Glacial morphology and post-glacial contourites in northern Prince Gustav Channel (NW Weddell Sea,Antarctica)

We present the results of a marine geophysical investigation of the northern Prince Gustav Channel. By comparative analysis of multibeam bathymetric data, single channel seismic reflection profiles, underway chirp sonar data, ADCP current data and sediment coring, we define the main morphological elements of the area. In particular we define the glacial morphogenesis in relation to the excavation of inner shelf basins and troughs along structural discontinuities and lithologic boundaries. We identify streamlined surfaces that testify to the grounding of ice and past ice flow directions. These glacial forms are found only on glacial tills preserved in the deepest part of the basins, while net erosion to bedrock has occurred elsewhere. Since the Last Glacial Maximum (LGM), the relict glacial morphology has been draped by hemipelagic and diatomaceous mud, and bottom currents have played a major role in focusing sedimentation within small depocentres, that we define as contouritic drifts. Based on shallow sediment architecture and supported by direct measurements, we propose that the direction of bottom water flow is from the outer shelf into the Prince Gustav channel as a result of a combination of tidal currents and ice shelf-related thermohaline circulation.     

The modern distribution of chironomid sub-fossils (Insecta: Diptera) in the Sierra Nevada, California: Potential for paleoclimatic reconstructions

Surface lake sediment was recovered from 57 lakes along an elevation gradient in the central, eastern Sierra Nevada of California. The surface sediment was analysed for subfossil chironomid remains in order to assess the modern distribution of chironomids in the region. The lakes sampled for the calibration dataset were between 2.0 and 40.0 m in depth, spanned an altitudinal gradient of 1360 m and a surface water temperature gradient of approximately 14 °C. Redundancy analysis (RDA) identified that five of the measured environmental variables – surface water temperature, elevation, depth, strontium, particulate organic carbon – accounted for a statistically significant amount of the variance in chironomid community composition. Quantitative transfer functions, based on weighted-averaging (WA), partial least squares (PLS) and weighted-averaging partial least squares (WA-PLS), were developed to estimate surface water temperature from the chironomid assemblages. The best model was a WA model with classical deshrinking, which had a relatively high coefficient of determination (r² = 0.73), low root mean square error of prediction (RMSEP = 1.2 °C) and a low maximum bias (0.90 °C). The results from this study suggest that robust quantitative estimates of past surface water temperature can be derived from the application of these models to fossil chironomid assemblages preserved in late-Quaternary lake sediment in this region.     

The Application of a Statistical Trend Analysis Model to Ground Water Monitoring Data from Solid Waste Landfills

A statistical trend methodology is used to compare ground water quality between eight landfill sites in western Michigan as a case study. Monitoring data were collected over a 15-year period on 36 parameters at an upgradient and downgradient well selected at each of the eight sites. This yielded a total of 576 monitoring data sets available for analysis. New trend and contamination indices are introduced that are used to compare ground water contamination between these eight sites. These indices are used to assess each landfill's relative potential for environmental harm.
Many questions remain unanswered, but what is demonstrated here is that this type of methodology has the potential to be used to assess trends of ground water chemistry concentrations at landfill sues in a region. A specific purpose of such an assessment could be to provide a quantified basis for the prioritization of funds allocated for cleanup of contaminated landfill sites. Having a technical capability to reduce large amounts of ground water monitoring data to appropriate summaries, which then can be used to assess environmental contamination between several sites, could also have important economic and health implications in other settings. Hopefully this paper will encourage further development of such technologies for these purposes.     

Application of sedimentary and chronological analyses to refine the depositional context of a Late Pleistocene vertebrate deposit,Naracoorte, South Australia

