Equilibrium rotational stability and figure of Mars

Studies extending over three decades have concluded that the current orientation of the martian rotation pole is unstable. Specifically, the gravitational figure of the planet, after correction for a hydrostatic form, has been interpreted to indicate that the rotation pole should move easily between the present position and a site on the current equator, 90° from the location of the massive Tharsis volcanic province. We demonstrate, using general physical arguments supported by a fluid Love number analysis, that the so-called non-hydrostatic theory is an inaccurate framework for analyzing the rotational stability of planets, such as Mars, that are characterized by long-term elastic strength within the lithosphere. In this case, the appropriate correction to the gravitational figure is the equilibrium rotating form achieved when the elastic lithospheric shell (of some thickness LT) is accounted for. Moreover, the current rotation vector of Mars is shown to be stable when the correct non-equilibrium theory is adopted using values consistent with recent, independent estimates of LT. Finally, we compare observational constraints on the figure of Mars with non-equilibrium predictions based on a large suite of possible Tharsis-driven true polar wander (TPW) scenarios. We conclude, in contrast to recent comparisons of this type based on a non-hydrostatic theory, that the reorientation of the pole associated with the development of Tharsis was likely less than 15° and that the thickness of the elastic lithosphere at the time of Tharsis formation was at least ∼50 km. Larger Tharsis-driven TPW is possible if the present-day gravitational form of the planet at degree 2 has significant contributions from non-Tharsis loads; in this case, the most plausible source would be internal heterogeneities linked to convection.     

Applications of a total dissolved gas pressure probe in ground water studies

Measurements of dissolved gases have numerous applications in ground water hydrology, and it is now possible to measure the total dissolved gas pressure in situ using a probe. Dissolved gas pressure is measured by submerging a headspace volume with a gas-permeable membrane, allowing dissolved gases in the water to equilibrate with gases in the headspace, then measuring the pressure in the headspace with a pressure transducer. Total dissolved gas pressure (TGP) probes have many potential uses in ground water studies employing dissolved gases, including: (1) determining approximate excess air levels, which may provide information about the time and location of recharge; (2) screening wells for air contamination, which can compromise the accuracy of dissolved gas tracer techniques: (3) detecting a trapped gas phase, which can significantly reduce hydraulic conductivity and impede the transport of dissolved solutes and gases; (4) enabling the use of gas-filled passive diffusion samplers for determining accurate dissolved gas concentrations; and (5) determining relative concentrations of CH4 and CO2 when they are known to be highly abundant. Although TGP probes designed for surface water have been available for several years, TGP probes suitable for ground water applications have only recently become available. Herein we present what are, to our knowledge, the first reported ground water dissolved gas data collected using a TGP probe. We also explain the basic operating principles of these probes and discuss the potential applications listed.     

Metal–organic complexation in the marine environment

We discuss the voltammetric methods that are used to assess metal–organic complexation in seawater. These consist of titration methods using anodic stripping voltammetry (ASV) and cathodic stripping voltammetry competitive ligand experiments (CSV-CLE). These approaches and a kinetic approach using CSV-CLE give similar information on the amount of excess ligand to metal in a sample and the conditional metal ligand stability constant for the excess ligand bound to the metal. CSV-CLE data using different ligands to measure Fe(III) organic complexes are similar. All these methods give conditional stability constants for which the side reaction coefficient for the metal can be corrected but not that for the ligand. Another approach, pseudovoltammetry, provides information on the actual metal–ligand complex(es) in a sample by doing ASV experiments where the deposition potential is varied more negatively in order to destroy the metal–ligand complex. This latter approach gives concentration information on each actual ligand bound to the metal as well as the thermodynamic stability constant of each complex in solution when compared to known metal–ligand complexes. In this case the side reaction coefficients for the metal and ligand are corrected. Thus, this method may not give identical information to the titration methods because the excess ligand in the sample may not be identical to some of the actual ligands binding the metal in the sample.     

