Closed system behaviour of argon in osumilite records protracted high‐T metamorphism within the Rogaland–Vest Agder Sector,Norway

Here, we present results of the first ⁴⁰Ar/³⁹Ar dating of osumilite, a high‐T mineral that occurs in some volcanic and high‐grade metamorphic rocks. The metamorphic osumilite studied here is from a metapelitic rock within the Rogaland–Vest Agder Sector, Norway, an area that experienced regional granulite facies metamorphism and subsequent contact metamorphism between 1,100 Ma and 850 Ma. The large grain size (~1 cm) of osumilite in the studied rock, which preserves a nominally anhydrous assemblage, increases the potential for large portions of individual grains to have remained essentially unaffected by the effects of diffusive argon loss, potentially preserving prograde ages. Step‐heating diffusion experiments yielded a maximum activation energy of ~461 kJ/mol and a pre‐exponential factor of ~8.34 × 10⁸ cm²/s for Ar diffusion in osumilite. These parameters correspond to a relatively high closure temperature of ~620°C for a cooling rate of 10°C/Ma in an osumilite crystal with a 175 µm radius. Fragments of osumilite separated from the sample preserve a range of ages between c. 1,070 and 860 Ma. The oldest ages are inferred to date the growth of coarse‐grained osumilite during prograde granulite facies regional metamorphism, which pre‐date contact metamorphism that has historically been ascribed to the growth of osumilite in the region. The majority of fragments record ages between c. 920 and 860 Ma, inferred to reflect the growth of osumilite and/or diffusive argon loss during contact metamorphism. The retention of old ⁴⁰Ar/³⁹Ar dates was facilitated by the low diffusivity of Ar in osumilite (i.e. a closed system), large grain sizes, and anhydrous metamorphic conditions. The ability to date osumilite with the ⁴⁰Ar/³⁹Ar method provides a valuable new thermochronometer that may constrain the timing and duration of high‐T magmatic and metamorphic events.     

Diatoms on Earth, Comets, Europa and in Interstellar Space

There exists a close correspondence between the measured infrared properties of diatoms and the infrared spectrum of interstellar dust as observed in the Trapezium nebula and toward the galactic center source GC-IRS 7. Diatoms and bacteria also exhibit an absorbance peak near 2200 Å, which is found to agree with the observed ultraviolet absorbance properties of interstellar grains. We review the observational data and consider the known properties of diatoms and bacteria. It is suggested that these characteristics are consistent with the concept of acosmic microbiological system in which these or similar microorganisms might exist on comets, Europa and in interstellar space.     

Fidelity of ocean bottom seismic observations

The often poor quality of ocean bottom seismic data, particularly that observed on horizontal seismometers, is shown to be the result of instruments responding to motions in ways not intended. Instruments designed to obtain the particle motion of the ocean bottom are found to also respond to motions of the water. The shear discontinuity across the ocean floor boundary results in torques that cause package rotation, rather than rectilinear motion, in response to horizontal ground or water motion. The problems are exacerbated by bottom currents and soft sediments. The theory and data presented in this paper suggest that the only reliable way of obtaining high fidelity particle motion data from the ocean floor is to bury the sensors below the bottom in a package with density close to that of the sediment. Long period signals couple well to ocean bottom seismometers, but torques generated by bottom currents can cause noise at both long and short periods. The predicted effects are illustrated using parameters appropriate for the operational OBS developed for the U. S. Office of Naval Research. Examples of data from ocean bottom and buried sensors are also presented.     

A method to reduce the spin-up time of ocean models

The spin-up timescale in large-scale ocean models, i.e., the time it takes to reach an equilibrium state, is determined by the slow processes in the deep ocean and is usually in the order of a few thousand years. As these equilibrium states are taken as initial states for many calculations, much computer time is spent in the spin-up phase of ocean model computations. In this note, we propose a new approach which can lead to a very large reduction in spin-up time for quite a broad class of existing ocean models. Our approach is based on so-called Jacobian–Free Newton–Krylov methods which combine Newton’s method for solving non-linear systems with Krylov subspace methods for solving large systems of linear equations. As there is no need to construct the Jacobian matrices explicitly the method can in principle be applied to existing explicit time-stepping codes. To illustrate the method we apply it to a 3D planetary geostrophic ocean model with prognostic equations only for temperature and salinity. We compare the new method to the ‘ordinary’ spin-up run for several model resolutions and find a considerable reduction of spin-up time.     

A multi-envelope vertical coordinate system for numerical ocean modelling

A multi-envelope generalised coordinate system for numerical ocean modelling is introduced. In this system, computational levels are curved and adjusted to multiple ‘virtual bottoms’ (aka envelopes) rather than following geopotential levels or the actual bathymetry. This allows defining computational levels which are optimised to best represent different physical processes in different sub-domains of the model. In particular, we show how it can be used to improve the representation of tracer advection in the ocean interior. The new vertical system is compared with a widely used z-partial step scheme. The modelling skill of the models is assessed by comparison with the analytical solutions or results produced by a model with a very high-resolution z-level grid. Three idealised process-oriented numerical experiments are carried out. Experiments show that numerical errors produced by the new scheme are much smaller than those produced by the standard z-partial step scheme at a comparable vertical resolution. In particular, the new scheme shows superiority in simulating the formation of a cold intermediate layer in the ocean interior and in representing dense water cascading down a steep topography.     

