Changes in tidal asymmetry in the German Wadden Sea

Ocean Dynamics - The recent morphological development of the German Wadden Sea (North Sea, Europe) has been characterized by expanding intertidal flats and deepening, narrowing tidal channels at...     

Stress Changes Modelled for the Sequence of Strong Earthquakes in the South Iceland Seismic Zone Since 1706

The South Iceland seismic zone is, roughly speaking, situated between two sections of the mid-Atlantic ridge, i.e., the Reykjanes Ridge southwest of Iceland and the Eastern Volcanic Zone on the island. It is a transform zone, where earthquakes are expected to occur on E-W-trending left-lateral shear faults, equivalent to conjugate, N-S-oriented right-lateral, rupture planes. In fact, earthquakes take place on en-échelon N-S-oriented faults, which is indicated by the distribution of main shock intensities, aftershocks as well as by surface fault traces. The stress field continuously generated in the fault zone by opening of the adjacent ridges is computed and superimposed on the stress field changes induced by a series of 13 earthquakes (M 6) between 1706 and 2000. The level of the pre-seismic stress field is analysed as well as the size of the area under high stress. Finally, the post-seismic stress field of June 2000 is analysed, to see where high stresses might have accumulated. The modelling indicates that the rupture planes located on separated parallel N-S-striking zones are dense enough to lead to an area-wide stress release by the series of events. The obtained pre-seismic stress level for most events is high and stable with the exception of situations when several strong shocks occur over a time span of several days, i.e., display typical main shock-aftershock patterns. The size of areas under high stress aside from of the rupture plane, i.e., where no event occurs at the specific time, is of medium to small size.     

Demarcation and Scaling of Long-term Seismogenesis

A space-time envelope of minor seismicity related to major shallow earthquakes is identified from observations of the long-term Precursory Scale Increase () phenomenon, which quantifies the three-stage faulting model of seismogenesis. The envelope, which includes the source area of the major earthquake, is here demarcated for 47 earthquakes from four regions, with tectonic regimes ranging from subduction to continental collision and continental transform. The earthquakes range in magnitude from 5.8 to 8.2, and include the 24 most recent mainshocks of magnitude 6.4 and larger in the San Andreas system of California, the Hellenic Arc region of Greece, and the New Zealand region, together with the six most recent mainshocks of magnitude 7.4 and larger in the Pacific Arc region of Japan. Also included are the destructive earthquakes that occurred at Kobe, Japan (1995, magnitude 7.2), Izmit, Turkey (1999, magnitude 7.4), and W.Tottori, Japan (2000, magnitude 7.3). The space (A _P ) in the space-time envelope is optimised with respect to the scale increase, while the time (T _P ) is the interval between the onset of the scale increase and the occurrence of the earthquake. A strong correlation is found between the envelope A _P T _P and the magnitude of the earthquake; hence the conclusion that the set of precursory earthquakes contained in the envelope is intrinsic to the seismogenic process. Yet A _P and T _P are correlated only weakly with each other, suggesting that A _P is affected by differences in statical conditions, such as geological structure and lithology, and T _P by differences in dynamical conditions, such as plate velocity. Among other scaling relations, predictive regressions are found between, on the one hand, the magnitude level of the precursory seismicity, and on the other hand, both T _P and the major earthquake magnitude. Hence the method, as here applied to retrospective analysis, is potentially adaptable to long-range forecasting of the place, time and magnitude of major earthquakes.     

MTBE in Drinking Water Production – Occurrence and Efficiency of Treatment Technologies

