Handlotungen und Echolotungen in der Seevermessung geringer Wassertiefen in strömenden Gewässern — eine kritische Betrachtung

Zusammenfassung Vergleichslotungen zwischen Echolot und Handlot führen zu einer mathematischen Ableitung der Handlotleinen-Kurve in strömenden Gewässern. Durch Einführung von zwei Vereinfachungen — Vernachlässigung des Lotleinen-Gewichts und Annahme der Konstanz der Strömungsgeschwindigkeit nach der Tiefe — wird theoretisch die Kettenlinie, praktisch eine Parabel ermittelt. Als bestimmend für den Parameter der Kettenlinie ergeben sich das Lotgewicht und der Staudruck auf die Lotleine. Aus einem praktischen Beispiel wird der Parameter entnommen, und es werden für diese Verhältnisse die für die Tiefenwerte bis 26 m zu erwartenden Fehlmessungen des Handlotes sowie die Größe der Ablagen der Lotbirne vom Lotpunkt berechnet. Für andere Werte der Strömungsgeschwindigkeit werden die Veränderungen auf die Ausbuchtung der Lotleine ebenfalls rechnerisch bestimmt und in Kurven dargestellt. Aus diesen Kurven ergeben sich zwangsläufig die größten Tiefen, die man bei verschiedenen Strömungsgeschwindigkeiten mit dem schweren Handlot vermessen darf; sie liegen bei v=1 m/sec bei 8 m, bei v=0,7 m/sec bei 12 m und bei v=0,5 m/sec bei 20 m Wassertiefe.Praktische Beispiele der Seevermessung aus der jüngsten Zeit zeigen deutlich die Notwendigkeit, zukünftig nur noch mit dem Echolot zu vermessen.

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A comment on the applicability of hand leads and echo sounders to surveying operations in flowing shallow waters

Summary From comparisons between hand-lead soundings and echo soundings in streaming waters the divergency of the lead line from the vertical is mathematically derived. In introducing two simplifications, i. e. in neglecting the weight of the lead line and in assuming the velocity of current to be constant at all depths, the catenary curve which practically speaking is a parabola, is theoretically ascertained. The weight of the lead and the dynamic pressuro of the water (the pressure as exerted on a jet and measured by it) are found to be decisive for the parameter of the catenary-curve. The parameter is derived from a practical example and, according to the conditions of same, the errors to be expected in sounding with the hand lead at depths up to 26 m (= 79 ft) as well as the divergency of the sounding lead from the vertical are calculated. The various degrees of the lead line's divergency caused by a greater or lesser intensity of the current are likewise calculated and represented by curves. These curves necessarily indicate the maximum depths that can be sounded with sufficient accuracy with the heavy hand lead (5 kilos) at different velocities of current; the approximate values are as follows: 8 m for 1,0 m/sec, 12 m for 0,7 m/sec, 20 m for 0,5 m/sec (or: 25 ft for 2,0 knots, 37 ft for 1,5 knots, 61 ft for 1,0 knot). As a result of practical experience in recent survey operations the echo sounder should be regarded as the only reliable instrument to be used in future surveying.

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Note critique sur l'applicabilité de la sonde au plomb-poisson et celle du sondeur acoustique aux levés hydrographiques effectués en faibles profondeurs dans les eaux courantes

Résumé Les comparaisons des sondages au plomb-poisson avec ceux effectués par écho permettent d'en dériver mathématiquement la courbe formée par la ligne de sonde dans des eaux courantes. En introduisant deux simplifications, c'est à dire en négligeant le poids de la ligne et en supposant que la vitesse de courant soit constante dans toutes les profondeurs on arrive à déterminer théoriquement la chaînette qui est en effet une parabole. Le paramètre est fonction du poids du plomb-poisson et celle de la poussée sensiblement horizontale sur le fil due au frottement du liquide. On se sert d'un exemple pratique pour en dériver le paramètre, pour calculer, dans les conditions de cet exemple, les sondages faux de la sonde au plomb-poisson dont il faut tenir compte dans les profondeurs jusqu'à 26 m, et pour déterminer la déviation entre le plomb au bout de la ligne et la verticale. Les diverses variations de la courbe, que la ligne subit et qui sont causées par d'autres valeurs de la vitesse de courant sont aussi calculées et représentées à l'aide des courbes. Ces courbes indiquent forcément les profondeurs permettant encore une précision suffisante du sondage au plombpoisson lourd (5 kg) aux différentes variations de la vitesse de courant. Ces maxima sont à peu près comme suit:v=1,0 m/sec à 8 m de profondeur,v=0,7 m/sec à 12 m de profondeur,v=0,5 m/sec à 20 m de profondeur. Des exemples pratiques offerts par des récentes levés hydrographiques prouvent que le sondeur acoustique doit être considéré comme le seul instrument assurant le précis levé hydrographique.

