全文获取类型
收费全文 | 70379篇 |
免费 | 799篇 |
国内免费 | 1229篇 |
专业分类
测绘学 | 2544篇 |
大气科学 | 5207篇 |
地球物理 | 13864篇 |
地质学 | 27491篇 |
海洋学 | 4866篇 |
天文学 | 12741篇 |
综合类 | 2250篇 |
自然地理 | 3444篇 |
出版年
2021年 | 459篇 |
2020年 | 499篇 |
2019年 | 489篇 |
2018年 | 5683篇 |
2017年 | 4926篇 |
2016年 | 3794篇 |
2015年 | 986篇 |
2014年 | 1369篇 |
2013年 | 2377篇 |
2012年 | 2291篇 |
2011年 | 4416篇 |
2010年 | 3575篇 |
2009年 | 4482篇 |
2008年 | 3702篇 |
2007年 | 4117篇 |
2006年 | 1822篇 |
2005年 | 1501篇 |
2004年 | 1698篇 |
2003年 | 1623篇 |
2002年 | 1429篇 |
2001年 | 1125篇 |
2000年 | 1072篇 |
1999年 | 892篇 |
1998年 | 927篇 |
1997年 | 869篇 |
1996年 | 737篇 |
1995年 | 749篇 |
1994年 | 683篇 |
1993年 | 565篇 |
1992年 | 529篇 |
1991年 | 535篇 |
1990年 | 614篇 |
1989年 | 531篇 |
1988年 | 484篇 |
1987年 | 609篇 |
1986年 | 501篇 |
1985年 | 647篇 |
1984年 | 731篇 |
1983年 | 703篇 |
1982年 | 614篇 |
1981年 | 661篇 |
1980年 | 544篇 |
1979年 | 495篇 |
1978年 | 519篇 |
1977年 | 460篇 |
1976年 | 450篇 |
1975年 | 452篇 |
1974年 | 438篇 |
1973年 | 467篇 |
1971年 | 277篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
The paper presents lead isotope data from 211 samples from Phanerozoic lead-bearing ore occurrences in Central Europe, particularly from the Southern part of the former German Democratic Republic. The data are interpreted in terms of Amov's dynamic model of continuous lead isotope evolution. The relationships between thoro-genic and urano-genic model ages and the source of lead in different regional units are discussed. We observed differences in lead isotope evolution in the Hercynian internides and externides. Within the Moldanubian and Saxothuringian zones we distinguish five main lead-bearing ore associations: (1) Cambrian, stratiform base metal (Hermsdorf-Waldsassen; 206Pb/ 204Pb=17.50–17.70), (2) Devonian, vein type Sb-bearing, metamorphogene (neumühle-Hartmannsdorf; 17.80–18.00), (3) Upper Carboniferous-Permian, polymetallic, including tin, vein type (Kutna hora-Freiberg-Altenberg; 18.00–18.20), (4) Triassic (-Jurassic), Pb–Ba, vein type (Stibro-Halsbrücke; 18.20–18.60), (5) Cenozoic, polymetallic, vein type, riftogene (Roztoky-Banska tiavnica; 18.80–19.10). Pb isotope characteristics from ores of the Montagne Noire and the Brioude-Massiac district correspond to this subdivision. Ore associations from the Rheno-Hercynian zone display higher 207Pb/204Pb ratios which can be explained by more evolved and less metamorphosed source rocks. Mineralizations of the eastern Harz (Straßberg-Neudorf) belong to the Permian association, those from the western Harz (Clausthal-Bad Grund) to the Triassic-Jurassic. Because of Pb isotope agreement the stratabound Rammelsberg and the vein bound Ramsbeck-I mineralization are presumed to be isogenetic. Pb isotope identity of distinct mineralizations in the basement zone (Halsbrücke-Bad Grund) and in the Triassic sediments (Gorny Slask-Mechernich-Bleiglanzbänke) suggests a strong genetic coherence. Pb isotope conformity between the Upper Carboniferous-Permian-Triassic ore associations and Hercynian postkinematic granitoids, and lamprophyric rocks, also favours a close relationship. Pb isotope and other data indicate crustal sources. As the age of the ore associations decreases, crustal influences generally increase, apart from the Roztoky mineralization. 相似文献
82.
