Flux and dispersion of gases from the “Drachenschlund” hydrothermal vent at 8°18' S, 13°30' W on the Mid-Atlantic Ridge

Hydrothermal emission of mantle helium appears to be directly related to magma production rate, but other processes can generate methane and hydrogen on mid-ocean ridges. In an on-going effort to characterize these processes in the South Atlantic, the flux and distribution of these gases were investigated in the vicinity of a powerful black smoker recently discovered at 8°17.9' S, 13°30.4' W. The vent lies on the shoulder of an oblique offset in the Mid-Atlantic Ridge and discharges high concentrations of methane and hydrogen. Measurements during expeditions in 2004 and 2006 show that the ratio of CH₄ to ³He in the neutrally buoyant plume is quite high, 4 × 10⁸. The CTD stations were accompanied by velocity measurements with lowered acoustic Doppler current profilers (LADCP), and from these data we estimate the methane transport to have been 0.5 mol s^− 1 in a WSW-trending plume that seems to develop during the ebb tidal phase. This transport is an order of magnitude greater than the source of CH₄ calculated from its concentration in the vent fluid and the rise height of the plume. From this range of methane fluxes, the source of ³He is estimated to be between 0.14 and 1.2 nmol s^− 1. In either case, the ³He source is significantly lower than expected from the spreading rate of the Mid-Atlantic Ridge. From the inventory of methane in the rift valley adjacent to the vent, it appears that the average specific rate of oxidation is 2.6 to 23 yr^− 1, corresponding to a turnover time between 140 and 16 days. Vertical profiles of methane in the surrounding region often exhibited Gaussian-like distributions, and the variances appear to increase with distance from the vent. Using a Gaussian plume model, we obtained a range of vertical eddy diffusivities between 0.009 and 0.08 m²m² s^− 1. These high values may be due to tidally driven internal waves across the promontory on which the vent is located.     

Long-term plankton studies at the lower Rhine/Germany

The river Rhine has lain under considerable anthropogenic stress of its water quality for 100 years. As early as 1905 the first results of studies of the plankton in the Rhine were published. Due to the long residence time of the water a real potamoplankton can develop and at the end of the Lower Rhine it reaches its highest density. The paper consists of two parts. At first an overview is given about the history of plankton studies in the Rhine. The second part is the presentation of results from a monitoring at the Lower Rhine from 1979 to 2004.First systematic studies started at the beginning of the 20th century at the beginning of pollution. Our studies started during a phase of recreation from extreme pollution and eutrophication. Samples were taken at four stations: Bad Honnef, km 640, entrance to North Rhine-Westphalia, Düsseldorf, km 732, Duisburg, km 792 downstream large industrial effluents and big cities, Kleve-Bimmen, km 865 at the border to the Netherlands.In the 1970s nutrients were high, especially phosphate 0.65 mg PO₄-P L⁻¹ in 1979. After 1980 phosphate dropped to 0.11 mg PO₄-P L⁻¹ in 2004 (mean values of the growing season). Ammonia was reduced from about 0.52 (1979) to 0.02 (2004) mg NH₄-N L⁻¹. Nitrate remained between 3.72 (1989) and 2.26 (2004) mg NO₃-N L⁻¹ at a relatively high level. Oxygen concentrations were very low during the 1960s and 1970s, sometimes only 4 mg L⁻¹ O₂. During our studies the oxygen increased up to 9 mg L⁻¹ O₂ with a tendency to 11 mg L⁻¹ O₂ in the last years. Chlorophyll a was estimated to be between 59 (1979) and 31μg L⁻¹ (1986) with short peaks up to 170 μg L⁻¹ (1989). Since 1992 the mean values have varied between 30 (1993) and 21 μg L⁻¹ (2004).The floristic phytoplankton composition is characterised by the dominance of the centric diatom Stephanodiscus hantzschii. Other diatoms like Skeletonema subsalsum, Skeletonema potamos and Asterionella formosa were regularly present in smaller quantities. The second dominant group was coccale green algae. During the 1980s they formed up to 35% of the biomass. Since the 1990s their contribution to the phytoplankton became much smaller. This change corresponds with the increase of wastewater treatment and the diminution of nutrients. All the other groups of algae were present in minor quantities. During the time of higher trophy in the 1970s and 1980s the phytoplankton formed two peaks, in recent years only one peak has developed, depending on different flow conditions during the growing season and lower trophic state in the upstream parts of the river.Excellent correspondence exists between cell number, biovolume and chlorophyll a content and the results of delayed fluorescence (DF) measurement. The trophic status in the Lower Rhine may be estimated as (moderate) eutrophic. The ecological status of the phytoplankton is good based on the requirements of the European Water Framework Directive (WFD).The zooplankton consists mainly of rotatoria and larvs of Dreissena polymorpha. Grazing on phytoplankton seems to be mainly due to the large quantities of benthic Dreissena and the newly introduced mussel Corbicula.     