In Germany, the gasoline additive methyl tert‐butyl ether (MTBE) is almost constantly detected in measurable concentrations in surface waters and is not significantly removed during riverbank filtration. The removal of MTBE from water has been the focus of many studies that mostly were performed at high concentration levels and centred in understanding the mechanisms of elimination. In order to assess the performance of conventional and advanced water treatment technologies for MTBE removal in the low concentration range further studies were undertaken. Laboratory experiments included aeration, granulated activated carbon (GAC) adsorption, ozonation and advanced oxidation processes (AOP). The results show that the removal of MTBE by conventional technologies is not easily achieved. MTBE is only removed by aeration at high expense. Ozonation at neutral pH values did not prove to be effective in eliminating MTBE at all. The use of ozone/H₂O₂ (AOP) may lead to a partly elimination of MTBE. However, the ozone/H₂O₂ concentrations required for a complete removal of MTBE from natural waters is much higher than the ozone levels applied nowadays in waterworks. MTBE is only poorly adsorbed on activated carbon, thus GAC filtration is not efficient in eliminating MTBE. A comparison with real‐life data from German waterworks reveals that if MTBE is detected in the raw water it is most often found in the corresponding drinking water as well due to the poor removal efficiency of conventional treatment steps.     

Relations between metamorphism and orogeny in a typical section of the Indian Himalayas

Summary A comprehensive geological and petrological investigation has been undertaken in an area of about 10 000 km² in the Indian Himalaya (S-Lahul, Himachal Pradesh). The development of mineral assemblages in metamorphic rocks of medium grade is considered to be a dominant Alpine event, although almost exclusively Paleozoic and Precambrian rocks have been involved. The Barrowian type of this metamorphism, ranging from the anchi- to the sillimanite zone, took place under the elavated T-gradient of about 4°C/100 m. It is suggested that normal geothermal conditions prevailed only in the outermost zone of this orogenic belt. In the Late Tertiary this metamorphic series has been moved as a huge nappe upon the Lower Himalaya. During this process a unique feature of reverse metamorphism has been formed. It can be shown that this feature was caused by a combination of metamorphism and very rapid tectonic movements.

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Beziehungen zwischen Metamorphose und Orogenese in einem typischen Querschnitt des Indischen Himalaya

Zusammenfassung Ein etwa 10 000 km² großes Gebiet des Indischen Himalaya (S-Lahul, Himachal Pradesh) wurde einer umfassenden geologischen und petrographischen Bearbeitung unterzogen. Die Ausbildung der in den mittelgradig metamorphen Gesteinen vorliegenden Mineralparagenesen wird als ein dominant alpines Ereignis betrachtet, obwohl fast nur paläozoische und präkambrische Gesteine einbezogen wurden. Die Metamorphose selbst ist von Barrow-Typus und reicht von der Anchi- bis zur Sillimanitzone. Sie fand unter einem erhöhten Temperaturgradienten von etwa 4°C/100 m statt. Nur in der äußersten Zone des Orogens entsprach der Gradient etwa normalen geothermischen Verhältnissen. Im Spättertiär wurde diese alpin-metamorphe Serie in Form einer mächtigen Kristallindecke dem Niedrigen Himalaya aufgeschoben. Dabei wurde eine einzigartige Zone inverser Metamorphose ausgebildet. Es konnte gezeigt werden, daß diese inverse Metamorphose durch das Zusammenwirken von Metamorphose und sehr rasch ablaufender Tektonik entstand.

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With 13 Figures

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Dedicated to Prof. Dr. Dr. h. c.B. Sander on the occasion of his 90th birthday.     

The volcano-magnetic effect

Summary A geometrically simple volcano is considered, havig a spherical magma chamber of 2.5 km radius centred at 10 km depth. The Curie point isotherm is assumed to be a plane at 20 km depth, except for the spherical volume which is also non-magnetic. The stress pattern in the vicinity of the spherical chamber, due to regional stress of sufficient intensity to cause an eruptions, is used to calculate the change in magnetization which results from the piezomagnetic effect through the volume of solid rock. The consequent magnetic field anomaly at the surface is then obtaied by numerical integration of the dipole law of force over the stressed volume. For rocks of the type found on the volcanic island of St. Vincent (West Indies), this model gives a maximum local volcano-magnet c effect of about 7 gammas.     