A principally new, quantitative system of the classification of the spectra of planetary nebulae is proposed. Spectral class of excitation class of the nebulap is determined according to the relative intensities of emission lines (N
1+N
2) [OIII]/4686 HeII and (N
1+N
2) [OIII]/H (Table I, Figure 1). The excitation classes are obtained for 142 planetary nebulae of all classes—low (p=1–3), middle (p=4–8), and high (p=9–12+) (Tables II, III, and IV). An empirical relationship between excitation classp and mean radius of nebulae
is discovered (Figure 2). This relationship as well as excitation classp, as an independend parameter, admit an evolutionary interpretation. It is shown that after reaching the highest class of excitationp=12+ the nebulae decrease their class of excitation with the further increases of sizes. The diagram of this relationship
has two nearly-symmetric branches — rising and descending with the apogee onp=12+ (Figure 2). 相似文献
83.
TS. G. Tsvetkov 《Astrophysics and Space Science》1988,150(2):223-234
On the basis of observational data for the absolute R and relative R/R amplitudes of variations in radius of galactic classical cepheids (55 stars from Balona and Stobie (1979) and 30 stars from Sollazzoet al. (1981)), four kinds of empirical linear relations are obtained: log(P V)–logR, logP–logR, log(P V)–log(R/R), and logP–log(R/R);P, R, and V are the pulsation periods, the mean stellar radii, and the amplitudes of light variations, respectively. Three groups of stars are considered: short-period cepheids (SPC)-with logP1.1; long-period cepheids (LPC)-with logP>1.1; and s-cepheids (sC). Both the R values and the R/R values increase withP andP V, for a given group of variables. A comparison is performed with our results obtained from data in other sources (Kurochkin, 1966; Gieren, 1982; etc.). The investigated relations can be applied for determining R and R/R of galactic classical cepheids, by using their observedP and V. All studied galactic classical cepheids have R/R<0.35, R<10R
for SPC and 10R
<R60R
for LPC. The sC have smaller R and R/R values than other classical cepheids, at the same periods (the difference is about 2 times for R and 1.4–2.8 times for R/R); the studied sC have R/R in the range 0.025–0.075 and R in the range 1–3R
(only Y Oph has R8R
). 相似文献
84.
Liouville's theorem for radiation, of which the generalized étendue is a consequence, implies 2 d2
d2
A = constant along the ray path, where is the refractive index and d2
and d2
A are the ranges, respectively, of solid angle and of area that define a ray (actually a bundle of rays). Implications of this concept on the propagation of radio waves from the actual to the apparent source in the solar corona (i.e., the scatter image of the true source) are discussed. The implications for sources of fundamental plasma radiation include: (1)The observed solid angle (defining the directivity) and apparent area A of the source are compatible with Liouville's theorem only if the apparent source (the scatter image of the true source) corresponds to the envelope of subsources with a small filling factor f. (2) The brightness temperature T
Bof the actual source is greater than that of the apparent source by f
-1. (3) For sources of fundamental plasma radiation the factor f is very small ( 10-2). (4) A long-standing discrepancy between the observed low value of T
B at meter/decameter wavelengths for the quiet Sun and the known coronal temperature may be resolved by noting that the implied coronal temperature is given by T
B
f and that the factor f must be significantly less than unity.A brief discussion is included of the relation between Liouville's theorem, the generalized étendue, Milne's laws, occupation numbers, extension in phase, and suppression of emission by a medium with refractive index unequal to unity. 相似文献
85.
G. R. Isaak 《Solar physics》1983,82(1-2):235-235
The size of the rotational splitting recently observed (Claverie et al., 1981) is correlated with the 12.2d variation in the measurements of solar oblateness observed by Dicke (1976) and implies a convection zone of depth of 0.1 R
. The near equality of amplitudes of global velocity oscillations (Claverie et al., 1981) of the various m components of the l = 1 and l = 2 modes as seen from the Earth viewing the Sun nearly along the equator is unexpected for pure rotational splitting. It is suggested that a magnetic perturbation is present and an oblique asymmetric magnetic rotator with magnetic fields of a few million gauss is responsible. A more detailed account was submitted to Nature.Proceedings of the 66th IAU Colloquium: Problems in Solar and Stellar Oscillations, held at the Crimean Astrophysical Observatory, U.S.S.R., 1–5 September, 1981. 相似文献
86.