Cave deposits of infill sediments and associated vertebrate fossils provide a valuable source of information on terrestrial palaeoenvironments, climatic conditions and palaeocommunities. In the deposits of the Naracoorte Caves World Heritage Area, such records span the last 500 ka and are renowned for their rich, diverse vertebrate assemblages. Previous research into the Grant Hall deposit of Victoria Fossil Cave suggested that it may preserve the only peak last interglacial (ca. 125 ka) faunal community within the World Heritage Area. The current work tested this existing model for the age of faunal remains from Grant Hall using multiple techniques. Physical and geochemical properties of the visually homogeneous sediments were analysed at regular intervals through the sequence to establish meaningful stratigraphic divisions and sediment provenance. Optically stimulated luminescence dating of individual quartz grains indicates that sediments accumulated in Grant Hall from 93 ± 8 to 70 ± 5 ka. Minimum ages provided by U/Th dating of fossil teeth (72.3 ± 2.2 to 38.2 ± 0.8 ka) are consistent with the luminescence chronology, and show that the deposit represents a more recent faunal accumulation than previously modelled for the site. U/Th ages on calcite straws within the deposit are significantly older than the sediments and fossil teeth (>500 to 186.4 ± 1 ka). As such they provide no further constraint on the chronology of the deposit but do indicate that speleothem deposition was active over much of the Middle Pleistocene. Sedimentary analyses resulted in the identification of five depositional units, contrasting with previous divisions which were based only on visual observation of the sedimentary sequence. Sediments within each unit are broadly classified as sandy silts with soil structures and may be indirectly derived from the lunettes of nearby Bool Lagoon, although their ultimate provenance is unknown. As a result of this work, palaeoenvironmental reconstruction based on fossil remains in the deposit may be more accurately related to prevailing climatic and environmental conditions at the time of accumulation. It also contributes to an understanding of the temporal occurrence of regional vertebrate faunas through the Late Pleistocene, reinforcing the value of developing stratigraphically constrained chronologies for cave deposits based on multiple techniques.     

Post-glacial fluvial response and landform development in the upper Muskegon River valley in North-Central Lower Michigan, U.S.A.

This study focuses on the upper part of the Muskegon River system in north-central Lower Michigan and is the first to reconstruct the post-glacial history of fluvial landform development in the core of North America's Great Lakes region. Results indicate that the upper Muskegon River valley contains four alluvial terraces and numerous paleomeanders. Radiocarbon dating of peats within these old channels provides a good chronology for stream behavior and landform development. The T-4 terrace is a paired Pleistocene outwash/lacustrine surface that probably formed about 12,500 years ago. The T-3 terrace is a fill-strath surface that was cut between about 12,000 and perhaps 9500 years ago. The geometry of macromeanders on this surface suggests that stream discharge was  8 times greater than during the Holocene.The Pleistocene/Holocene transition is marked by a major period of downcutting that likely began as the climate warmed/dried and sediment yield diminished. This period of downcutting potentially lasted through the drier middle Holocene, creating a 6-m-high escarpment in the valley. The Muskegon River then began to aggrade when the climate became wetter. Subsequently the river again incised, creating the paired T-2 terrace, about 3400 years ago when the climate became still wetter. T-2 paleomeanders indicate that stream discharge at this time was consistent with the modern river. In the past 2500 years, the stream has constructed a poorly defined complex of T-1 terraces. These surfaces likely formed due to complex response associated with more variable climate. This study demonstrates that the upper Muskegon River has a similar post-glacial history as streams on deglacial and periglacial landscapes elsewhere in the world.     

The geography of mercury and PCBs in North Carolina's local seafood

Mercury and PCBs are used by non-governmental organizations and federal agencies to inform seafood safety recommendations. Pollution dynamics suggest recommendations on the national scale may be too large to be accurate. We tested softshell and hardshell blue crab, white and pink shrimp, oysters, clams, spot, and mullet from fishers in each of the three North Carolina fishery districts. We measured mercury using EPA method 7473 and PCBs using a commercially available ELISA kit. Over 97% of samples were below the Environmental Protection Agency levels of concern for both mercury and PCBs. Mercury and PCBs have different spatial dynamics, but both differ significantly by water body, suggesting that seafood safety recommendations should occur by water body instead of at the national scale. This finding supports previous research suggesting that differences in water chemistry, terrestrial influence, and flushing time in a particular water body control the contaminant load in locally resident species.     

Observations of asteroids with ALMA

Thermal observations of large asteroids at millimeter wavelengths have revealed high amplitude rotational lightcurves. Such lightcurves are important constraints on thermophysical models of asteroids, and provide unique insight into the nature of their surface and subsurface composition. A better understanding of asteroid surfaces provides insight into the composition, physical structures, and processing history of these surviving remnants from the formation of our solar system. In addition, detailed observations of the larger asteroids, accompanied by thermophysical models with appropriate temporal and spatial resolution, promise to decrease uncertainties in their flux predictions. Of particular interest are the near-Earth objects, which can be observed at large phase angles, permitting better assessment of the thermal response of their unilluminated surfaces. The high sensitivity of ALMA will enable us to detect many small bodies in all the major groups, to obtain lightcurves for a large sample of main-belt and near-Earth objects, to resolve the surfaces of some large objects, and to separate the emission from primary and secondary objects in binary pairs. In addition to the science goals of asteroid studies, these bodies may also prove useful operationally because those with known shapes and well-characterized lightcurves could be employed for flux calibration by ALMA and other high frequency instruments.     

