Isotopic fractionation of Cu in tektites

Tektites are terrestrial natural glasses of up to a few centimeters in size that were produced during hypervelocity impacts on the Earth’s surface. It is well established that the chemical and isotopic composition of tektites is generally identical to that of the upper terrestrial continental crust. Tektites typically have very low water content, which has generally been explained by volatilization at high temperature; however, the exact mechanism is still debated. Because volatilization can fractionate isotopes, comparing the isotopic composition of volatile elements in tektites with those of their source rocks may help to understand the physical conditions during tektite formation.Interestingly, volatile chalcophile elements (e.g., Cd and Zn) seem to be the only elements for which isotopic fractionation is known so far in tektites. Here, we extend this study to Cu, another volatile chalcophile element. We have measured the Cu isotopic composition for 20 tektite samples from the four known different strewn fields. All of the tektites (except the Muong Nong-types) are enriched in the heavy isotopes of Cu (1.98 < δ⁶⁵Cu < 6.99) in comparison to the terrestrial crust (δ⁶⁵Cu ≈ 0) with no clear distinction between the different groups. The Muong Nong-type tektites and a Libyan Desert Glass sample are not fractionated (δ⁶⁵Cu ≈ 0) in comparison to the terrestrial crust. To refine the Cu isotopic composition of the terrestrial crust, we also present data for three geological reference materials (δ⁶⁵Cu ≈ 0).An increase of δ⁶⁵Cu with decreasing Cu abundance probably reflects that the isotopic fractionation occurred by evaporation during heating. A simple Rayleigh distillation cannot explain the Cu isotopic data and we suggest that the isotopic fractionation is governed by a diffusion-limited regime. Copper is isotopically more fractionated than the more volatile element Zn (δ^66/64Zn up to 2.49‰). This difference of behavior between Cu and Zn is predicted in a diffusion-limited regime, where the magnitude of the isotopic fractionation is regulated by the competition between the evaporative flux and the diffusive flux at the diffusion boundary layer. Due to the difference of ionic charge in silicates (Zn²⁺ vs. Cu⁺), Cu has a diffusion coefficient that is larger than that of Zn by at least two orders of magnitude. Therefore, the larger isotopic fractionation in Cu than in Zn in tektites is due to the significant difference in their respective chemical diffusivity.     

Geophysical and Geoarchaeological Investigations at Aganoa Beach,American Samoa: An Early Archaeological Site in Western Polynesia

Archaeological investigations at Aganoa, a coastal site in American Samoa, western Polynesia, revealed a marine resources exploitation base for the early inhabitants of the island. A series of 19 radiocarbon age determinations indicates the principal period of site utilization began no later than 570 B.C., and probably earlier, and lasted for about 300 years. This site is squarely in the phase identified by previous scholars as “ancestral Polynesian.” Geophysical survey in the form of long, shore‐perpendicular transects showed the accretionary history of this beach and ridge area. Surprisingly, it revealed that the earlier ridges were directly below the modern ridge (i.e., progradation of this geomorphic feature had not occurred). The survey revealed a buried paleosol with little or no disturbance, which yielded a well‐preserved assemblage of plain and decorated ceramics, stone artifacts, fishhooks, and archaeofauna. No evidence of archaeological continuity was seen between the end of the terminal Lapita occupation and the later reoccupation of the site after about A.D. 700. This study demonstrates the utility and feasibility of using ground‐penetrating radar for the discovery of deeply buried coastal sites.     

High resolution simulation of the South Asian monsoon using a variable resolution global climate model

This study examines the feasibility of using a variable resolution global general circulation model (GCM), with telescopic zooming and enhanced resolution (~35 km) over South Asia, to better understand regional aspects of the South Asian monsoon rainfall distribution and the interactions between monsoon circulation and precipitation. For this purpose, two sets of ten member realizations are produced with and without zooming using the LMDZ (Laboratoire Meteorologie Dynamique and Z stands for zoom) GCM. The simulations without zoom correspond to a uniform 1° × 1° grid with the same total number of grid points as in the zoom version. So the grid of the zoomed simulations is finer inside the region of interest but coarser outside. The use of these finer and coarser resolution ensemble members allows us to examine the impact of resolution on the overall quality of the simulated regional monsoon fields. It is found that the monsoon simulation with high-resolution zooming greatly improves the representation of the southwesterly monsoon flow and the heavy precipitation along the narrow orography of the Western Ghats, the northeastern mountain slopes and northern Bay of Bengal (BOB). A realistic Monsoon Trough (MT) is also noticed in the zoomed simulation, together with remarkable improvements in representing the associated precipitation and circulation features, as well as the large-scale organization of meso-scale convective systems over the MT region. Additionally, a more reasonable simulation of the monsoon synoptic disturbances (lows and disturbances) along the MT is noted in the high-resolution zoomed simulation. On the other hand, the no-zoom version has limitations in capturing the depressions and their movement, so that the MT zone is relatively dry in this case. Overall, the results from this work demonstrate the usefulness of the high-resolution variable resolution LMDZ model in realistically capturing the interactions among the monsoon large-scale dynamics, the synoptic systems and the meso-scale convective systems, which are essential elements of the South Asian monsoon system.     