     

Comparison of an Electrochemical and Luminescence‐Based Oxygen Measuring System for Use in the Biodegradability Testing According to Closed Bottle Test (OECD 301D)

The effects of persistent organic pollutants on the aquatic environment still can hardly be assessed. Therefore, ready biodegradability is a desired key characteristic of chemicals. Accordingly, biodegradation testing is of utmost importance and is a vital part within the risk assessment for organic chemicals. In the closed bottle test (CBT; OECD 301D) the degree of biological degradation of a chemical is assessed by monitoring the oxygen consumption so far with a Clark electrode as standard method. However, this method is time‐consuming, laborious and led to frequent fluctuations of the test results, which limited their validity. Due to these shortcomings, an optical system that enables contact‐free measuring of the oxygen concentration in a closed bottle, based on dynamic luminescence quenching, was examined. The test results were compared to those obtained with the “classical” electrochemical technique (Clark electrode). At first, a basic standard for the handling of the new instrument in the laboratory was developed. Then possible influencing factors, reliability, comparability, and reproducibility of the test results were investigated by running the CBTs in parallel with the electrode and optode method. The findings proved the new optode method to be unambiguously superior to the electrode technique. The frequency of fluctuations of the test results and time and effort necessary for the test run could considerably be reduced. The degradation kinetics of the test substances could be followed easily in the CBT by increasing the measuring points without much additional effort.     

Long-term plankton studies at the lower Rhine/Germany

The river Rhine has lain under considerable anthropogenic stress of its water quality for 100 years. As early as 1905 the first results of studies of the plankton in the Rhine were published. Due to the long residence time of the water a real potamoplankton can develop and at the end of the Lower Rhine it reaches its highest density. The paper consists of two parts. At first an overview is given about the history of plankton studies in the Rhine. The second part is the presentation of results from a monitoring at the Lower Rhine from 1979 to 2004.First systematic studies started at the beginning of the 20th century at the beginning of pollution. Our studies started during a phase of recreation from extreme pollution and eutrophication. Samples were taken at four stations: Bad Honnef, km 640, entrance to North Rhine-Westphalia, Düsseldorf, km 732, Duisburg, km 792 downstream large industrial effluents and big cities, Kleve-Bimmen, km 865 at the border to the Netherlands.In the 1970s nutrients were high, especially phosphate 0.65 mg PO₄-P L⁻¹ in 1979. After 1980 phosphate dropped to 0.11 mg PO₄-P L⁻¹ in 2004 (mean values of the growing season). Ammonia was reduced from about 0.52 (1979) to 0.02 (2004) mg NH₄-N L⁻¹. Nitrate remained between 3.72 (1989) and 2.26 (2004) mg NO₃-N L⁻¹ at a relatively high level. Oxygen concentrations were very low during the 1960s and 1970s, sometimes only 4 mg L⁻¹ O₂. During our studies the oxygen increased up to 9 mg L⁻¹ O₂ with a tendency to 11 mg L⁻¹ O₂ in the last years. Chlorophyll a was estimated to be between 59 (1979) and 31μg L⁻¹ (1986) with short peaks up to 170 μg L⁻¹ (1989). Since 1992 the mean values have varied between 30 (1993) and 21 μg L⁻¹ (2004).The floristic phytoplankton composition is characterised by the dominance of the centric diatom Stephanodiscus hantzschii. Other diatoms like Skeletonema subsalsum, Skeletonema potamos and Asterionella formosa were regularly present in smaller quantities. The second dominant group was coccale green algae. During the 1980s they formed up to 35% of the biomass. Since the 1990s their contribution to the phytoplankton became much smaller. This change corresponds with the increase of wastewater treatment and the diminution of nutrients. All the other groups of algae were present in minor quantities. During the time of higher trophy in the 1970s and 1980s the phytoplankton formed two peaks, in recent years only one peak has developed, depending on different flow conditions during the growing season and lower trophic state in the upstream parts of the river.Excellent correspondence exists between cell number, biovolume and chlorophyll a content and the results of delayed fluorescence (DF) measurement. The trophic status in the Lower Rhine may be estimated as (moderate) eutrophic. The ecological status of the phytoplankton is good based on the requirements of the European Water Framework Directive (WFD).The zooplankton consists mainly of rotatoria and larvs of Dreissena polymorpha. Grazing on phytoplankton seems to be mainly due to the large quantities of benthic Dreissena and the newly introduced mussel Corbicula.     

