Does suspended matter drained from the Isahaya freshwater reservoir cause organic enrichment in the northern Ariake Bay?

The inner part of Isahaya Bay was converted to a freshwater reservoir following the closure of the land claim dike in 1997. Turbid water drains into Isahaya Bay when water levels increase. We investigated whether particulate organic matter (POM) from the reservoir in Isahaya Bay has caused bottom organic enrichment in the northern part of Ariake Bay. Using potential end-members from before to after the rainy seasons, during which a frequent discharge from the reservoir was expected, stable isotope analyses were performed on sediments collected from Isahaya Bay and northern Ariake Bay. Each end-member was isotopically differentiated by δ¹³C and δ¹⁵N (riverine POM: ?28.5 to ?27.2‰ and 3.3–4.6‰; reservoir POM: ?25.7 to ?25.3‰ and 7.4–8.4‰; marine POM: ?21.8 to ?19.7‰ and 6.7–7.6‰; microphytobenthos estimated from consumers: ?16.1 to ?15.9‰ and 5.2–6.1‰, respectively). Sediment isotopic signatures fell within the mixing space defined by the signatures of the end-members. Marine POM contributed greatly to bottom sediments in both seasons in Isahaya Bay and Ariake Bay, ranging from ca. 60–70 and 40–60%, respectively. Reservoir POM contributed around 10% to bottom sediments. This percentage slightly increased in the sediment of Isahaya Bay after the rainy season, but decreased in the sediment of Ariake Bay. Thus, most of the POM discharged from the reservoir would not reach the northern part of Ariake Bay and would not be a major contributor to organic enrichment. This study is the first to quantitatively describe the contribution of drained reservoir POM outside Isahaya Bay.     

Three‐dimensional texture of natural pseudotachylyte: Pseudotachylyte formation mechanism in hydrous accretionary complex

Melt‐origin pseudotachylyte is the most reliable seismogenic fault rock. It is commonly believed that pseudotachylyte generation is rare in the plate subduction zone where interstitial fluids are abundant and can trigger dynamic fault‐weakening mechanisms such as thermal pressurization. Some recent studies, however, have discovered pseudotachylyte‐bearing faults in exhumed ancient accretionary complexes, indicating that frictional melting also occurrs during earthquakes in subduction zones. To clarify the pseudotachylyte generation mechanism and the variation of slip behavior in the plate subduction zone, a pseudotachylyte found in the exhumed fossil accretionary complex (the Shimanto Belt, Nobeoka, Japan) was re‐focused and microscopic and three‐dimensional observations of the pseudotachylyte‐bearing fault were performed based on optical, electron, and X‐ray microscope images. Based on the patterns contained in the fragment, the pseudotachylyte is divided into four domains, although no clear domain boundaries or layering structures are not found. Three‐dimensional observation also suggests that the pseudotachylyte were fragmented or isolated by cataclasite or carbonate breccia. The pseudotachylyte was rather injected into the surrounding carbonate breccia, which is composed of angular fragments of the host rock and a matrix of tiny crystalline carbonate. The pseudotachylyte volume was extracted from the X‐ray microscope image and the heat abundance consumed by the pseudotachylyte generation was estimated at 2.18 MJ/m², which can be supplied during a slip of approximately 0.5 m. These observations and calculations, together with the results of the previous investigations, suggest hydrofracturing and rapid carbonate precipitation that preceded or accompanied the frictional melting. Dynamic hydrofracturing during a slip can be caused by rapid fluid pressurization, and can induce abrupt decrease in fluid pressure while drastically enhancing the shear strength of the shear zone. Consequently, frictional heating would be reactivated and generate the pseudotachylyte. These deformation processes can explain pseudotachylyte generation in hydrous faults with the impermeable wall rock.     

Coexisting different types of zoned garnet in kyanite‐quartz eclogites from the Sanbagawa metamorphic belt: Evidence of deformation‐induced lithological mixing during prograde metamorphism

Garnet grains in Sanbagawa quartz eclogites from the Besshi region, central Shikoku commonly show a zoning pattern consisting of core and mantle/rim that formed during two prograde stages of eclogite and subsequent epidote–amphibolite facies metamorphism, respectively. Garnet grains in the quartz eclogites are grouped into four types (I, II, III, and IV) according to the compositional trends of their cores. Type I garnet is most common and sometimes coexists with other types of garnet in a thin section. Type I core formed with epidote and kyanite during the prograde eclogite facies stage. The inner cores of types II and III crystallized within different whole‐rock compositions of epidote‐free and kyanite‐bearing eclogite and epidote‐ and kyanite‐free eclogite at the earlier prograde stage, respectively. The inner core of type IV probably formed during the pre‐eclogite facies stage. The inner cores of types II, III, and IV, which formed under different P–T conditions of prograde metamorphism and/or whole‐rock compositions, were juxtaposed with the core of type I, probably due to tectonic mixing of rocks at various points during the prograde eclogite facies stage. After these processes, they have shared the following same growth history: (i) successive crystal growth during the later stage of prograde eclogite facies metamorphism that formed the margin of the type I core and the outer cores of types II, III, and IV; (ii) partial resorption of the core during exhumation and hydration stage; and (iii) subsequent formation of mantle zones during prograde metamorphism of the epidote–amphibolite facies. The prograde metamorphic reactions may not have progressed under an isochemical condition in some Sanbagawa metamorphic rocks, at least at the hand specimen scale. This interpretation suggests that, in some cases, material interaction promoted by mechanical mixing and fluid‐assisted diffusive mass transfer probably influences mineral reactions and paragenesis of high‐pressure metamorphic rocks.     

