Efficacy of Coagulants and Ballast Compounds in Removal of Cyanobacteria (<Emphasis Type="Italic">Microcystis</Emphasis>) from Water of the Tropical Lagoon Jacarepaguá (Rio de Janeiro,Brazil)

Eutrophication is considered the most important water quality problem in freshwaters and coastal waters worldwide promoting frequent occurrence of blooms of potentially toxic cyanobacteria. Removal of cyanobacteria from the water column using a combination of coagulant and ballast is a promising technique for mitigation and an alternative to the use of algaecides. In laboratory, we tested experimentally the efficiency of two coagulants, polyaluminium chloride (PAC) and chitosan (made of shrimp shells), alone and combined with two ballasts: red soil (RS) and the own lagoon sediment, to remove natural populations of cyanobacteria, from an urban brackish coastal lagoon. PAC was a very effective coagulant when applied at low doses (≤8 mg Al L^?1) and settled the cyanobacteria, while at high doses (≥16 mg Al L^?1) large flocks aggregated in the top of test tubes. In contrast, chitosan was not able to form flocks, even in high doses (>16 mg L^?1) and did not efficiently settle down cyanobacteria when combined with ballast. The RS itself removed 33–47 % of the cyanobacteria. This removal was strongly enhanced when combined with PAC in a dose-dependent matter; 8 mg Al L^?1 was considered the best dose to be applied. The lagoon sediment alone did not promote any settling of cyanobacteria but removal was high when combined with PAC. Combined coagulant and ballast seems a very efficient, cheap, fast and safe curative measure to lessen the harmful cyanobacteria bloom nuisance in periods when particularly needed, such as around the 2016 Olympics in Jacarepaguá Lagoon.     

Assessing Risks of Shallow Riparian Groundwater Quality Near an Oil Sands Tailings Pond

The potential discharge of groundwater contaminated by oil sands process‐affected water (OSPW) is a concern for aquatic ecosystems near tailings ponds. Groundwater in the area, but unaffected by OSPW, may contain similar compounds, complicating the assessment of potential ecological impacts. In this study, 177 shallow groundwater samples were collected from riparian areas along the Athabasca River and tributaries proximate to oil sands developments. For “pond‐site” samples (71; adjacent to study tailings pond), Canadian aquatic life guidelines were exceeded for 11 of 20 assessed compounds. However, “non‐pond” samples (54; not near any tailings pond) provided similar exceedances. Statistical analyses indicate that pond‐site and non‐pond samples were indistinguishable for all but seven parameters assessed, including salts, many trace metals, and fluorescence profiles of aromatic naphthenic acids (ANA). This suggests that, regarding the tested parameters, groundwater adjacent to the study tailings pond generally poses no greater ecological risk than other nearby groundwaters at this time. Multivariate analyses applied to the groundwater data set separated into 11 smaller zones support this conclusion, but show some variation between zones. Geological and potential OSPW influences could not be distinguished based on major ions and metals concentrations. However, similarities in indicator parameters, namely ANA, F, Mo, Se, and Na‐Cl ratio, were noted between a small subset of samples from two pond‐site zones and two OSPW samples and two shallow groundwater samples documented as likely OSPW affected. This indicator‐based screening suggests that OSPW‐affected groundwater may be reaching Athabasca River sediments at a few locations.     

A Hierarchical Bayesian Model Averaging Framework for Groundwater Prediction under Uncertainty

Groundwater prediction models are subjected to various sources of uncertainty. This study introduces a hierarchical Bayesian model averaging (HBMA) method to segregate and prioritize sources of uncertainty in a hierarchical structure and conduct BMA for concentration prediction. A BMA tree of models is developed to understand the impact of individual sources of uncertainty and uncertainty propagation to model predictions. HBMA evaluates the relative importance of different modeling propositions at each level in the BMA tree of model weights. The HBMA method is applied to chloride concentration prediction for the “1,500‐foot” sand of the Baton Rouge area, Louisiana from 2005 to 2029. The groundwater head data from 1990 to 2004 is used for model calibration. Four sources of uncertainty are considered and resulted in 180 flow and transport models for concentration prediction. The results show that prediction variances of concentration from uncertain model elements are much higher than the prediction variance from uncertain model parameters. The HBMA method is able to quantify the contributions of individual sources of uncertainty to the total uncertainty.     

Can GPS-Derived Surface Loading Bridge a GRACE Mission Gap?