Unusual exsolution phenomena in omphacite and partial replacement of phengite by phlogopite + kyanite in an eclogite from the Erzgebirge

In the Erzgebirge Crystalline Complex, eclogites occur in three different high pressure (HP) units (1, 2 and 3) recording contrasting pressure (P)–temperature (T) conditions. Eclogites from HP-unit 1 experienced peak metamorphic conditions in the coesite stability field at about 33 kbar/850 °C. Commonly, these eclogites from HP-unit 1 are all very similar, with an eclogitic peak assemblage of omphacite–garnet–coesite–K-feldspar, rarely accompanied by kyanite, and omphacites systematically deviating from a stoichiometric composition. In contrast, an eclogite recently found near Blumenau, is mineralogically and geochemically different from the typical eclogites of HP-unit 1. This unusual eclogite reveals the eclogitic equilibrium assemblage omphacite–garnet–coesite–phengite–phlogopite–kyanite, and yields metamorphic peak conditions of 870 °C and >29 kbar. There is clear textural evidence of the formation of phlogopite and kyanite under partial consumption of phengite and garnet. Moreover, the omphacite is stoichiometric and contains abundant exsolution lamellae, the thickest of which were identified as quartz by the electron microprobe. The finer lamellae were studied by transmission electron microscopy (TEM). Oligoclase was identified as an exsolution phase. Other lamellae proved to consist of K-white mica, also interpreted as exsolution. Prior to exsolution, the omphacite composition must have been cation-deficient, as that of the other, common HP-unit 1 eclogites. These non-stoichiometric compositions are ascribed to partial substitution by the Ca-Eskola pyroxene component, which calculates to an average of 8 mol% for omphacite in HP-unit 1 eclogites. According to experiments, this substitution becomes significant at P > 30 kbar. Exsolution of K-white mica may indicate hydroxyl defects in the original omphacite, also favoured by high pressure. Oligoclase and K-white mica exsolution from Ca-Eskola-rich clinopyroxene has not previously been reported. The omphacite has a disordered C2/c structure; and in just one case very small (a few tens of nanometres) antiphase domains, resulting from the C2/c to P2/n transformation, are present. These features may indicate a brief thermal history and rapid tectonic processes. Received: 4 January 1999 / Accepted: 20 April 2000     

Object and Pixel-Based Reservoir Modeling of a Braided Fluvial Reservoir

To assess differences between object and pixel-based reservoir modeling techniques, ten realizations of a UK Continental Shelf braided fluvial reservoir were produced using Boolean Simulation (BS) and Sequential Indicator Simulation (SIS). Various sensitivities associated with geological input data as well as with technique-specific modeling parameters were analyzed for both techniques. The resulting realizations from the object-based and pixel-based modeling efforts were assessed by visual inspection and by evaluation of the values and ranges of the single-phase effective permeability tensors, obtained through upscaling. The BS method performed well for the modeling of two types of fluvial channels, yielding well-confined channels, but failed to represent the complex interaction of these with sheetflood and other deposits present in the reservoir. SIS gave less confined channels and had great difficulty in representing the large-scale geometries of one type of channel while maintaining its appropriate proportions. Adding an SIS background to the Boolean channels, as opposed to a Boolean background, resulted in an improved distribution of sheetflood bodies. The permeability results indicated that the SIS method yielded models with much higher horizontal permeability values (20–100%) and lower horizontal anisotropy than the BS versions. By widening the channel distribution and increasing the range of azimuths, however, the BS-produced models gave results approaching the SIS behavior. For this reservoir, we chose to combine the two methods by using object-based channels and a pixel-based heterogeneous background, resulting in moderate permeability and anisotropy levels.     

