Evaluation of LPM permafrost distribution in NE Asia reconstructed and downscaled from GCM simulations

A high‐resolution map of potential frozen ground distribution in NE Asia (90–150°E, 25–60°N) at the period of the Last Permafrost Maximum (LPM, c. 21 000 years ago) was dually reconstructed by means of a statistical classification using air freezing and thawing indices and a topographical downscaling using a digital relief model (ETOPO1). Background LPM climate data were derived from global climate model simulations of the Paleoclimate Model Intercomparison Project, Phase II (PMIP2). The reconstructed LPM map shows the southward shift of the southern limit of climate‐driven permafrost by 400–1500 km, with the greatest advance in the western sector (90–110°E), encompassing an area from central Siberia to most of the Altai area. The advance of environmentally conditional permafrost and seasonally frozen ground was greatest in the eastern sector (110–150°E), with an average shift of about 450 km. The descent of the lower limit of LPM alpine permafrost was in the range of 400–800 m. A comparison of the reconstructed map with published literature shows that this method, simplistically constructed yet effectively recognizing seasonality, continentality and topography, captures local features better than more elaborate methods. The sensitivity examination of a constant atmospheric lapse rate shows that altitudes of 2000–5000 m a.s.l. were most sensitive, though with only a limited effect on overall LPM distribution.     

Marine debris impacts to a tidal fringing-marsh in North Carolina

We evaluated injuries to Spartina alterniflora by debris items common to North Carolina coastal waters as a function of debris type (wire blue crab pots, vehicle tires, and anthropogenic wood) and deployment duration, and monitored S. alterniflora recovery following debris removal. Injuries sustained by S. alterniflora and subsequent recovery, varied considerably between debris types. Differences were likely due to dissimilarities in the structure and composition of debris. Tires caused an immediate (within 3 weeks) and long-term impact to S. alterniflora; tire footprints remained devoid of vegetation 14 months post-removal. Conversely, crab pot impacts were not as abrupt and recovery was short-term (<10 months). We suggest that removal programs specifically target habitats that are susceptible to negative impacts (e.g., salt marsh) and prone to debris accumulation. Management would benefit from the inclusion of habitat information in removal databases.     

Evaluation of on-line pyrolysis two-dimensional gas chromatography time-of-flight mass spectrometry (Py-GC × GC-ToFMS) on whole sediments from a Mediterranean sapropel sequence

Analysis of the molecular composition of the organic matter (OM) from whole sediment samples can avoid analytical bias that might result from isolation of components from the sediment matrix, but has its own analytical challenges. We evaluated the use of GC × GC-ToFMS to analyze the pyrolysis products of six whole sediment samples obtained from above, within and below a 1 million year old OM-rich Mediterranean sapropel layer. We found differences in pyrolysis products <n-C₂₂ between the OM-rich sapropel samples and the OM-poor background marls. The presence of alkyl pyrroles, probably derived from chlorophyll, in pyrolysates of the sapropels but not in those of the marls suggests that higher marine productivity and greater OM preservation accompanied deposition of the sapropels. Detection of tetramethyl benzenes considered to be pyrolysis products of isorenieratene in the sapropel samples is evidence that nitrogen-fixing green sulfur bacteria contributed to the high productivity. Greater abundances of shorter chain aliphatic hydrocarbons, pyrroles, furans and alkyl aromatics in the pyrolysates of sapropel samples relative to the marls confirm better preservation of marine OM in the sapropels. In addition, the presence of greater amounts of thiophenes in the sapropels than in the marls is consistent with the existence of euxinic conditions during sapropel deposition. The combination of whole sediment pyrolysis and GC × GC-ToFMS is promising, but the procedure requires careful selection of its multiple analytical variables, particularly the pyrolysis temperature and the operational features of the GC columns.     

Hydrocarbon biomarkers of Neoproterozoic to Lower Cambrian oils from eastern Siberia

The Neoproterozoic Era is of widespread geobiological interest because it marks the critical transition from a world of microbes to one where animals become an established feature of the landscape. Much research into this time period has focused on the ventilation of the oceans, as this is widely considered a primary factor driving the diversification of complex, multicellular life. In this study, Proterozoic to Cambrian aged oils from eastern Siberia were analyzed for their hydrocarbon biomarker contents and compound specific carbon isotopes in order to further our understanding of the prevailing environment and its microbial and metazoan communities. Geochemically, these oils are broadly comparable to those of the Ediacaran-Cambrian sedimentary rocks and oils of the South Oman Salt Basin. Organic matter in the source sedimentary rocks included significant contributions from green algae, demosponges and bacteria including cyanobacteria and methanotrophic proteobacteria. Although the ages of the Siberian oils and putative parent source rock intervals are poorly constrained, the geochemical similarities between the Ediacaran Oman Huqf and Nepa-Botuoba-Katanga family of Siberian oil samples are impressive, leading to the inference that their source rocks are coeval. On the other hand, oils from the Baykit High are distinctive, likely older and possibly of Cryogenian age.     