Diatom-inference models for surface-water temperature and salinity developed from a 57-lake calibration set from the Sierra Nevada, California, USA

Physical, chemical, and biological data were collected from a suite of 57 lakes that span an elevational gradient of 1360 m (2115 to 3475 m a.s.l.) in the eastern Sierra Nevada, California, USA as part of a multiproxy study aimed at developing transfer functions from which to infer past drought events. Multivariate statistical techniques, including canonical correspondence analysis (CCA), were used to determine the main environmental variables influencing diatom distributions in the study lakes. Lakewater depth, surface-water temperature, salinity, total Kjeldahl nitrogen, and total phosphorus were important variables in explaining variance in the diatom distributions. Weighted-averaging (WA) and weighted-averaging partial least squares (WA-PLS) were used to develop diatom-based surface-water temperature and salinity inference models. The two best diatom-inference models for surface-water temperature were developed using simple WA and inverse deshrinking. One model covered a larger surface-water temperature gradient (13.7 °C) and performed slightly poorer (r² = 0.72, RMSE = 1.4 °C, RMSEP_jack = 2.1 °C) than a second model, which covered a smaller gradient (9.5 °C) and performed slightly better (r² = 0.89, RMSE = 0.7 °C, RMSEP_jack = 1.5 °C). The best diatom-inference model for salinity was developed using WA-PLS with three components (r² = 0.96, RMSE = 4.06 mg L^–1, RMSEP_jack = 11.13 mg L^–1). These are presently the only diatom-based inference models for surface-water temperature and salinity developed for the southwestern United States. Application of these models to fossil-diatom assemblages preserved in Sierra Nevada lake sediments offers great potential for reconstructing a high-resolution time-series of Holocene and late Pleistocene climate and drought for California.     

Changes of lead and barium with time in California off-shore basin sediments

During ancient times the natural deposition fluxes of lead which can be leached with dilute acid from sediments in Santa Barbara, Santa Monica and San Pedro basins offshore from the Los Angeles Urban complex, were about 0.7, 0.1 and 0.2 μg Pb/cm² yr respectively. Since there was little difference in biological productivity in surface waters of these basins, it is proposed that clay is a major transport vehicle for sequestered soluble lead, which then explains why the lead deposition flux within the Santa Barbara basin was so much larger compared to the other basins. The fluxes of silicate mud in the basins in ancient times were about 92, 19 and 30 mg/cm² yr in Santa Barbara, Santa Monica and San Pedro basins respectively. Today deposition fluxes of acid soluble lead within these three basins are 3- to 9-fold greater, being about 2.1, 1.1 and 1.8 μg Pb/cm² yr respectively, partly in the form of directly deposited large sewage particles, which account for none, $\text{2}\text{3}$ and $\text{3}\text{4}$ of the total industrial lead deposition fluxes in the respective basins. Concentrations of leachable lead in varve dated sediment layers increase with time and isotopic compositions of these leads change in accordance with corresponding known changes of isotopic compositions of industrial lead in the Los Angeles atmosphere. Lead remaining in acid leached sediment residues originates from igneous and clay minerals, exhibiting no change in concentration or isotopic composition since pre-industrial times.Deposition fluxes of total barium in sediments among the three basins were proportional to mass deposition fluxes before 1950 in the same manner as for lead. Afterwards, there are barium concentration maxima with time in both Santa Monica and San Pedro Basin sediments which are attributable to industrial sewage rather than to episodic erosion from barium-rich sedimentary evaporite strata exposed locally along the shore. An increase of barium concentrations in present day Santa Barbara basin sediments may reflect dispersal of barium-rich drilling mud from local drilling operations.     

Taking the Pulse of Mountains: Ecosystem Responses to Climatic Variability

An integrated program of ecosystem modeling and field studies in the mountains of the Pacific Northwest (U.S.A.) has quantified many of the ecological processes affected by climatic variability. Paleoecological and contemporary ecological data in forest ecosystems provided model parameterization and validation at broad spatial and temporal scales for tree growth, tree regeneration and treeline movement. For subalpine tree species, winter precipitation has a strong negative correlation with growth; this relationship is stronger at higher elevations and west-side sites (which have more precipitation). Temperature affects tree growth at some locations with respect to length of growing season (spring) and severity of drought at drier sites (summer). Furthermore, variable but predictable climate-growth relationships across elevation gradients suggest that tree species respond differently to climate at different locations, making a uniform response of these species to future climatic change unlikely. Multi-decadal variability in climate also affects ecosystem processes. Mountain hemlock growth at high-elevation sites is negatively correlated with winter snow depth and positively correlated with the winter Pacific Decadal Oscillation (PDO) index. At low elevations, the reverse is true. Glacier mass balance and fire severity are also linked to PDO. Rapid establishment of trees in subalpine ecosystems during this century is increasing forest cover and reducing meadow cover at many subalpine locations in the western U.S.A. and precipitation (snow depth) is a critical variable regulating conifer expansion. Lastly, modeling potential future ecosystem conditions suggests that increased climatic variability will result in increasing forest fire size and frequency, and reduced net primary productivity in drier, east-side forest ecosystems. As additional empirical data and modeling output become available, we will improve our ability to predict the effects of climatic change across a broad range of climates and mountain ecosystems in the northwestern U.S.A.     