NOBLE GASES AND THE CLASSIFICATION OF BRACHINA

Noble-gas systematics show that Brachino is not a member of the SNC-group of meteorites. The whole-rock K-Ar gas retention age is (3.11 ± 0.07) AE as compared to the 1.3 AE solidification ages of SNCs; the content of radiogenic¹²⁹ Xe* of (3.47 ±. 15) × 10^?10 cm³ STP/g is about two orders of magnitude higher, and the¹²⁹ Xe/¹³² Xe ratio (11.0), the ratio of radiogenic¹²⁹ Xe* to fissiogenic¹³⁶ Xe_f (300), and the ratio³⁶ Ar/¹³² Xe in the trapped gases are about one order of magnitude higher than observed for SNCs. The same evidence argues strongly against any simple genetic relationship with eucrites. The noble-gas abundance pattern resembles closely that in silicate inclusions from the iron meteorites Campo del Cielo and Udei Station. Abundances of cosmic-ray produced³ He and²¹ Ne (5.7 and. 99 × 10^?8 cm³ STP/g, resp.) indicate an exposure age of ～ 2.4 Ma. Irradiation conditions appear to have been perfectly normal except for an unaccountably low content of spallogenic ³⁸Ar. Losses by diffusion of radiogenic⁴ He are severe; they must have occurred at or before the onset of the exposure of the meteoroid to the cosmic radiation.     

REE-, Zr-, and Th-rich titanite and associated accessory minerals from a kersantite in the Frankenwald, Germany

Summary The mineral chemistry of a Variscan lamprophyre (kersantite) from the Frankenwald, Germany, has been investigated by electron microprobe. This potassic, Si-saturated, mafic rock contains an assemblage of different generations of titanite and allanite-(Ce), Th-rich zircon, and metamict REE–Ti–Zr–Th silicates. The primary ferroan-ceroan titanite contains unusually high contents of REE₂O₃ (max. (ΣLa to Sm)+Y = 36.8 oxide wt.%), ZrO₂ (max. 5.4 wt.%), and ThO₂ (max. 3.1 wt.%). Its empirical formula averages to (Ca_0.31 La_0.17 Ce_0.30 Pr_0.03 Nd_0.08 Sm_0.01 Y_0.01 Fe²⁺_0.06 Th_0.02 Mn_0.01)_Σ1.00 (Ti_0.60 Fe²⁺_0.22 Al_0.06 Zr_0.07 Mg_0.04 Nb_0.01)_Σ1.00 O_1.00(Si_0.93 Al_0.07)_Σ1.00 O₄. Element correlations reveal operation of the complex substitution Ca²⁺+Ti⁴⁺+Th⁴⁺ ⇔ REE³⁺+Al³⁺+Zr⁴⁺. In comparison to allanite-(Ce), ferroan-ceroan titanite preferentially incorporated the LREE and Th. This finding is inconsistent with previous experimental studies and suggests that both minerals are not cogenetic. High Zr contents in titanite, usually known only from Si-undersaturated alkaline rocks, and the predominance of Fe²⁺ suggest that the ferroan-ceroan titanite crystallized from an alkali-rich, low-fO₂ residual melt.     

Use of alternative conceptual models to assess the impact of a buried valley on groundwater vulnerability

A buried valley incised into a sequence of pre-Quaternary sediments is shown to seriously affect the vulnerability of groundwater. Often the existence of buried valleys is not known or is not described explicitly in a hydrogeological model. In the present study, two numerical groundwater models, representing two alternative conceptual models, were produced to help quantify the effect of the valley on groundwater vulnerability. One model included the buried valley and the other did not. Both models were subjected to calibration and were found to describe hydraulic head and river discharge equally well. Even though the two models showed similar calibration statistics; fluxes, travel paths and travel times were affected by the inclusion of the buried valley. The recharge area and the groundwater age of potential abstraction wells placed in the pre-Quaternary deep aquifers surrounding the buried valley were different for the two models, with significantly higher vulnerability when the valley was included in the model. Based on the results of the present study, it is concluded that a buried valley may not always be detectable when calibrating a wrong conceptual model. If reliable results should be obtained a good geological model has to be constructed.     

The biosphere: A homogeniser of Pb-isotope signals

Rock, soil, and plant (terrestrial moss, European mountain ash leaves, mountain birch leaves, bark and wood, and spruce needles and wood) samples, collected at 3 km intervals along a 120 km long transect (40 sites) cutting the city of Oslo, Norway, were analysed for their Pb concentration and Pb-isotope ratios. A general decrease in ²⁰⁶Pb/²⁰⁷Pb, ²⁰⁸Pb/²⁰⁷Pb and ²⁰⁶Pb/²⁰⁸Pb ratios, with a characteristic low variability in all plant materials and the plant-derived O-horizon of soil profiles, compared to rocks and mineral soils, is observed along the transect. It is demonstrated that minerogenic and biogenic sample materials belong to two different spheres, the lithosphere and biosphere, and that geochemical processes determining their chemical and isotopic compositions differ widely. Background variation for both sample materials needs to be established and documented at the continental and global scale before the anthropogenic influence on the geochemistry of the earth’s surface can be reliably estimated.