Mega-monsoon variability during the late Triassic: Re-assessing the role of orbital forcing in the deposition of playa sediments in the Germanic Basin

The formation of the supercontinent Pangaea during the Permo–Triassic gave rise to an extreme monsoonal climate (often termed ‘mega-monsoon’) that has been documented by numerous palaeo-records. However, considerable debate exists about the role of orbital forcing in causing humid intervals in an otherwise arid climate. To shed new light on the forcing of monsoonal variability in subtropical Pangaea, this study focuses on sediment facies and colour variability of playa and alluvial fan deposits in an outcrop from the late Carnian (ca 225 Ma) in the southern Germanic Basin, south-western Germany. The sediments were deposited against a background of increasingly arid conditions following the humid Carnian Pluvial Event (ca 234 to 232 Ma). The ca 2·4 Myr long sedimentary succession studied shows a tripartite long-term evolution, starting with a distal mud-flat facies deposited under arid conditions. This phase was followed by a highly variable playa-lake environment that documents more humid conditions and finally a regression of the playa-lake due to a return of arid conditions. The red–green (a*) and lightness (L*) records show that this long-term variability was overprinted by alternating wet/dry cycles driven by orbital precession and ca 405 kyr eccentricity, without significant influence of obliquity. The absence of obliquity in this record indicates that high-latitude forcing played only a minor role in the southern Germanic Basin during the late Carnian. This is different from the subsequent Norian when high-latitude signals became more pronounced, potentially related to the northward drift of the Germanic Basin. The recurring pattern of pluvial events during the late Triassic demonstrates that orbital forcing, in particular eccentricity, stimulated the occurrence and intensity of wet phases. It also highlights the possibility that the Carnian Pluvial Event, although most likely triggered by enhanced volcanic activity, may also have been modified by an orbital stimulus.     

Pre-Cenozoic intra-plate magmatism along the Central Andes (17–34°S): Composition of the mantle at an active margin

Sr–Nd–Pb isotope ratios of alkaline mafic intra-plate magmatism constrain the isotopic compositions of the lithospheric mantle along what is now the eastern foreland or back arc of the Cenozoic Central Andes (17–34°S). Most small-volume basanite volcanic rocks and alkaline intrusive rocks of Cretaceous (and rare Miocene) age were derived from a depleted lithospheric mantle source with rather uniform initial ¹⁴³Nd/¹⁴⁴Nd ( 0.5127–0.5128) and ⁸⁷Sr/⁸⁶Sr ( 0.7032–0.7040). The initial ²⁰⁶Pb/²⁰⁴Pb ratios are variable (18.5–19.7) at uniform ²⁰⁷Pb/²⁰⁴Pb ratios (15.60 ± 0.05). A variety of the Cretaceous depleted mantle source of the magmatic rocks shows elevated Sr isotope ratios up to 0.707 at constant high Nd isotope ratios. The variable Sr and Pb isotope ratios are probably due to radiogenic growth in a metasomatized lithospheric mantle, which represents the former sub-arc mantle beneath the early Palaeozoic active continental margin. Sr–Nd–Pb isotope signatures of a second mantle type reflected in the composition of Cretaceous (one late Palaeozoic age) intra-plate magmatic rocks (¹⁴³Nd/¹⁴⁴Nd  0.5123, ⁸⁷Sr/⁸⁶Sr  0.704, ²⁰⁶Pb/²⁰⁴Pb  17.5–18.5, and ²⁰⁷Pb/²⁰⁴Pb  15.45–15.50) are similar to the isotopic composition of old sub-continental lithospheric mantle of the Brazilian Shield.