Activation of Persulfate by Surfactants under Acidic and Basic Conditions

Activated persulfate is a commonly used oxidant source used for in situ chemical oxidation (ISCO) for remediation of subsurface contamination. Surfactants are sometimes used in ISCO to desorb contaminants and dissolve nonaqueous phase liquids (NAPLs). The potential activation of persulfate by such surfactants was investigated, and the reactive oxygen species generated by persulfate in the presence of anionic, nonionic, and cationic surfactants were determined. Twenty surfactants were screened; most activated persulfate to generate reductants + nucleophiles at acidic and basic pH. The most reactive anionic, nonionic, and cationic surfactants (Lankropol 4500, polyethylene glycol 400, and Ethoduomeen T/25) were investigated in more detail. All three surfactants activated persulfate; however, the cationic surfactant showed the most potential for persulfate activation with high fluxes of hydroxyl radical and reductants + nucleophiles. The results of this research demonstrate that surfactants added to ISCO systems often activate persulfate to generate reductants at both acidic and basic pH, and hydroxyl radical at basic pH. These findings provide a new paradigm for persulfate activation in surfactant in situ chemical oxidation (SISCO) systems; pH regimes >11 may not be necessary for persulfate activation resulting in cost savings and potentially more effective activation of persulfate.     

Jupiter's atmospheric temperatures: From Voyager IRIS to Cassini CIRS

Retrievals performed on Cassini Composite Infrared Spectrometer data obtained during the distant Jupiter flyby in 2000/2001 have been used to generate global temperature maps of the planet in the troposphere and stratosphere, but to higher latitudes than were shown previously by Flasar et al. [Flasar, F.M., 39 colleagues, 2004a. Nature 427, 132-135; Flasar, F.M., 44 colleagues, 2004b. Space Sci. Rev. 115, 169-297]. Similar retrievals were performed on Voyager 1 IRIS data to provide the first detailed IRIS map of the stratosphere, and high latitudes in the troposphere. Thermal winds were calculated for each data set and show strong vertical shears in the zonal winds at low latitudes, and meridional temperature gradients indicate the presence of circumpolar jets, as well. The temperatures retrieved from the two spacecraft were also compared with yearly ground-based data obtained over the intervening two decades. Tropospheric temperatures reveal gradual changes at low latitudes, with little obvious seasonal or short-term variation [Orton et al., 1994. Science 265, 625-631]. Stratospheric temperatures show much more complicated behavior over short timescales, consistent with quasi-quadrennial oscillations at low latitudes, as suggested in prior analyses of shorter intervals of ground-based data [Orton et al., 1991. Science 252, 537-542; Friedson, A.J., 1999. Icarus 137, 34-55]. A scaling analysis indicates that meridional motions, mechanically forced by wave or eddy convergence, play an important role in modulating the temperatures and winds in the upper troposphere and stratosphere on seasonal and shorter timescales. At latitudes away from the equator, the mechanical forcing can be derived simply from a temporal record of temperature and its vertical derivative. Ground-based observations with improved vertical resolution and/or long-term monitoring from spacecraft are required for this purpose, though the Voyager and Cassini data given indications that the magnitude of the forcing is very small.     

Hydraulic conductivity prediction for sandy soils

The potential for petroleum-contaminated soils to impact ground water is evaluated using the soil leachability model in South Carolina and Georgia. In this model, the Green and Ampt (1911) equation is used to estimate unsaturated flow with saturated hydraulic conductivity (K(S)) values obtained using the Rawls and Brakensiek (1989) equation from inputs of percent sand- and clay-sized particles. However, many soils have > 70% sand-sized particles, which is the maximum amount for which the Rawls and Brakensiek equation is valid. Therefore, 70 sets of K(S) and particle-size data from the literature for southeastern United States sandy soils were analyzed to develop a new equation for estimating K(S). A multiple linear regression model with an adjusted R2 = 0.65 (p < 0.0001) was developed from percent clay- and sand-sized particle data. Eight additional sets of data were used to validate the model. The root mean square deviation and maximum squared difference, (yi - yi(2)), values for the new model are smaller than those obtained using the Rawls and Brakensiek equation, or Rosetta, a neural network-based model (Schaap 1999). The new model provides estimates that are within an order of magnitude for all but one of the test data sets. Rosetta predicts K(S) within one order of magnitude of measured values for six test data, and predicts K(S) within two orders of magnitude for the other two. The Rawls and Brakensiek predictions are within one order of magnitude for four test data, but are two or more orders of magnitude too high for the remaining four points. The new equation is recommended for estimating K(S) for sandy southeastern United States soils for which inputs are limited to percent sand and clay.