We investigated two ‘gap-filler’ methods based on GPS-derived low-degree surface loading variations (GPS-I and GPS-C) and a more simple method (REF-S) which extends a seasonal harmonic variation into the expected Gravity Recovery and Climate Experiment (GRACE) mission gap. We simulated two mission gaps in a reference solution (REF), which is derived from a joint inversion of GRACE (RL05) data, GPS-derived surface loading and simulated ocean bottom pressure. The GPS-I and GPS-C methods both have a new type of constraint applied to mitigate the lack of GPS station network coverage over the ocean. To obtain the GPS-C solution, the GPS-I method is adjusted such that it fits the reference solution better in a 1.5 year overlapping period outside of the gap. As can be expected, the GPS-I and GPS-C solutions contain larger errors compared to the reference solution, which is heavily constrained by GRACE. Within the simulated gaps, the GPS-C solution generally fits the reference solution better compared to the GPS-I method, both in terms of spherical harmonic loading coefficients and in terms of selected basin-averaged hydrological mass variations. Depending on the basin, the RMS-error of the water storage variations (scaled for leakage effects) ranges between 1.6 cm (Yukon) and 15.3 cm (Orinoco). In terms of noise level, the seasonal gap-filler method (REF-S) even outperforms the GPS-I and GPS-C methods, which are still affected by spatial aliasing problems. However, it must be noted that the REF-S method cannot be used beyond the study of simple harmonic seasonal variations.     

The use of mycorrhiza for eco‐engineering measures in steep alpine environments: effects on soil aggregate formation and fine‐root development

Steep erosion‐prone and vegetation‐free slopes are widespread in alpine areas and are often discussed since they have a high socio‐economic damage potential. We present an eco‐engineering approach to test whether a mycorrhizal inoculum improves the establishment of hedge brush layers and in turn soil structural stability on a steep, coarse‐grained vegetation‐free slope in the eastern Swiss Alps. We established (i) mycorrhizal and (ii) non‐mycorrhizal treated eco‐engineered research plots on a field experimental scale, covering a total area of approximately 1000 m² on an east‐northeast (ENE) exposed slope, where many environmental parameters can be regarded as homogeneous. After a full vegetation period, we quantified soil aggregate stability, the formation of water stable aggregates and the fine‐root development. Our results illustrate that the establishment of brush layers without mycorrhizal inoculum increased aggregate stability significantly. Against our expectation and glasshouse experiments, the addition of mycorrhizal inoculum did not have a statistically significant effect after one vegetation period although it tended to increase aggregate stability. Analogously, root length density (RLD) tended to be higher at the non‐mycorrhizal treated site. Aggregate stability was significantly correlated with RLD. Studies on a bigger field experimental scale are inevitable, complement glasshouse studies and lead to a better understanding for a successful application of sustainable eco‐engineering measures in alpine environments. Based on our results and considering the fact that the response time in natural ecosystems may be slower than in laboratory approaches, we conclude that long‐term field studies are necessary to validate results gained through laboratory experiments. Copyright © 2014 John Wiley & Sons, Ltd.     

Regional grain size variations in aeolian sediments along the transition between Tibetan highlands and north‐western Chinese deserts – the influence of geomorphological settings on aeolian transport pathways

Sediment distribution is investigated applying grain size analysis to 279 surface samples from the transitional zone between high mountains (Qilian Shan) and their arid forelands (Hexi Corridor) in north‐western China. Six main sediment types were classified. Medium scale (10³ m) geomorphological setting is carefully considered as it may play an important role concerning sediment supply and availability. A tripartite distribution of sedimentological landscape units along the mountain to foreland transition is evident. Aeolian sediments (e.g. loess and dune sands) are widespread. They are used to identify aeolian transport pathways. The mU/fS‐ratio (5–11 µm/48–70 µm) among primary loess opposes the two grain size fractions being most sensitive to varying accumulation conditions. The first fraction is attributed to long‐distance transport in high suspension clouds whereas the latter represents local transport in saltation mode. The ratio shows strong correlation with elevation (R² = 0.77). Thus, it indicates a relatively higher far‐traveled dust supply in mountainous areas (>3000 m above sea level [a.s.l.]) compared to the foreland. The contribution of westerlies to high mountain loess deposits is considered likely. Hereby, the influence of the geomorphological setting on grain size composition of aeolian sediments becomes apparent: the contribution from distant dust sources is ubiquitous in the study area. However, the far‐distance contribution may be reduced by the availability of fine sand provided in low topography settings. Plain foreland areas support fine sand deflation from supplying river beds, allowing the formation of sandy loess in foreland areas and intramontane basins. In contrast, high mountain topography inhibits strong sand deflation into loess deposits. Eastern parts of the Hexi Corridor show higher aeolian sand occurrence. In contrast, the western parts are dominated by gravel gobi surfaces. This is attributed to higher sand supply in eastern parts provided by the Badain Jaran Desert and fluvial storages as sand sources. Copyright © 2014 John Wiley & Sons, Ltd.     