Phosphate amendment of metalliferous waste rocks, Century Pb-Zn mine, Australia: Laboratory and field trials

The aim of the study was to determine whether the application of phosphate compounds (phosphorite rock, phosphate fertilizer) to polyminerallic waste rocks can inhibit sulfide oxidation and metal mobility (Cu, Pb, Zn, Cd, Ni, Mn, Mg). Waste rocks comprised sulfidic carbonaceous shales and were sourced from the Century Pb-Zn mine, NW Queensland, Australia. The acid producing, Pb-Zn rich rocks consisted of major quartz, muscovite/illite, dolomite, siderite and kaolinite as well as smaller amounts of sulfide minerals (e.g. galena, sphalerite, pyrite). Laboratory leach experiments were conducted on finely granulated phosphate-treated waste rocks (>2 to <30 mm) over 13 weeks, whereas phosphate amendment of coarsely granulated waste rocks (sand to boulder size) was investigated using heap leach piles at the mine site over an 11 months period. Results of the laboratory experiments demonstrate that the treatment of finely granulated waste rocks with phosphorite rock produced leachates with near-neutral pH values due to calcite dissolution. This in turn did not allow the leaching of apatite, formation of secondary phosphate phases and phosphate stabilization to occur. Metal mobility in these amended wastes was restricted by the dissolution of calcite and the resultant near-neutral pH conditions. By contrast, the application of the water-soluble phosphate fertilizer MKP (KH₂PO₄) to polyminerallic sulfidic waste rocks during the short-term laboratory experiments led to the formation of phosphate coatings and precipitates and inhibited acid and metal release (Cd, Mn, Ni, Pb, Zn). At least in the short term, the application of phosphate fertilizers proved to be an effective method. However, results of the long-term field trials demonstrate that coarsely granulated waste rocks were not coated by secondary phosphate phases and that amendment by phosphorite rock or superphosphate fertilizer did not improve leachate quality compared to the unamended waste. Thus, phosphate stabilization appears ineffective in suppressing oxidation of sulfides in coarsely granulated mine wastes.     

Characterization of accumulated precipitates during subsurface iron removal

The principle of subsurface iron removal for drinking water supply is that aerated water is periodically injected into the aquifer through a tube well. On its way into the aquifer, the injected O₂-rich water oxidizes adsorbed Fe²⁺, creating a subsurface oxidation zone. When groundwater abstraction is resumed, the soluble Fe²⁺ is adsorbed and water with reduced Fe concentrations is abstracted for multiple volumes of the injection water. In this article, Fe accumulation deposits in the aquifer near subsurface treatment wells were identified and characterized to assess the sustainability of subsurface iron removal regarding clogging of the aquifer and the potential co-accumulation of other groundwater constituents, such as As. Chemical extraction of soil samples, with Acid-Oxalate and HNO₃, showed that Fe had accumulated at specific depths near subsurface iron removal wells after 12 years of operation. Whether it was due to preferred flow paths or geochemical mineralogy conditions; subsurface iron removal clearly favoured certain soil layers. The total Fe content increased between 11.5 and 390.8 mmol/kg ds in the affected soil layers, and the accumulated Fe was found to be 56-100% crystalline. These results suggest that precipitated amorphous Fe hydroxides have transformed to Fe hydroxides of higher crystallinity. These crystalline, compact Fe hydroxides have not noticeably clogged the investigated well and/or aquifer between 1996 and 2008. The subsurface iron removal wells even need less frequent rehabilitation, as drawdown increases more slowly than in normal production wells. Other groundwater constituents, such as Mn, As and Sr were found to co-accumulate with Fe. Acid extraction and ESEM-EDX showed that Ca occurred together with Fe and by X-ray Powder Diffraction it was identified as calcite.     

Reconstructing coastal flood occurrence combining sea level and media sources: a case study of the Solent, UK since 1935

Using newly digitised sea-level data for the ports of Southampton (1935–2005) and Portsmouth (1961–2005) on the south coast of the UK, this study investigates the relationship between the 100 highest sea-level events recorded at the two cities and the incidence of coastal floods in the adjoining Solent region. The main sources of flood data are the daily newspapers The Southern Daily Echo, based in Southampton and The News, based in Portsmouth, supported by a range of local publications and records. The study indicates a strong relationship between the highest measured sea levels and the incidence of coastal floods and highlights the most vulnerable areas to coastal flooding which include parts of Portsmouth, Southampton, Hayling Island, Fareham and Cowes. The most severe flood in the dataset resulted from the storm surge events of 13–17 December 1989 when eight consecutive extreme high waters occurred. The data suggest that while extreme sea-level events are becoming more common, the occurrence of flood events is not increasing. This is attributed to improved flood remediation measures combined with a reduction of storm intensity since the 1980s. However, several recent events of significance were still recorded, particularly 3 November 2005 when Eaststoke on Hayling Island (near Portsmouth) was flooded due to high sea levels combined with energetic swell waves.     

Characterization of mesoscale instabilities in localized granular shear using digital image correlation

Within shear bands in sands, deformation is largely non-affine, stemming primarily from buckling of well-known force chains and also from vortex-like structures. In the spirit of current trends toward multiscale modeling, understanding the links between these mesoscale deformational entities and corresponding macroscale response will form the basis for the next generation of sand behavioral models and may also aid in efforts to understand jamming–unjamming transitions in dense granular flows in general. Experimental methods to quantify and characterize such subscale kinematics, in particular in real sands, will play critical roles in these efforts. Digital Image Correlation (DIC) is a fast growing experimental technique to nondestructively measure surface displacements from digital images. Here, DIC has been employed to identify and characterize the development of vortex structures inside shear bands formed in dense sands during plane strain compression. A rigorous assessment of the DIC method has been performed, in particular for subscale behavioral characterization in unbonded granular solids, and guidelines are offered for accurate implementation. While DIC systematically overestimates shear band thickness, a methodology has been devised to compensate for this overestimation. Shear band thickness for four different uniform sands were found to range between 6 and 9 grain diameters, and for a well-graded sand between 8 and 9.5 grain diameters. These determinations agree with visual inspections of grain kinematics from the image data, as well as recent theoretical predictions.     

Biosecurity's unruly spaces

This paper is about the geopolitics of animal health governance. Through a biosecurity event in South Africa's pig sector we examine changes in the way the governance of disease risk is configuring intra-national spaces. Our case suggests an emerging geopolitics of animal health, one that is defined not by differences between nations but by a more complex patchwork of ‘secure’ and ‘unruly spaces’.