陆相盆地中的海侵层序特征:中欧盆地三叠系与松辽盆地白垩系对比研究

中欧盆地三叠系是典型的海陆过渡相沉积，松辽盆地白垩系是含有海侵事件记录的陆相河湖盆地。两盆地的共同特点是：①大陆克拉通上长期发育的大型坳陷盆地；②靠近古大洋和（或）有向海通道；③主要由互层状泥岩、粉砂岩、碳酸盐岩和膏盐层组成；④无典型海相化石，可能发育有半咸水和（或）高盐度生物；⑤海侵层中自生矿物的δ^34S,δ^13C,δ^18O同位素比值及介质盐度指数（Sr/Ba）、碱度指数（Ca Mg)／（Si Al）、还原性指标（Zn Ni)/Ga、硫沉积通量指数（归一化硫含量）等显著高于相邻层位背景值。     

Chemical modelling of the groundwater composition in aquifers affected by lignite mine dumps discharge (surface mine Inden,Germany)

The oxidation of pyrite results in sulphate concentrations from 1,300 to 2,000 mg/l in the dump water of the open cast mine Inden, which is located in Germany. Under near-neutral pH and reduced redox conditions, precipitation of siderite (FeCO₃) retains up to 85% of the pre-liberated ferrous iron, so that iron concentrations in the dump water are relatively low as compared to the concentrations of sulphate. The highly mineralised dump water will enter the aquifer system northwards of Inden during the next centuries. This area is used intensely for water extraction. Model calculations show that there will be no problem of acidification in the adjacent aquifer system and, therefore, no problem of high heavy metal concentrations during the next centuries. The most important problem will be high sulphate concentrations in the groundwater. Besides dispersion and diffusion, there are no chemical mechanisms that lower the sulphate concentrations downstream. On the basis of the simulations, sulphate plumes of about 1–2 km in width and up to 15 km in length are expected. Within the core of these plumes, sulphate concentrations will be above the drinking water limits.     

A structural phase-transition in K(Mg1−xCux)F3 perovskite

A complete solid-solution series between cubic (Pm 3 m) KMgF₃ and tetragonal (I4/mcm) KCuF₃ was synthesized at 730–735 °C in an inert atmosphere. X-ray powder-diffraction at room temperature shows that the transition between the cubic and tetragonal perovskite structures in the series K (Mg_1?xCu_x) F₃ occurs at x ～ 0.6. Rietveld structure-refinements were done for selected compositions. In the cubic phase, all parameters are linear with composition up to the transition point. At the transition point, there is a strong discontinuity in the cell volume; this is strongly anisotropic with expansion along the a axes and contraction along the c axis due to a pronounced axial elongation of the (Mg, Cu) F₆ octahedron that increases with increasing Cu content. The phase transition is first-order, with a discontinuity of ≈2% in the symmetry-breaking strain at x_C. It is proposed that the phase transition in K (Mg, Cu) F₃ is due to the onset of the cooperative Jahn-Teller effect. Compositional relationships for lattice vibrations in this solid solution were established using thin-film infrared spectroscopy. A phase transition occurring above 60 mole % KCuF₃ is indicated by the appearance of one of the two modes expected for the tetragonal phase; the weaker mode is not resolved below 80 mole % KCuF₃. Modes common to both structures vary smoothly and continuously across the binary; however, frequencies do not depend linearly on composition, nor is mode-softening discernable. Two-mode behaviour is observed only for the bending motion of the cubic phase, because this peak alone has non-overlapping end-member components.     

Adapting rail and road networks to weather extremes: case studies for southern Germany and Austria

The assessment of the current impacts of extreme weather conditions on transport systems reveals high costs in specific locations. Prominent examples for Europe are the economic consequences of the harsh winter periods 2009/2010 and 2010/2011 and the floods in Austria, Eastern Europe, Germany and the United Kingdom in 2005 and 2007. Departing from the EC-funded project WEATHER, this paper delves into the subject of adaptation strategies by revisiting the project’s general findings on adaptation strategies and by adding two specific cases: (1) advanced winter maintenance on roads in southwest Germany and (2) technical and organizational measures in Alpine rail transport. For these two cases, feasible adaptation strategies are elaborated and their potential is discussed in light of damage cost forecasts up to 2050. For the road sector, we find a high potential to mitigate weather-related costs, although damages here are expected to decline. In contrast, rail systems face strongly increasing damages and the mitigation options offered by improved information and communication systems seem to be largely exploited. Consequently, it is easier to justify expensive adaptation measures for high-cost rail infrastructures than for road transport. A generic analysis of 14 damage cases worldwide, however, revealed that generally awareness raising, cooperation and communication strategies are sufficient to mitigate the most severe damages by natural disasters.     

Late Holocene climatic changes in Tierra del Fuego based on multiproxy analyses of peat deposits

A ca. 1400-yr record from a raised bog in Isla Grande, Tierra del Fuego, Argentina, registers climate fluctuations, including a Medieval Warm Period, although evidence for the ‘Little Ice Age’ is less clear. Changes in temperature and/or precipitation were inferred from plant macrofossils, pollen, fungal spores, testate amebae, and peat humification. The chronology was established using a ¹⁴C wiggle-matching technique that provides improved age control for at least part of the record compared to other sites. These new data are presented and compared with other lines of evidence from the Southern and Northern Hemispheres. A period of low local water tables occurred in the bog between A.D. 960-1020, which may correspond to the Medieval Warm Period date range of A.D. 950-1045 generated from Northern Hemisphere tree-ring data. A period of cooler and/or wetter conditions was detected between ca. A.D. 1030 and 1100 and a later period of cooler/wetter conditions estimated at ca. cal A.D. 1800-1930, which may correspond to a cooling episode inferred from Law Dome, Antarctica.     