Intensity measures for probabilistic assessment of non‐structural components acceleration demand

A fundamental issue in the framework of seismic probabilistic risk analysis is the choice of ground motion intensity measures (IMs). Based on the floor response spectrum method, the present contribution focuses on the ability of IMs to predict non‐structural components (NSCs) horizontal acceleration demand. A large panel of IMs is examined and a new IM, namely equipment relative average spectral acceleration (E‐ASA_R), is proposed for the purpose of NSCs acceleration demand prediction. The IMs efficiency and sufficiency comparisons are based on (i) the use of a large dataset of recorded earthquake ground motions; (ii) numerical analyses performed on three‐dimensional numerical models, representing actual structural wall and frame buildings; and (iii) systematic statistical analysis of the results. From the comparative study, the herein introduced E‐ASA_R shows high efficiency with respect to the estimation of maximum floor response spectra ordinates. Such efficiency is particularly remarkable in the case of structural wall buildings. Besides, the sufficiency and the simple formulation allowing the use of existing ground motion prediction models make the E‐ASA_R a promising IMs for seismic probabilistic risk assessment. Copyright © 2015 John Wiley & Sons, Ltd.     

Whitefish wars: Pangasius, politics and consumer confusion in Europe

Rapid growth in production of the farmed Vietnamese whitefish pangasius and its trade with the European Union has provoked criticism of the fish's environmental, social and safety credentials by actors including WWF and Members of the European Parliament and associated negative media coverage. This paper reviews the range of claims communicated about pangasius (identified as a form of mass mediated risk governance), in light of scientific evidence and analysis of data from the EU's Rapid Alert System for Food and Feeds food safety notification system for imported seafood. This analysis shows pangasius to be generally safe, environmentally benign and beneficial for actors along the international value chains that characterise the trade. The case is made that increasingly politicised debates in Europe around risk and uncertainty are potentially counterproductive for EU seafood security and European aquaculture industry, and that the trade in pangasius can contribute to sustainable seafood consumption in a number of ways. Transparent evidence-based assessment and systems for communicating complex issues of risk for products such as pangasius are required in order to support continuance of fair and mutually beneficial trade.     

The social relations of catfish production in Vietnam

The growth of intensive export-oriented Pangasius catfish production in Vietnam’s Mekong Delta is unparalleled in terms of rapidity and scale by any other agricultural sector, with production climbing from a low base to more than 1 million tons in a single decade. This paper examines the effects of this remarkable change on the rural class structure in locations where catfish farming has boomed, and analyses the role of local state-society relations in mediating outcomes resulting from the integration of local actors into the global value chain. We conclude that private economic activity is deeply embedded in informal relations with the state bureaucracy in Vietnam, with the result that the expansion of catfish aquaculture has generally acted to reproduce and entrench existing class relations rather leading to a radical reconfiguration of the rural class structure.     

Formation process of pyrite polyframboid based on the heavy-metal analysis by micro-PIXE

Pyrite framboid in sedimentary rocks could be concerned with arsenic contamination in groundwater of acidic environment and has been studied for the formation process of its unique morphology. However, not much has been discussed about the formation process based on the heavy-metal distribution in pyrite framboids and their aggregates. To reveal the formation process of pyrite framboids and their aggregates, mudstone from the Late Cretaceous Hakobuchi Group, central Hokkaido, Japan, are investigated for mode, petrographical, mineralogical, and micro-PIXE (particle-induced X-ray emission) analysis in this study. Spherical and sub-spherical pyrite framboids observed in polyframboids can be divided into two types based on the diameter of framboids (D) and the average diameter of microcrystals (d) within framboids: type 1, ranging from 2 to 9 μm and from 0.4 to 0.9 μm, respectively, and type 2, ranging from 8 to 50 μm and from 0.5 to 1.8 μm, respectively. Based on the quantitative traverse analyses and 2-D elemental mapping results by micro-PIXE, heterogeneities in the concentrations of heavy metals within the analyzed aggregations of pyrite are exhibited. On the basis of the As and Pb zoning patterns, the time range and chronological stages of pyrite-aggregation growth are revealed.     