Published Nd and Sr isotopic compositions of Mesozoic to Cenozoic arc-related magmatic rocks (18–40°S) represent the composition of the convective sub-arc mantle in the Central Andes and are similar to those of the Cretaceous (and rare Miocene) intra-plate magmatic rocks. The dominant convective and lithospheric mantle type beneath this old continental margin is depleted mantle, which is compositionally different from average MORB-type depleted mantle. The old sub-continental lithospheric mantle did not contribute to Mesozoic to Cenozoic arc magmatism.     

Geochemistry and mineralogy of laterites in the Sula Mountains greenstone belt, Lake Sonfon gold district, Sierra Leone

Geochemical and mineralogical investigations have been carried out on laterite profiles developed in the Lake Sonfon Au district of northern Sierra Leone. The area is underlain by Archean metavolcanics and constitutes part of the Sula Mountains greenstone belt, which is mineralized in Au. Extensive lateritization has affected the rocks of this region, resulting in a profile which from bottom to top consists typically of a decomposed bedrock zone, a pisolitic laterite layer and a duricrust layer. Both the pisolitic and duricrust layers of the laterite are sometimes punctuated by lenses of ironstones containing high amounts of Cu, Zn, Ni, Co and Ce. Gold occurs as small grains within the heavy mineral fraction recovered from the decomposed rock zones and pisolitic layers of the profiles and also in gravels of streams draining the area. The mineralogy of the duricrust and pisolitic layers is dominated by goethite, gibbsite and quartz, with minor amounts (<5% by volume) of ilmenite, magnetite, haematite, rutile and kaolinite. The kaolinite content increases towards the decomposed rock zone, where talc, vermiculite and other layer lattice silicates become abundant. The heavy-mineral fraction of stream sediments is composed essentially of ilmenite, magnetite, haematite, and traces of rutile, zircon, tourmaline and Au. The Au grains are often characterized by a 10–200-μm-wide rim having a much lower content of Ag (0.3 wt.% or lower) than the grain interior (about 5 wt.% on average). Dissolution effects are also observed on the grain surfaces. It is considered that Au derived from the amphibolite parent rock is dissolved, transported, and redeposited during laterization.The duricrust cover of the laterite profiles is characterized by high contents of Fe₂O₃ (ca. 60 wt.%) and Al₂O₃ (ca. 32wt.%) and low content of SiO₂ (ca. 9 wt.%). In comparison, the pisolitic layer is higher in SiO₂ (ca. 18 wt.%) as well as a slightly higher in Al₂O₃ (ca. 34 wt.%). Lateritic weathering has resulted in the removal of CaO, Na₂O, MgO and SiO₂, with relative enrichment of Fe₂O₃ and Al₂O₃. The geochemical distribution of the trace elements in the laterite profiles can be related to the occurrence of the auriferous mineralization. The significance of these observations is discussed in relation to the origin of the lateritic Au and the role of the associated trace elements as indicators of the mineralization.     

Lead isotopes of the carbonate-hosted Kabwe, Tsumeb, and Kipushi Pb-Zn-Cu sulphide deposits in relation to Pan African orogenesis in the Damaran-Lufilian Fold Belt of Central Africa