The Culgoora radioheliograph has been modified for observing at 327.4 MHz, which is in addition to the three frequencies (43.25, 80, and 160 MHz) previously available. At the new frequency the array beamwidth is 56, which represents the highest resolution yet available for metre-wavelength solar mapping.At 327.4 MHz the sources of radio emission are mainly in the lowest layers of the corona. Some preliminary four-frequency observations have been made of type I storms. It is found that the source size generally decreases with increasing observing frequency. This result confirms earlier suggestions that the sources of both type I and type III emission are contained in structures whose boundaries diverge outwards in the corona. 相似文献
87.
G. Caro V.C. Bennett B. Bourdon T.M. Harrison A. von Quadt S.J. Mojzsis J.W. Harris 《Chemical Geology》2008,247(1-2):253-265
146Sm–142Nd and 147Sm–143Nd systematics were investigated in garnet inclusions in diamonds from Finsch (S. Africa) and Hadean zircons from Jack Hills (W. Australia) to assess the potential of these systems as recorders of early Earth evolution. The study of Finsch inclusions was conducted on a composite sample of 50 peridotitic pyropes with a Nd model age of 3.3 Ga. Analysis of the Jack Hills zircons was performed on 790 grains with ion microprobe 207Pb/206Pb spot ages from 3.95 to 4.19 Ga. Finsch pyropes yield 100 × ?142Nd = ? 6 ± 12 ppm, ?143Nd = ? 32.5, and 147Sm/144Nd = 0.1150. These results do not confirm previous claims for a 30 ppm 142Nd excess in South African cratonic mantle. The lack of a 142Nd anomaly in these inclusions suggests that isotopic heterogeneities created by early mantle differentiation were remixed at a very fine scale prior to isolation of the South African lithosphere. Alternatively, this result may indicate that only a fraction of the mantle experienced depletion during the first 400 Myr of its history. Analysis of the Jack Hills zircon composite yielded 100 × ?142Nd = 8 ± 10 ppm, ?143Nd = 45 ± 1, and 147Sm/144Nd = 0.5891. Back-calculation of this present-day ?143Nd yields an unrealistic estimate for the initial ?143Nd of ? 160 ?-units, clearly indicating post-crystallization disturbance of the 147Sm–143Nd system. Examination of 146,147Sm–142,143Nd data reveals that the Nd budget of the Jack Hills sample is dominated by non-radiogenic Nd, possibly contained in recrystallized zircon rims or secondary subsurface minerals. This secondary material is characterized by highly discordant U–Pb ages. Although the mass fraction of altered zircon is unlikely to exceed 5–10% of total sample, its high LREE content precludes a reliable evaluation of 146Sm–142Nd systematics in Jack Hills zircons. 相似文献
88.
David M. Hirsch 《Contributions to Mineralogy and Petrology》2008,155(4):401-415
Garnet-bearing schists from the Waterville Formation of south-central Maine provide an opportunity to examine the factors
governing porphyroblast size over a range of metamorphic grade. Three-dimensional sizes and locations for all garnet porphyroblasts
were determined for three samples along the metamorphic field gradient spanning lowest garnet through sillimanite grade, using
high-resolution X-ray computed tomography. Comparison of crystal size distributions to previous data sets obtained by stereological
methods for the same samples reveals significant differences in mode, mean, and shape of the distributions. Quantitative textural
analysis shows that the garnets in each rock crystallized in a diffusion-controlled nucleation and growth regime. In contrast
to the typical observation of a correlation between porphyroblast size and position along a metamorphic field gradient, porphyroblast
size of the lowest-grade specimen is intermediate between the high- and middle-grade specimens’ sizes. Mean porphyroblast
size does not correlate with peak temperatures from garnet-biotite Fe-Mg exchange thermometry, nor is post-crystallization
annealing (Ostwald Ripening) required to produce the observed textures, as was previously proposed for these rocks. Robust
pseudosection calculations fail to reproduce the observed garnet core compositions for two specimens, suggesting that these
calc-pelites experienced metasomatism. For each of these two specimens, Monte Carlo calculations suggest potential pre-metasomatism
bulk compositions that replicate garnet core compositions. Pseudosection analyses allow the estimation of the critical temperatures
for garnet growth: ∼481, ∼477, and ∼485°C for the lowest-garnet-zone, middle-garnet-zone, and sillimanite-zone specimens,
respectively. Porphyroblast size appears to be determined in this case by a combination of the heating rate during garnet
crystallization, the critical temperature for the garnet-forming reaction and the kinetics of nucleation. Numerical simulations
of thermally accelerated, diffusion-controlled nucleation, and growth for the three samples closely match measured crystal
size distributions. These observations and simulations suggest that previous hypotheses linking the garnet size primarily
to the temperature at the onset of porphyroblast nucleation can only partially explain the observed textures. Also important
in determining porphyroblast size are the heating rate and the distribution of favorable nucleation sites. 相似文献
89.