Late Quaternary history of the Vakinankaratra volcanic field (central Madagascar): insights from luminescence dating of phreatomagmatic eruption deposits

The Quaternary Vakinankaratra volcanic field in the central Madagascar highlands consists of scoria cones, lava flows, tuff rings, and maars. These volcanic landforms are the result of processes triggered by intracontinental rifting and overlie Precambrian basement or Neogene volcanic rocks. Infrared-stimulated luminescence (IRSL) dating was applied to 13 samples taken from phreatomagmatic eruption deposits in the Antsirabe–Betafo region with the aim of constraining the chronology of the volcanic activity. Establishing such a chronology is important for evaluating volcanic hazards in this densely populated area. Stratigraphic correlations of eruption deposits and IRSL ages suggest at least five phreatomagmatic eruption events in Late Pleistocene times. In the Lake Andraikiba region, two such eruption layers can be clearly distinguished. The older one yields ages between 109?±?15 and 90?±?11 ka and is possibly related to an eruption at the Amboniloha volcanic complex to the north. The younger one gives ages between 58?±?4 and 47?±?7 ka and is clearly related to the phreatomagmatic eruption that formed Lake Andraikiba. IRSL ages of a similar eruption deposit directly overlying basement laterite in the vicinity of the Fizinana and Ampasamihaiky volcanic complexes yield coherent ages of 68?±?7 and 65?±?8 ka. These ages provide the upper age limit for the subsequently developed Iavoko, Antsifotra, and Fizinana scoria cones and their associated lava flows. Two phreatomagmatic deposits, identified near Lake Tritrivakely, yield the youngest IRSL ages in the region, with respective ages of 32?±?3 and 19?±?2 ka. The reported K-feldspar IRSL ages are the first recorded numerical ages of phreatomagmatic eruption deposits in Madagascar, and our results confirm the huge potential of this dating approach for reconstructing the volcanic activity of Late Pleistocene to Holocene volcanic provinces.     

Implications of subsurface thermal–hydraulic–mechanical processes associated with glaciation on Shield flow system evolution and performance assessment

A deep geologic repository (DGR) situated on the Canadian Shield will be subject to long-term climate change that will markedly alter surface conditions as a result of glaciation and permafrost penetration. Systematic, two-dimensional and three-dimensional coupled thermal–hydraulic–mechanical finite-element simulations with varying degrees of coupling, including depth-dependent salinity (represented as a change in groundwater density) and temperature-dependent density and viscosity, were undertaken to address the implications of glaciation on groundwater flow system dynamics as it could affect DGR performance. The modelling domain consisted of a 1.6-km deep sub-regional scale (≈100 km²) fractured Shield flow system. Initial and transient thermal, hydraulic and mechanical boundary conditions were developed from two realizations of the University of Toronto Glacial Systems Model of the last Laurentide glaciation. Results indicate that during the glacial loading/unloading cycle, for this particular conceptual model, there is limited penetration of glacial meltwaters to depth and small residual anomalous hydraulic head. During glacial coverage, the mechanical factor of safety increases in the moderately fractured and sparsely fractured rock mass, but principal effective stress reorientation also occurs. Given the assumed nonglacial in situ state of stress and mechanical properties, the fracture zones were predicted to be less stable under glacial conditions.

New analysis of Lunar Prospector radio tracking data brings the nearside gravity field of the Moon with an unprecedented resolution

A new analysis of the Doppler tracking data from the Lunar Prospector mission in 1999 revealed a number of previously-unseen gravity anomalies at spatial scales as small as 27 km over the nearside. The tracking data at low altitudes (50 km or below) were better analyzed to resolve the nearside features without dampening from a power law constraint, by partitioning the gravity parameters concentrated on either the nearside or farside. The resulting model presents gravity anomalies correlated with topography with a correlation coefficient of 0.7 or higher from degree 50 to 150, the widest bandwidth yet. The gravity-topography admittance of ∼70 mGal/km is found from numerous craters of which diameters are 60 km or less. In addition, the new model produces orbits that fit to independent radio tracking data from the Lunar Reconnaissance Orbiter and Kaguya (SELENE) better than previous gravity models. This high-resolution model can be of immediate use to geophysical analysis of small craters. Our technique could be applied to an upcoming mission, the Gravity Recovery And Interior Laboratory and useful to extract short wavelength signals from the MESSENGER Doppler data.     

Deep-sea Fe-Mn Crusts from the Northeast Atlantic Ocean: Composition and Resource Considerations

Eighteen deep-sea ferromanganese crusts (Fe-Mn crusts) from 10 seamounts in the northeast Atlantic were studied. Samples were recovered from water depths of ～1,200 to ～4,600 m from seamounts near Madeira, the Canary and Azores islands, and one sample from the western Mediterranean Sea.

The mineralogical and chemical compositions of the samples indicate that the crusts are typical continental margin, hydrogenetic Fe-Mn crusts. The Fe-Mn crusts exhibit a Co + Cu + Ni maximum of 0.96 wt%. Platinum-group element contents analyzed for five samples showed Pt contents from 153 to 512 ppb.

The resource potential of Fe-Mn crusts within and adjacent to the Portuguese Exclusive Economic Zone (EEZ) is evaluated to be comparable to that of crusts in the central Pacific, indicating that these Atlantic deposits may be an important future resource.