Lead isotope ratios of galena from the carbonate-hosted massive sulphide deposits of Kabwe (Pb-Zn) and Tsumeb (Pb-Zn-Cu) in Zambia and Namibia, respectively, have been measured and found to be homogeneous and characteristic of upper crustal source rocks. Kabwe galena has average isotope ratios of ^206/204Pb = 17.997 ± 0.007, ^207/204Pb = 15.713 ± 0.010 and ^208/204Pb = 38.410 ± 0.033. Tsumeb galena has slightly higher ^206/204Pb (18.112 ± 0.035) and slightly lower ^207/204Pb (15.674 ± 0.016) and ^208/204Pb (38.276 ± 0.073) ratios than Kabwe galena. The isotopic differences are attributed to local differences in the age and composition of the respective source rocks for Kabwe and Tsumeb. The homogeneity of the ore lead in the two epigenetic deposits suggests lead sources of uniform isotopic composition or, alternatively, thorough mixing of lead derived from sources with relatively similar isotopic compositions. Both deposits have relatively high ²³⁸U/²⁰⁴Pb ratios of 10.31 and 10.09 for Kabwe and Tsumeb galenas, respectively. These isotope ratios are considered to be typical of the upper continental crust in the Damaran-Lufilian orogenic belt, as also indicated by basement rocks and Cu-Co sulphides in stratiform Katangan metasediments which have a mean μ-value of 10.25 ± 0.12 in the Copperbelt region of Zambia and the Democratic Republic of Congo (formerly Zaire). The ²³²Th/²⁰⁴Pb isotope ratios of 43.08 and 40.42 for Kabwe and Tsumeb suggest Th-enriched source regions with ²³²Th/²³⁵U (κ-values) of 4.18 and 4.01, respectively. Model isotopic ages determined for the Kabwe (680 Ma) and Tsumeb (530 Ma) deposits indicate that the timing of the mineralisation was probably related to phases of orogenic activity associated with the Pan-African Lufilian and Damaran orogenies, respectively. Galena from the carbonate-hosted Kipushi Cu-Pb-Zn massive sulphide deposit in the Congo also has homogeneous lead isotope ratios, but its isotopic composition is comparable to that of the average global lead evolution curve for conformable massive sulphide deposits. The μ (9.84) and κ (3.69) values indicate a significant mantle component, and the isotopic age of the Kipushi deposit (456 Ma) suggests that the emplacement of the mineralisation was related to a post-tectonic phase of igneous activity in the Lufilian belt. The isotope ratios (^206/204Pb, ^207/204Pb, ^208/204Pb) of the three deposits are markedly different from the heterogeneous lead ratios of the Katangan Cu-Co stratiform mineralisation of the Copperbelt as well as those of the volcanogenic Nampundwe massive pyrite deposit in the Zambezi belt which typically define radiogenic linear trends on lead-lead plots. The host-rock dolomite of the Kabwe deposit also has homogeneous lead isotope ratios identical to the ore galena. This observation indicates contamination of the Kabwe Dolomite Formation with ore lead during mineralisation. Received: 8 September 1997 / Accepted: 21 August 1998     

The restricted stability of osumilite under hydrous conditions in the system K2O-MgO–Al2O3–SiO2–H2O

Osumilite_ss was synthesized as a single phase product in the model system K₂O-MgO-Al₂O₃-SiO₂ at 800° C/ 0.5 Kbar water pressure and at 800° to 840° C/1.0 Kbar total pressure with 0.3 in the gas phase. The experimentally determined solid solubility range of synthetic osumilites can be expressed by the formula KMg₂(Al_3-xMg_x) (Al_2–xSi_10+x)O₃₀ with 0x0.4. A survey of sixteen chemical analyses of natural osumilites from eleven occurrences shows a solid solubility characterized by 0x0.6. Reversed stability experiments for the synthetic osumilite KMg₂(Al_2.75Mg_0.25)(Al_1.75Si_10.25)O₃₀ determined at water pressure equal to total pressure demonstrate its restriction to water pressures below 0.8 Kbar (at 0.5 Kbar, the stability range is between 765° and 800° C). At the lower thermal stability limit osumilite+H₂O vapor break down to cordierite+K feldspar+phlogopite_ss+quartz, at the higher one to cordierite+K feldspar+phlogopite+liquid. Reduction of water fugacity will expand the stability field largely by shifting the lower and higher thermal stability limits to lower and higher temperatures, respectively. The dependence of osumilite stability on water fugacity makes osumilite a sensitive indicator mineral for dry conditions in rocks formed at total pressures higher than about 0.8 Kbar.