G. Ottonello 《Geochimica et cosmochimica acta》2008,72(24):5920-5934
The ground-state geometries, electronic energies and vibrational properties of carboxylic complexes of iron were investigated both in vacuo and under the effect of a reaction field, to determine thermodynamic properties of iron-acetates and the role of the carboxylic functional on the isotopic imprinting of this metal in metalorganic complexation. The electronic energy, zero point corrections and thermal corrections of these substances at variational state were investigated at the DFT/B3LYP level of theory with different basis set expansions and the effect of the reaction field on the variational structures was investigated through the Polarized Continuun Model. Thermochemical cycle calculations, combined with solvation energy calculations and appropriate scaling from absolute to conventional properties allowed to compute the Gibbs free energy of formation from the elements of the investigated aqueous species and to select the best procedure to be applied in the successive vibrational analysis. The best compliance with the few existing thermodynamic data for these substances was obtained by coupling the gas phase calculations at DFT/B3LYP level with the [6-31G(d,p)]-[6-31G+(d,p)] (for cations and neutral molecules - anions; respectively) with solvation calculations adopting atomic radii optimized for the HF/6-31G(d) level of theory (UAHF). A vibrational analysis conducted on 54Fe, 56Fe, 57Fe and 58Fe gaseous isotopomers yielded reduced partition function ratios which increased not only with the nominal valence of the central cation, as expected, but, more importantly, with the extent of the complexation operated by the organic functional. Coupling thermodynamic data with separative effects it was shown that this last is controlled, as expected, by the relative bond strength of the complex in both aggregation states. Through the Integral Equation Formalism of the Polarized Continuum Model (IEFPCM) the effect of the ionic strength of the solution and of a T-dependent permittivity on the energy and separative effects of the solvated metalorganic complexes were analyzed in detail. The solvent effect in the standard state (hypothetical one-molal solution referred to infinite dilution; T = 298.15 K, P = 1 bar) is a limited reduction of the separative effects of all the isotopomeric couples. With an increase in T (and the concomitant decrease in the dielectric constant of the solvent) this effect diminishes progressively. 相似文献
90.
Thermodynamic model for arsenic speciation in sulfidic waters: A novel use of ab initio computations
Recent discoveries demonstrate that the chemistry of arsenic in sulfidic waters is much more complex that previously believed. One implication is that all earlier thermodynamic data on stabilities of As thioanions require revision. Previously used experimental approaches for determining As thioanion stabilities may be inadequate to deal with the full range of complexity. Here we use computational as well as empirical information to construct a provisional model for equilibrium As thioanion distributions in sulfidic waters. Whereas previous authors have argued for either As(III) or As(V) thioanions, the new model predicts that both are important and can occur simultaneously under commonly encountered pH and ΣS−II conditions. At the order of magnitude level, the model reasonably predicts the solubility of As2S3 in sulfidic solutions, provides tentative peak assignments for published Raman spectroscopic data and plausibly accounts for how sulfide modifies the bacterial toxicity of As. The model yields a thermodynamic justification for how sulfide, which is usually regarded as a reducing agent, can counter-intuitively drive oxidation of As(III) to As(V), as has been observed both in the laboratory and in the field. Despite its uncertain accuracy, the model serves as a useful source of new, testable hypotheses about As geochemistry and highlights crucial experimental data needs. 相似文献