. All species occurring in the mats were members of the surrounding sediment fauna. Out of the 47 species found, only a few, among them predominantly the harpacticoid, Mesochra lilljeborgi B oeck , 1864, and the nematode Daptonema setosum ( bütschli , 1874), accounted for the majority of the individual abundance in the mats. Both are regularly found in sulphidic biotopes near Hiddensee. As SEM micrographs revealed, the oligochaete Paranais litoralis (O. F. M üller , 1788) and the harpacticoid Cletocamptus confluens (Schmeil, 1894) were apparently optimal substrates for dense lawns of cyanobacteria. This indicates possible close interactions between the meiofauna and these microbiota. The frequent predation of histophagous ciliates on nematodes and harpacticoids, which were probably weakened by oxygen deficiency and/or high sulphide concentrations, were not only a sign of a generally neglected pathway in the food chain, but also impressively emphasized the huge variety of interactions taking place between meio- and microfauna within this specific benthic microcosm. Because of their floating character, the mats can play an important role in the dispersal of benthic fauna. 相似文献
The determination of trace amounts of inorganic elements by electrothermal atomic absorption spectrophotometry (ETA-AAS) or inductively coupled plasma atomic emission spectrometry (ICP-AES) suffers from some kinds of interference due to the inorganic fraction of the matrix of many environmental samples. The ratio between a major matrix element and the analyzed trace element plays an important role in the spectrochemical behaviour of the latter. The resulting enhancing or depressing effect also gives rise to severe faults when the well known standard addition method (SAM) is used. The present work shows the interactions due to the presence of elements such as calcium, sodium, potassium, magnesium and iron during the spectrochemical determinations of trace amounts of cadmium in marine mussels. A possible liquid anion exchange extraction is suggested for the analysis of cadmium by ETA-AAS. 相似文献