Exploration for Mississippi-Valley type stratabound Zn ores with stream suspensates and stream sediments, Virginia, U.S.A.

Suspended and equivalent active sediments were collected from streams at 84 sites at the eastern and western sides of a ridge with stratabound Zn mineralization, Rockingham County, Virginia (USA). The purpose was to evaluate the relative effectiveness of suspended and bottom sediment in the geochemical exploration for Mississippi-Valley type Zn ores. The orebody is composed of sphalerite and minor amounts of galena with some chalcopyrite, strikes parallel to the enclosing dolomite beds at N34°E, and cuts vertically across the 30°SE dip. Oxidation of the ore extends to about 100 m in depth.Zinc was effective in detecting the mineralized zone. Zinc in the suspensates provided a denser anomaly system (7 strong and 2 moderate samples) than Zn in the <150 μm size of the bottom sediment, either totally dissolved (4 strong and 1 moderate anomalies) or extracted with cold 3% HCl (5 strong and 3 moderate anomalies). The magnitude of the high values for suspensate Zn was considerably higher than those for the other sample types studied. Suspensate Zn was complemented by 3 strong suspensate Cu anomalies. The suspensate Zn anomaly dispersion was about 850 m, 400 m of which was upstream from the mineralization. Lead was detected only in the cold acid extraction and in combination with Cu and Zn gave an extensive overlapping multielement anomaly string that targeted the ore zone and had a dispersion downstream from the mineralization of more than 1000 m. The Pb anomalies extended about 900 m upstream and 400 m downstream from the ore zone. Together with suspensate Zn, the Pb anomalies suggest a continuation of mineralization upstrike from the known orebody.The major anomaly systems are along the eastern side of the ridge with comparatively few anomalies present in the drainage along the western side. The concentration of anomalies in the eastern drainage and anomaly disposition with respect to known mineralization result from structural control on the hydromorphic dispersion of metals from the orebody.     

A moderate melting model for the Vøring margin (Norway) based on structural observations and a thermo-kinematical modelling: Implication for the meaning of the lower crustal bodies

High P-wave velocities (7.1–7.8 km/s) lower crustal bodies (LCBs) imaged along volcanic margins are commonly interpreted as plume and breakup-related thick mafic underplating. This interpretation is partly challenged in this paper based on new seismic observations and modelling of the outer Vøring Basin (Norway). An exceptional strong amplitude reflection, the T Reflection, is particularly well defined below the North Gjallar Ridge (NGR) between 7and 8 s TWT. The T Reflection is located near the volcanic lava flows emplaced during the NE Atlantic breakup ( 55–54 Ma ago) and coincides with the top of the LCB, forming a mid-crustal dome. Based on structural and temporal relationships, we show that the dome clearly influences the structural development of the NGR and predates the continental breakup at least by 10–15 Ma. Using a thermo-kinematical model, we tried also to investigate and quantify the relationships between the extension, LCB and the magmatic production. Modelling suggests that significant Paleocene–Early Eocene magmatism can be produced without any temperature anomaly in the mantle if differential stretching occurs during the breakup initiation. The conclusion of 2D thermo-kinematical parametric analysis is that the magmatic model predicts, either little extension (β < 2) with no melting or high extension (β > 5) with significant melting along the outer Vøring Basin. We suggest that the continental part of the LCB could not necessarily be breakup-related and so magmatic, as has often been stated previously. It is concluded here that the continental part of the LCB observed beneath the outer Vøring Basin may be partly (or fully) attributed to inherited, high-pressure granulite/eclogite lower crustal rocks. The real amount of mafic material emplaced along the outer Vøring Basin could be 20–40% less than thought.     

Factors influencing subaqueous dunes in the Scheldt Estuary

The size (wavelength and height) and the factors influencing the characteristics of subaqueous dunes in the river Scheldt between Antwerp and the Belgian-Dutch border were studied. More than 60 dune clusters (each cluster represented by a mean height and wavelength of mostly 10 to 20 or more observations) were analysed. A very good exponential correlation between dune height and wavelength was observed (r=0.90) which can be described by H _mean=0.0321L ^0.918. Length/depth ratios vary between 0.2 and 9, height/depth ratios between 0.25 and 0.01. There was no clear relationship between current velocity and dune size, as dunes of various sizes co-exist at the same current velocities. Twenty-two dunes were sampled and show grain sizes (d50) ranging between 0.1 and 0.7 mm. Seven out of eight large scale dune fields were found in sandy and/or hard bottom (gravel, coarse sand and shell fragments) environments, whereas small and medium dunes were found in muddy sand and sandy mud environments.     