Adjustable vertical vibration isolator with a variable ellipse curve mechanism

This paper presents a passive vertical quasi‐zero‐stiffness vibration isolator intended for relatively small objects. The present isolator has features of compactness, long stroke, and adjustability to various load capabilities. To realize these features, we use constant‐force springs, which sustain constant load regardless of their elongation, and propose a variable ellipse curve mechanism that is inspired by the principle of ellipsographs. The variable ellipse curve mechanism can convert the restoring force of the horizontally placed constant‐force springs to the vertical restoring force of the vibration isolator. At the same time as converting the direction, the vertical restoring force can be adjusted by changing the ratio of the semi‐minor axis to the semi‐major one of the ellipse. In this study, a prototype of a class of quasi‐zero‐stiffness vibration isolator with the proposed variable ellipse curve mechanism is created. Shaking table tests are performed to demonstrate the efficacy of the present mechanism, where the prototype is subjected to various sinusoidal and earthquake ground motions. It is demonstrated through the shaking table tests that the prototype can reduce the response acceleration within the same specified tolerance even when the mass of the vibration isolated object is changed. Copyright © 2017 John Wiley & Sons, Ltd.     

Temporal stress variations along a seismogenic megasplay fault in the subduction zone: An example from the Nobeoka Thrust,southwestern Japan

The Nobeoka Thrust, an ancient megasplay fault in the Shimanto Belt, southwestern Japan, contains fault rocks from the seismogenic zone, providing an accessible analog of active megasplay faults in deep subduction settings. In this study, the paleostress along the Nobeoka Thrust was analyzed using multiple inversion techniques, including k‐means clustering of fault datasets acquired from drillcores that intersected the thrust. The six resultant stress orientation clusters can be divided into two general groups: stress solutions with north–south‐trending σ₁ axes, and those with east–west‐trending σ₁ axes. These groups are characterized by the temporal changes for the orientations of the σ₁ and σ₃ principal stress axes that involve alternation between horizontal and vertical. The findings are probably due to a change in stress state before and after earthquakes that occurred on the fault; similar changes have been observed in active tectonic settings, such as the 2011 Tohoku‐Oki earthquake (Japan).     

New measurement technique for characterizing small extraterrestrial materials by X‐ray diffraction using the Gandolfi attachment

Identification and characterization of small extraterrestrial samples, such as small Antarctic meteorites <~1 cm, require the development of convenient laboratory‐based nondestructive analytical techniques using X‐ray diffraction (XRD). We explore the characterization criteria using an X‐ray diffractometer with a Gandolfi attachment using sub‐mm small fragments and powder aggregates for various kinds of stony meteorites and develop a new analytical technique. We primarily focus on olivine and pyroxene because they are the most abundant and important minerals for stony meteorite classification. A new calibration is performed to estimate the FeO content of the olivine in unequilibrated ordinary chondrites, which is useful for determining the meteorite chemical group irrespective of powder aggregate diameter but dependent on fragment grain diameter. This is because X‐ray intensity absorption is more effective for grains than for powders. Clinoenstatite (Cen) and orthoenstatite (Oen) were distinguished using the presence or absence of the isolated Oen 511 index peak. The method is also applied to other stony meteorites including carbonaceous chondrites and achondrites. The XRD results are consistent with studies based on polished sections involving textural observations by scanning microscope and chemical compositions of the constituent minerals. The new measurement technique presented here is convenient because of its use in air by the laboratory‐based X‐ray diffractometer, which makes it useful for the initial analyses of restricted extraterrestrial sample characterization.     