A crucial role for slab break-off in the generation of major mineral deposits: insights from central and eastern Australia

In the Lachlan Fold Belt of southeastern Australia, major orogenic gold and porphyry gold–copper deposits formed simultaneously within distinct tectonic settings during a very short time interval at ca. 440 Ma. The driving mechanism that controlled the temporal coincidence of these deposits remains largely unexplained. A review of contemporaneous metallogenic, tectonic, magmatic and sedimentological events in central and eastern Australia reveals that a change in subduction dynamics along the Australian sector of the Early Palaeozoic circum–Gondwana mega-subduction system could have influenced lithospheric stress conditions far inboard of the subduction margin. The magnitude of ore formation and the spatial extent of related events are proposed in this paper to have been controlled by the interplay of mantle processes and lithospheric changes that followed slab break-off along a portion of the mega-subduction system surrounding Gondwana at that time. Slab break-off after subduction lock-up caused mantle upwelling that, in turn, provided an instantaneous heat supply for magmatic and hydrothermal events. Coincident reorganisation of lithospheric stress conditions far inboard of the proto-Pacific margin of Australia controlled reactivation of deep-lithospheric fault structures. These fault systems provided a pathway for fluids and heat fuelled by mantle upwelling into the upper lithosphere and caused the deposition of ~440 Ma gold deposits in the Lachlan Fold Belt, as well as a range of metallogenic, tectonic and sedimentary changes elsewhere in central and eastern Australia.     

Progressive oxidation of pyrite in five bituminous coal samples: An As XANES and Fe Mössbauer spectroscopic study

Naturally occurring pyrite commonly contains minor substituted metals and metalloids (As, Se, Hg, Cu, Ni, etc.) that can be released to the environment as a result of its weathering. Arsenic, often the most abundant minor constituent in pyrite, is a sensitive monitor of progressive pyrite oxidation in coal. To test the effect of pyrite composition and environmental parameters on the rate and extent of pyrite oxidation in coal, splits of five bituminous coal samples having differing amounts of pyrite and extents of As substitution in the pyrite, were exposed to a range of simulated weathering conditions over a period of 17 months. Samples investigated include a Springfield coal from Indiana (whole coal pyritic S = 2.13 wt.%; As in pyrite = detection limit (d.l.) to 0.06 wt.%), two Pittsburgh coal samples from West Virginia (pyritic S = 1.32–1.58 wt.%; As in pyrite = d.l. to 0.34 wt.%), and two samples from the Warrior Basin, Alabama (pyritic S = 0.26–0.27 wt.%; As in pyrite = d.l. to 2.72 wt.%). Samples were collected from active mine faces, and expected differences in the concentration of As in pyrite were confirmed by electron microprobe analysis. Experimental weathering conditions in test chambers were maintained as follows: (1) dry Ar atmosphere; (2) dry O₂ atmosphere; (3) room atmosphere (relative humidity ∼20–60%); and (4) room atmosphere with samples wetted periodically with double-distilled water. Sample splits were removed after one month, nine months, and 17 months to monitor the extent of As and Fe oxidation using As X-ray absorption near-edge structure (XANES) spectroscopy and ⁵⁷Fe Mössbauer spectroscopy, respectively. Arsenic XANES spectroscopy shows progressive oxidation of pyritic As to arsenate, with wetted samples showing the most rapid oxidation. ⁵⁷Fe Mössbauer spectroscopy also shows a much greater proportion of Fe³⁺ forms (jarosite, Fe³⁺ sulfate, FeOOH) for samples stored under wet conditions, but much less difference among samples stored under dry conditions in different atmospheres. The air-wet experiments show evidence of pyrite re-precipitation from soluble ferric sulfates, with As retention in the jarosite phase. Extents of As and Fe oxidation were similar for samples having differing As substitution in pyrite, suggesting that environmental conditions outweigh the composition and amount of pyrite as factors influencing the oxidation rate of Fe sulfides in coal.     

Qingbaikouan and Crygenian in South China: Constraints by SHRIMP Zircon U-Pb dating

The Qingbaikouan System is the lowest unit of the Neoproterozoic Erathem in Chinese stratigraphic succession,and it now provides a precise geochronological framework and geological time scale for mapping and stratal correlation in China.However,a sensitive high-resolution ion microprobe （SHRIMP） U-Pb zircon age date （1368±12 Ma） obtained from a bentonite in the Qingbaikouan Xiamaling Formation indicates that it belongs to the Mesoproterozoic Erathem instead.This change is a milestone in understanding the Precambrian Stratigraphic Time Scale in China,and it has had great influence on Precambrian correlations in Asia.Otherwise,a large amount of geochronological work has been done in the ＂Jiangnan Orogen Belt＂ of South China,and new isotopic data have redefined the traditional recognition of metamorphosed Mesoproterozoic strata from the Sibao orogeny to the Neoproterozoic Erathem.Based on SHRIMP zircon U-Pb age data,the authors regard the Sibao orogeny （equal to the Wuling orogeny） as a movement at ca 820 Ma,meaning that the Sibao orogeny was not equivalent to the Grenvillian orogeny.Finally,we report here the first SHRIMP U-Pb age of the boundary between the top of the Qingbaikouan Gongdong Formation （786.8±5.6 Ma） and the bottom of the Chang＇an （diamictite） Formation （778.4±5.2 Ma）,which is the age of the lowest diamictite of the Nanhuan System in China.