Efficacy of Coagulants and Ballast Compounds in Removal of Cyanobacteria (<Emphasis Type="Italic">Microcystis</Emphasis>) from Water of the Tropical Lagoon Jacarepaguá (Rio de Janeiro,Brazil)

Eutrophication is considered the most important water quality problem in freshwaters and coastal waters worldwide promoting frequent occurrence of blooms of potentially toxic cyanobacteria. Removal of cyanobacteria from the water column using a combination of coagulant and ballast is a promising technique for mitigation and an alternative to the use of algaecides. In laboratory, we tested experimentally the efficiency of two coagulants, polyaluminium chloride (PAC) and chitosan (made of shrimp shells), alone and combined with two ballasts: red soil (RS) and the own lagoon sediment, to remove natural populations of cyanobacteria, from an urban brackish coastal lagoon. PAC was a very effective coagulant when applied at low doses (≤8 mg Al L^?1) and settled the cyanobacteria, while at high doses (≥16 mg Al L^?1) large flocks aggregated in the top of test tubes. In contrast, chitosan was not able to form flocks, even in high doses (>16 mg L^?1) and did not efficiently settle down cyanobacteria when combined with ballast. The RS itself removed 33–47 % of the cyanobacteria. This removal was strongly enhanced when combined with PAC in a dose-dependent matter; 8 mg Al L^?1 was considered the best dose to be applied. The lagoon sediment alone did not promote any settling of cyanobacteria but removal was high when combined with PAC. Combined coagulant and ballast seems a very efficient, cheap, fast and safe curative measure to lessen the harmful cyanobacteria bloom nuisance in periods when particularly needed, such as around the 2016 Olympics in Jacarepaguá Lagoon.     

Contribution of geophysical methods to karst-system exploration: an overview

The karst environment is one of the most challenging in terms of groundwater, engineering and environmental issues. Geophysical methods can provide useful subsurface information in karst regions concerning, for instance, hazard estimation or groundwater exploration and vulnerability assessment. However, a karst area remains a very difficult environment for any geophysical exploration; selection of the best-suited geophysical method is not always straightforward, due to the highly variable and unpredictable target characteristics. The state of the art is presented, in terms of the contributions made by geophysical methods to karst-system exploration, based on extensive analysis of the published scientific results. This report is an overview and should be used as a preliminary methodological approach, rather than a guideline.     

Natural geobatteries associated with sulphide ore deposits, II. Field studies at the viburnum trend, southeast Missouri, U.S.A.

Any conductive sulphide ore body can generate electrical ore potentials and this can be regarded as a geobattery, with an upper positive cathode and a lower negative anode. Two mechanisms which can occur simultaneously and which appear to explain these potentials are the oxygen concentration cell (OCC) and the sulphide galvanic cell (SGC). When there is a difference of O₂ concentration between the cathode and anode, the OCC operates by contributing oxygen to the anode, and ceases when the difference is diminished. However, gradients of pH, temperature or pressure can keep the cell operating. In the SGC the sulphides dissolve at the anode (producing metal ions, sulphur and electrons), while at the cathode, either sulphides dissolve producing metal and sulphur ions, or reaction is as in the OCC. The ore potential measured in the field is the sum of the oxygen concentration cell and at times locally dominant sulphide galvanic cells.     

Transposed Climates for Study of Water Supply Variability on the Laurentian Great Lakes

Hydrological models of the Great Lakes basin were used to study the sensitivity of Great Lakes water supplies to climate warming by driving them with meteorological data from four U.S. climate zones that were transposed to the basin. Widely different existing climates were selected for transposition in order to identify thresholds of change where major impacts on water supplies begin to occur and whether there are non-linear responses in the system. The climate zones each consist of 43 years of daily temperature and precipitation data for 1,000 or more stations and daily evaporation-related variables (temperature, wind speed, humidity, cloud cover) for approximately 20–35 stations. A key characteristic of these selected climates was much larger variability in inter-annual precipitation than currently experienced over the Great Lakes. Climate data were adjusted to simulate lake effects; however, a comparison of hydrologic results with and without lake effects showed that there was only minor effects on water supplies.     

An investigation of the controls on Irish precipitation δ18O values on monthly and event timescales

This two-year study investigates the relative influence of meteorological variables (precipitation amount and temperature), atmospheric circulation, air mass history, and moisture source region on Irish precipitation oxygen isotopes (δ¹⁸O_p) on event and monthly timescales. Single predictor correlations reveal that on the event scale, 20% of δ¹⁸O_p variability is attributable to the amount effect and 7% to the temperature effect while on the monthly timescale the North Atlantic Oscillation accounts for up to 20% of δ¹⁸O_p variability and the amount and temperature effects are not significant. In comparison, multivariate linear regression reveals that the interaction of temperature and precipitation amount explains up to 40% of δ¹⁸O_p variance at event and monthly timescales. Five-day kinematic back trajectories suggest that the amount-weighted mean δ¹⁸O_p value of southerly- and northerly-derived events are lower by 2‰ relative to events derived from the west. Because air mass history and atmospheric circulation appear to influence δ¹⁸O_p in Ireland, Irish paleo-δ¹⁸O_p proxy records are best interpreted as reflecting a combination of parameters, not just paleotemperature or paleorainfall.     

Precipitation variability during the past 400?years in the Xiaolong Mountain (central China) inferred from tree rings

We developed the first tree-ring chronology, based on 73 cores from 29 Pinus tabulaeformis trees, for the Xiaolong Mountain area of central China, a region at the boundary of the Asian summer monsoon. This chronology exhibits significant (at 0.01 level) positive correlations with precipitation in May and June, and negative correlations with temperature in May, June and July. Highest linear correlation is observed between tree growth and the seasonalized (April–July) precipitation, suggesting that tree rings tend to integrate the monthly precipitation signals. Accordingly, the April–July total precipitation was reconstructed back to 1629 using these tree rings, explaining 44.7?% of the instrumental variance. A severe drought occurred in the area during the 1630s–1640s, which may be related to the weakened Asian summer monsoon caused by a low land-sea thermal gradient. The dry epoch during the 1920s–1930s and since the late 1970s may be explained by the strengthened Hadley circulation in a warmer climate. The dry (wet) epochs of the 1920s–1930s (the 1750s and 1950s) occurred during the warm (cold) phases of the El Ni?o-Southern Oscillation and the Pacific Decadal Oscillation that are often associated with weakened (strengthened) East Asian summer monsoon. These relationships indicate significant teleconnections operating over the past centuries in central China related to large-scale synoptic features.     

Modeling the temperature of the polar mesopause region: Part II—Intra-seasonal monthly oscillations

Measurements show that the polar mesospheric clouds (PMC) can vary, in the zonal mean, with periods around 1 month [Bailey et al., 2005. Observations of polar mesospheric clouds by the Student Nitric Oxide Explorer. J. Geophys. Res. 110, D13203, doi:10.1029/2004JD005422]. This observation has been the impetus for the present paper, where we describe corresponding temperature oscillations generated by the Numerical Spectral Model (NSM). Our numerical results are taken from the 3D and 2D versions of the NSM, which produce inter-annual and long-term variations in the polar mesopause region, as discussed in the accompanying paper (Part I). In the NSM, the intra-seasonal temperature variations with periods around 2 months are generated by the meridional winds that in turn are accelerated by the momentum deposition from small-scale gravity waves (GW) propagating north/south. The wave-driven dynamical process underlying the oscillations is intrinsically non-linear like that generating the quasi-biennial oscillation (QBO). Our analysis demonstrates that the seasonal annual and semi-annual variations excite the oscillation frequencies through non-linear cascading.