Assessment of digital camera-derived vegetation indices in quantitative monitoring of seasonal rice growth

A commercially available digital camera can be used in a low-cost automatic observation system for monitoring crop growth change in open-air fields. We developed a prototype Crop Phenology Recording System (CPRS) for monitoring rice growth, but the ready-made waterproof cases that we used produced shadows on the images. After modifying the waterproof cases, we repeated the fixed-point camera observations to clarify questions regarding digital camera-derived vegetation indices (VIs), namely, the visible atmospherically resistant index (VARI) based on daytime normal color images (RGB image) and the nighttime relative brightness index (NRBI_NIR) based on nighttime near infrared (NIR) images. We also took frequent measurements of agronomic data such as plant length, leaf area index (LAI), and aboveground dry matter weight to gain a detailed understanding of the temporal relationship between the VIs and the biophysical parameters of rice. In addition, we conducted another nighttime outdoor experiment to establish the link between NRBI_NIR and camera-to-object distance. The study produced the following findings. (1) The customized waterproof cases succeeded in preventing large shadows from being cast, especially on nighttime images, and it was confirmed that the brightness of the nighttime NIR images had spatial heterogeneity when a point light source (flashlight) was used, in contrast to the daytime RGB images. (2) The additional experiment using a forklift showed that both the ISO sensitivity and the calibrated digital number of the NIR (cDN_NIR) had significant effects on the sensitivity of NRBI_NIR to the camera-to-object distance. (3) Detailed measurements of a reproductive stem were collected to investigate the connection between the morphological feature change caused by the panicle sagging process and the downtrend in NRBI_NIR during the reproductive stages. However, these agronomic data were not completely in accord with NRBI_NIR in terms of the temporal pattern. (4) The time-series data for the LAI, plant length, and aboveground dry matter weight could be well approximated by a sigmoid curve based on NRBI_NIR and VARI. The results confirmed that NRBI_NIR was more sensitive to all of the agronomic data for overall season, including the early reproductive stages. VARI had an especially high correlation with LAI, unless yellow panicles appeared in the field of view.     

A Method for Rapid Determination of Re and Os Isotope Compositions Using ID‐MC‐ICP‐MS Combined with the Sparging Method

A simple, rapid method for the determination of Re and Os concentrations and isotope compositions using isotope dilution multi‐collector inductively coupled plasma‐mass spectrometry (ID‐MC‐ICP‐MS) combined with Carius tube digestion and sparging introduction of Os was developed. For Os measurement, four channeltron ion counters to detect different Os isotopes were used simultaneously, which led to a drastic reduction in the measurement time. Rhenium isotopes were measured by means of eight Faraday cups with solution nebulisation and an ultrasonic membrane desolvator. The representative ¹⁸⁸Os count rate of an Os standard solution containing 50 pg of total Os was approximately 110000–120000 cps at the onset of measurement; the Re intensity of our in‐house 10 pg g^?1 standard solution reached 1820 V/μg g^?1 with a sample uptake rate of 95–99 μl min^?1. These values indicate that the sensitivity of the method was sufficient even for samples with low Re and Os concentrations, such as chert. As the temporal variations of the amplification efficiency of the ion counters differed from one another, we adopted a sample‐calibrator bracketing method to correct the measured Re and Os isotope ratios. The Re and Os concentrations via the isotope dilution method and the ¹⁸⁷Os/¹⁸⁸Os ratios of two sedimentary rock reference materials (JMS‐2 and JCh‐1) on the basis of the isotope ratios determined by the MC‐ICP‐MS and by negative thermal ionisation mass spectrometry (N‐TIMS) were comparable within their ranges. Based on Os isotope measurement of the IAG reference material [Durham Romil Os (DROsS)], the average difference from the recommended value and precision of Os isotope measurements by the sparging method in combination with multi‐ion‐counters were 0.72% and 0.76% [1RSD (%), n = 29], respectively. The precisions in the ¹⁸⁷Os/¹⁸⁸Os ratios [1RSD (%)] of JMS‐2, JCh‐1 and DROsS were 0.35–0.71, 1.56–3.31 and 0.99–1.28%, respectively, which depended on their Os ion intensities. No systematic difference was observed between the Re and Os geochemical compositions of JCh‐1 and JMS‐2 obtained by means of digestion with inverse aqua regia and CrO₃‐H₂SO₄ solutions, suggesting that either acid solution can be used for the sparging method of sedimentary rock samples. As CrO₃‐H₂SO₄ solution is believed to liberate predominantly the hydrogenous Re and Os fraction from organic‐rich sediment, the sparging method combined with CrO₃‐H₂SO₄ digestion and multi‐ion‐counters in the mass spectrometry is expected to be a powerful tool for reconstructing the secular change in marine Os isotope compositions with high sample throughput.     

CaPtO3 as a novel post-perovskite oxide

Structural, morphological, magnetic, and thermal properties have been investigated for a novel post-perovskite oxide CaPtO₃ synthesized under high pressure. By comparing obtained structural parameters with those for known post-perovskite compounds, we argue that the chemical bond has a strong covalent character. Precise measurements of the Langevin susceptibility χ ₀ = −9.6 × 10⁻⁵ emu/mol and Debye temperature θ ∼ 470 K provide a good opportunity to confirm the reliability of first-principle calculations on predicting physical properties of the Earth’s D” layer.