The fate of suspended sediment and particulate organic carbon in transit through the channels of a river catchment

Particulate organic matter (POM) transiting through rivers could be lost to overbank storage, stored in‐channel, added to by erosion or autochthonous production, or turned over to release greenhouse gases to the atmosphere (either while in the water column or while stored in the channel). In the UK, a net loss of POM across catchments has been recorded, and the aim here was to investigate the balances of processes acting on the POM. This study considered records of suspended sediment and POM flux in comparison to stream flow, velocity, stream power, and residence time for the River Trent (English Midlands, 8,231 km²). We show that for the lower two thirds (106 km) of the River Trent, 2% is lost to overbank storage; 10% is lost to the atmosphere in the water column; and 31% is turned over while in temporary storage. Permanent in‐channel storage is negligible, and for the lower course of the river, material stored in‐channel will have a residence time of the order of hundreds of days between the last flood hydrograph of one winter and the first winter storm of the next winter (usually in the same calendar year). When considered at the scale of the UK, 1% POM in transit would be lost to overbank sedimentation; 5% turned over in the water column, and 14% turned over while in temporary storage. In the upper third of the study river channel, there is insufficient stream power to transport sediment and so in‐channel storage or in‐channel turnover over to the atmosphere dominate. The in‐channel processes of the River Trent do not conform to that expected for river channels as the headwaters are not eroding or transporting sediment. Therefore, the source of sediment must be lower down the channel network.     

Changes in Projected Spatial and Seasonal Groundwater Recharge in the Upper Colorado River Basin

The Colorado River is an important source of water in the western United States, supplying the needs of more than 38 million people in the United States and Mexico. Groundwater discharge to streams has been shown to be a critical component of streamflow in the Upper Colorado River Basin (UCRB), particularly during low‐flow periods. Understanding impacts on groundwater in the basin from projected climate change will assist water managers in the region in planning for potential changes in the river and groundwater system. A previous study on changes in basin‐wide groundwater recharge in the UCRB under projected climate change found substantial increases in temperature, moderate increases in precipitation, and mostly periods of stable or slight increases in simulated groundwater recharge through 2099. This study quantifies projected spatial and seasonal changes in groundwater recharge within the UCRB from recent historical (1950 to 2015) through future (2016 to 2099) time periods, using a distributed‐parameter groundwater recharge model with downscaled climate data from 97 Coupled Model Intercomparison Project Phase 5 (CMIP5) climate projections. Simulation results indicate that projected increases in basin‐wide recharge of up to 15% are not distributed uniformly within the basin or throughout the year. Northernmost subregions within the UCRB are projected an increase in groundwater recharge, while recharge in other mainly southern subregions will decline. Seasonal changes in recharge also are projected within the UCRB, with decreases of 50% or more in summer months and increases of 50% or more in winter months for all subregions, and increases of 10% or more in spring months for many subregions.     

Investigating mid‐Ediacaran glaciation and final Gondwana amalgamation using coupled sedimentology and 40Ar/ 39Ar detrital muscovite provenance from the Paraguay Belt,Brazil

Understanding the evolution of the northern Paraguay Belt, Brazil, is critical in two current controversies: (i) the number, timing and significance of Ediacaran glaciations; and (ii) the timing of amalgamation of South American Gondwana. The Neoproterozoic Alto Paraguay Group forms much of the northern Paraguay Belt. The Serra Azul Formation, within this Group, contains unequivocal evidence for a glacial influence on sedimentation, including multi‐directional striations on sandstone clasts and striated, polished and bullet‐shaped mudstone clasts. However, the age of the Serra Azul Formation is not well‐constrained. The northern Paraguay Belt also formed after the traditionally accepted time for amalgamation of South American Gondwana. If the orogen represents closure of an ocean, then this traditional view is incorrect. A significant number of single grain ⁴⁰Ar/³⁹Ar detrital muscovite cooling ages (ca 120) from the Alto Paraguay Group are presented. The three youngest grains from the Serra Azul Formation yield a weighted mean age of 640 ± 15 Myr, providing a robust maximum depositional age for this formation. This age, when considered with other data, suggests that the Serra Azul Formation developed in a mid‐Ediacaran glaciation consistent with that expressed in the Gaskiers Formation of Newfoundland, Canada. Cryogenian ⁴⁰Ar/³⁹Ar detrital muscovite ages from the Alto Paraguay Group are hard to reconcile with the known geology of Amazonia and are interpreted as being sourced from the evolving orogen to the east – from an arc terrane, possibly the Goiás–Paranapanema Massif. Detrital muscovites in the upper part of the Alto Paraguay Group are as young as 544 ± 7 Myr, consistent with mounting evidence that indicates a Cambrian age for orogenesis within the Paraguay Belt during the final amalgamation of Gondwana. This article suggests that the data best support a model where ocean closure in the region continued until Ediacaran/Cambrian times, with final ocean closure represented by orogenesis in the Paraguay–Araguaia orogen.