Rapid tectonic exhumation, detachment faulting and orogenic collapse in the Caledonides of western Ireland

Collision of the oceanic Lough Nafooey Island Arc with the passive margin of Laurentia after 480 Ma in western Ireland resulted in the deformation, magmatism and metamorphism of the Grampian Orogeny, analogous to the modern Taiwan and Miocene New Guinea Orogens. After 470 Ma, the metamorphosed Laurentian margin sediments (Dalradian Supergroup) now exposed in Connemara and North Mayo were cooled rapidly (>35 °C/m.y.) and exhumed to the surface. We propose that this exhumation occurred mainly as a result of an oceanward collapse of the colliding arc southwards, probably aided by subduction rollback, into the new trench formed after subduction polarity reversal following collision. The Achill Beg Fault, in particular, along the southern edge of the North Mayo Dalradian Terrane, separates very low-grade sedimentary rocks of the South Mayo Trough (Lough Nafooey forearc) and accreted sedimentary rocks of the Clew Bay Complex from high-grade Dalradian meta-sedimentary rocks, suggesting that this was a major detachment structure. In northern Connemara, the unconformity between the Dalradian and the Silurian cover probably represents an eroded major detachment surface, with the Renvyle–Bofin Slide as a related but subordinate structure. Blocks of sheared mafic and ultramafic rocks in the Dalradian immediately below this unconformity surface probably represent arc lower crustal and mantle rocks or fragments of a high level ophiolite sheet entrained along the detachment during exhumation.Orogenic collapse was accompanied in the South Mayo Trough by coarse clastic sedimentation derived mostly from the exhuming Dalradian to the north and, to a lesser extent, from the Lough Nafooey Arc to the south. Sediment flow in the South Mayo Trough was dominantly axial, deepening toward the west. Volcanism associated with orogenic collapse (Rosroe and Mweelrea Formations) is variably enriched in high field strength elements, suggesting a heterogeneous enriched mantle wedge under the new post-collisional continental arc.     

Determination of sediment provenance at drift sites using hydrogen isotopes and unsaturation ratios in alkenones

The large (∼20‰) hydrogen isotopic gradient in surface waters of the northwest Atlantic Ocean is exploited to track changes in the source of alkenones to the Bermuda Rise sediment drift. Cultures of the predominant alkenone-producing coccolithophorid, E. huxleyi, were grown in deuterium-enriched seawater and shown to possess alkenones with a D/H ratio that closely tracked the water D/H ratio (r² = 0.999, n = 5 isotopic enrichments) with a fractionation factor (α) between 0.732 and 0.775. A hydrogen isotopic depletion of -193 ± 3‰ (n = 9) was measured in alkenones from suspended particles relative to seawater in the subpolar and subtropical northwest Atlantic Ocean. This value was used to calculate the water δD values in which alkenones from Bermuda Rise sediment were synthesized, and by extension, the water mass in which they were produced. Applying this technique we find that 60% to 100% of the alkenones in late Holocene Bermuda Rise sediment were produced in deuterium-depleted subpolar water to the northwest of the drift. To reconcile values of the alkenone unsaturation ratio (U^k′₃₇), a widely used proxy for sea surface temperature, with the δD values of alkenones in late Holocene sediments from the Bermuda Rise at least three sources of sediment must be invoked: a cold, very isotopically depleted source, almost certain to be the Scotian Margin; a warm, moderately isotopically-depleted source, likely to be the northwestern edge of the subtropical gyre; and a cold, isotopically enriched source, which we hypothesize to be the subpolar waters overlying the main branch of North Atlantic Deep Water flowing southwest from the Nordic Seas.