Multiple time-scale modelling of the circulation in Torres Strait—Australia

Ocean circulation influences nearly all aspects of the marine ecosystem. This study describes the water circulation patterns on time scales from hours to years across Torres Strait and adjacent gulfs and seas, including the north of the Great Barrier Reef. The tridimensional circulation model incorporated realistic atmospheric and oceanographic forcing, including winds, waves, tides, and large-scale regional circulation taken from global model outputs. Simulations covered a hindcast period of 8 years (i.e. 01/03/1997–31/12/2004), allowing the tidal, seasonal, and interannual flow characteristics to be investigated. Results indicated that the most energetic current patterns in Torres Strait were strongly dominated by the barotropic tide and its spring-neap cycle. However, longer-term flow through the strait was mainly controlled by prevailing winds. A dominant westward drift developed in summer over the southeasterly trade winds season, which then weakened and reversed in winter over the northwesterly monsoon winds season. The seasonal flow through Torres Strait was strongly connected to the circulation in the north of the Great Barrier Reef, but showed little connectivity with the coastal circulation in the Gulf of Papua. Interannual variability in Torres Strait was highest during the monsoon period, reflecting variability in wind forcing including the timing of the monsoon. The characteristics of the circulation were also discussed in relation to fine sediment transport. Turbidity level in Torres Strait is expected to peak at the end of the monsoon, while it is likely to be at a low at the end of the trade season, eventually leading to a critically low bottom light level which constitutes a severe risk of seagrass dieback.     

The stratospheric version of LMDz: dynamical climatologies, arctic oscillation, and impact on the surface climate

A climatology of the stratosphere is determined from a 20-year integration with the stratospheric version of the Atmospheric General Circulation Model LMDz. The model has an upper boundary at near 65 km, uses a Doppler spread non-orographic gravity waves drag parameterization and a subgrid-scale orography parameterization. It also has a Rayleigh damping layer for resolved waves only (not the zonal mean flow) over the top 5 km. This paper describes the basic features of the model and some aspects of its radiative-dynamical climatology. Standard first order diagnostics are presented but some emphasis is given to the model’s ability to reproduce the low frequency variability of the stratosphere in the winter northern hemisphere. In this model, the stratospheric variability is dominated at each altitudes by patterns which have some similarities with the arctic oscillation (AO). For those patterns, the signal sometimes descends from the stratosphere to the troposphere. In an experiment where the parameterized orographic gravity waves that reach the stratosphere are exaggerated, the model stratosphere in the NH presents much less variability. Although the stratospheric variability is still dominated by patterns that resemble to the AO, the downward influence of the stratosphere along these patterns is near entirely lost. In the same time, the persistence of the surface AO decreases, which is consistent with the picture that this persistence is linked to the descent of the AO signal from the stratosphere to the troposphere. A comparison between the stratospheric version of the model, and its routinely used tropospheric version is also done. It shows that the introduction of the stratosphere in a model that already has a realistic AO persistence can lead to overestimate the actual influence of the stratospheric dynamics onto the surface AO. Although this result is certainly model dependent, it suggests that the introduction of the stratosphere in a GCM also call for a new adjustment of the model parameters that affect the tropospheric variability.     

Increased benthic grazing: An alternative explanation for low phytoplankton biomass in northern San Francisco Bay during the 1976–1977 drought

Among the consequences of extremely low river flow into northern San Francisco Bay during a two-year drought were (1) a gradual increase in salinity, (2) an unusual decline in chlorophyll a concentration, and (3) the upstream migration of estuarine benthic invertebrates to the normally brackish area of the bay. Total abundance in the benthos at a shallow monitoring site increased from a normal 2000 to greater than 20 000 individuals m^?2 during the summer of 1977, presumably in response to the increased salinity. Estimated filtration rates derived from equations in the literature for one of the species, the suspended-feeding bivalve Mya arenaria ranged from 1 to 4 m³ m^?2 day^?1 during 1977 depending on abundance and mean size on sampling dates. Because water depth at this site is less than 2 m, Mya could have filtered all of the particles (including diatoms) from the water column on the order of once per day. Several other immigrant species undoubtedly contributed to the removal of particles from the near-bottom water as well. Increased benthic grazing, therefore, could have accounted for the anomalously low phytoplankton biomass observed during the drought. These results suggest that during periods of prolonged low river flow and increased salinity benthic food webs could become more important than planktonic food webs in the upper part of the estuary.