Fluidization and multiphase transport of particulate cometary material as an explanation of the smooth terrains and repetitive outbursts on 9P/Tempel 1

The Deep Impact mission discovered repetitive outbursts on Comet 9P/Tempel 1 and the presence of several smooth terrains on its surface. We present new measurements of the extent of the smooth terrains, the slopes along their centerlines, and the areas of their likely source regions. Our analysis of these features indicates that they are <700 orbits old and probably the result of an ongoing process. The implications of the recently found locations of the source regions of the repetitive outbursts are also analyzed. We propose that the origins of these phenomena are in the different regimes of fluidization and gas transport in a weakly bound particulate mixture of ice and dust above an assumed amorphous/crystalline H₂O phase change boundary where CO and/or CO₂ gas is released. The depth of this boundary is estimated to lie between 30 and 100 m below the surface. The smooth terrains are visualized as occurring about once every ∼70 orbits at random locations of the nucleus where a spurt in CO production occurs over a limited region of the phase change boundary. The weak (tensile strength ) crystalline and dust overburden is locally ruptured and fluidized by the CO gas pressure and is then extruded onto the surface at speeds of ∼0.003-0.03 m/s, well below the escape velocity of 1.3 m/s. Once on the surface a base pressure of only 2.5 Pa is required to ensure fluidization of the extruded material and it can remain fluidized for typically ∼20 h against diffusive loss of CO. As the material accelerates down the local topography it deflates due to diffusive gas loss. The flow becomes increasingly viscous until it is no longer fluidized at which point it quickly halts forming a terminal scarp. The mean speed of the laminar flow is estimated at 0.3 m/s for an emplacement time of ∼3 h. Topographic features on the flow >0.3 m in size should become fully relaxed during the emplacement time explaining the smooth texture seen in the images. In contrast, the repetitive outbursts require a gas-laden reservoir to have formed in the vicinity of the phase change boundary well below their preferred location. We visualize the outbursts to be the result of either spouting or bubble transport to the surface where the release of gas is diurnally modulated by either thermal stresses or H₂O sublimation back pressure. The source region for the i2 smooth terrain is found to coincide with an H₂O-ice rich area and we propose that the process of elutriation, i.e., the separation of different classes of particulates depending on their drag properties, occurs in the fluidized material as it flows up to and through the surface. In this way the material becomes enhanced in H₂O crystals relative to siliceous and carbonaceous particulates.     

Increased concentrations of potassium in heartwood of trees in response to groundwater contamination

The wood of tuliptrees (Liriodendron tulipifera L.) growing above groundwater contamination from a hazardous-waste landfill in Maryland contained elevated concentrations of potassium (K). The groundwater contamination also contained elevated concentrations of dissolved K, as well as arsenic (As), cadmium (Cd), chloride (Cl), iron (Fe), manganese (Mn), zinc (Zn), and organic solvents. The dissolved K is derived from disposed smoke munitions. The excess K in the tuliptrees is concentrated in the heartwood, the part of the xylem most depleted in K in trees growing outside of the contamination. These data show that the uptake and translocation of K by tuliptrees can be strongly influenced by the availability of K in groundwater contamination and suggest the utility of this species as an areal indicator of groundwater contamination.     

The influence of sediment size,relative grain size and channel slope on initiation of sediment motion in boulder bed rivers. A lichenometric study

Sediment transport of four boulder bed rivers is studied using lichenometry. The presence of lichens on boulders in the river channel is used to date the last mobilization of the blocks. Using size frequency diagrams and regional growth curves calibrated with dated reference points it is possible to determine the flood event responsible for the last mobilization of each boulder with lichens present. The specific stream power of flood events over the last 60 years is then calculated, and thresholds of sediment transport based on the sediment size are calculated. The results from the four studied rivers are compared to similar relationships in the literature. Sediment motion thresholds appear to be very variable within the same type of river (mountainous boulder bed rivers). The critical specific stream power necessary to mobilize a particle of a given diameter may vary by up to 10 times from one river to the next. Bed sediment size and river slope may explain this large range of stream powers. Calculation of the relative size of the transported particles (D_i/D₅₀) also shows that both hiding and protrusion effects, as well as channels slope, are important factors in sediment transport. Copyright © 2010 John Wiley & Sons, Ltd.     

Identifying geochemical reactions on wellbore cement/caprock interface under sequestration conditions

The integrity of wells, which are key components for CO₂ sequestration, depends mainly on the seal between the wellbore cement and the geologic formation. To identify the reaction products that may alter the cement/caprock interface, batch experiments and computer modelling were conducted and analysed. Over time, the dissolution and precipitation of minerals alters the physical properties of the interface, including its tightness. One main objective of the simulation was thus to analyse the evolution of the porosity of cement and caprock over time. The alteration of the cement/caprock interface was identified as a complex problem and differentiated depending on rock type. The characteristic feature of a cement/shale contact zone is the occurrence of a highly carbonated, compacted layer within the shale, which in turn causes cement/shale detachment. In the case of a cement/anhydrite interface, the most important reaction is severe anhydrite dissolution. Secondary calcite precipitation takes place in deeper parts of the rock. The cement/rock contact zone is prone to rapid mineral dissolution, which contributes to increased porosity and may alter the well integrity. Comparison of computer simulations with autoclave experiments enabled the adjustment of unknown parameters. This enhances the knowledge of these particular assemblages. Overall, a good match was obtained between experiments and simulations, which enhances confidence in using models to predict longer-term evolution.