Isolated versus common envelope dynamos in planetary nebula progenitors

The origin, evolution and role of magnetic fields in the production and shaping of proto-planetary nebulae (PPNe) and planetary nebulae (PNe) are a subject of active research. Most PNe and PPNe are axisymmetric with many exhibiting highly collimated outflows; however, it is important to understand whether such structures can be generated by isolated stars or require the presence of a binary companion. Towards this end, we study a dynamical, large-scale α−Ω interface dynamo operating in a 3.0 M_⊙ Asymptotic Giant Branch (AGB) star in both an isolated setting and a setting in which a low-mass companion is embedded inside the envelope. The back reaction of the fields on the shear is included and differential rotation and rotation deplete via turbulent dissipation and Poynting flux. For the isolated star, the shear must be resupplied in order to sufficiently sustain the dynamo. Furthermore, we investigate the energy requirements that convection must satisfy to accomplish this by analogy to the Sun. For the common envelope case, a robust dynamo results, unbinding the envelope under a range of conditions. Two qualitatively different types of explosion may arise: (i) magnetically induced, possibly resulting in collimated bipolar outflows and (ii) thermally induced from turbulent dissipation, possibly resulting in quasi-spherical outflows. A range of models is presented for a variety of companion masses.     

Deep-sea Fe-Mn Crusts from the Northeast Atlantic Ocean: Composition and Resource Considerations

Eighteen deep-sea ferromanganese crusts (Fe-Mn crusts) from 10 seamounts in the northeast Atlantic were studied. Samples were recovered from water depths of ～1,200 to ～4,600 m from seamounts near Madeira, the Canary and Azores islands, and one sample from the western Mediterranean Sea.

The mineralogical and chemical compositions of the samples indicate that the crusts are typical continental margin, hydrogenetic Fe-Mn crusts. The Fe-Mn crusts exhibit a Co + Cu + Ni maximum of 0.96 wt%. Platinum-group element contents analyzed for five samples showed Pt contents from 153 to 512 ppb.

The resource potential of Fe-Mn crusts within and adjacent to the Portuguese Exclusive Economic Zone (EEZ) is evaluated to be comparable to that of crusts in the central Pacific, indicating that these Atlantic deposits may be an important future resource.     

Carbon Dioxide in igneous petrogenesis: I

A number of experimental CO₂ solubility data for silicate and aluminosilicate melts at a variety of P- T conditions are consistent with solution of CO₂ in the melt by polymer condensation reactions such as SiO _4(m ^4? +CO_2(v)+Si _n O _3n+1(m) ⁽²ⁿ⁺¹⁾ ?Si _n+1O _3n+4(m) ^(2n+4)? +CO _3(m ^)2? . For various metalsilicate systems the relative solubility of CO₂ should depend markedly on the relative Gibbs free change of reaction. Experimental solubility data for the systems Li₂O-SiO₂, Na₂O-SiO₂, K₂O-SiO₂, CaO-SiO₂, MgO-SiO₂ and other aluminosilicate melts are in complete accord with predictions based on Gibbs Free energies of model polycondesation reactions. A rigorous thermodynamic treatment of published P- T-wt.% CO₂ solubility data for a number of mineral and natural melts suggests that for the reaction CO_2(m) ? CO_2(v)

1. CO₂-melt mixing may be considered ideal (i.e., { \(a_{{\text{CO}}_{\text{2}} }^m = X_{{\text{CO}}_{\text{2}} }^m \) );
2. \(\bar V_{{\text{CO}}_{\text{2}} }^m \) , the partial molal volume of CO₂ in the melt, is approximately equal to 30 cm³ mole^?1 and independent of P and T;
3. Δ C _p ⁰ is approximately equal to zero in the T range 1,400° to 1,650 °C and
4. enthalpies and entropies of the dissolution reaction depend on the ratio of network modifiers to network builders in the melt. Analytic expressions which relate the CO₂ content of a melt to P, T, and \(f_{{\text{CO}}_{\text{2}} } \) for andesite, tholeiite and olivine melilite melts of the form

$$\ln X_{{\text{CO}}_{\text{2}} }^m = \ln f_{{\text{CO}}_{\text{2}} } - \frac{A}{T} - B - \frac{C}{T}(P - 1)$$ have been determined. Regression parameters are (A, B, C): andesite (3.419, 11.164, 0.408), tholeiite (14.040, 5.440,0.393), melilite (9.226, 7.860, 0.352). The solubility equations are believed to be accurate in the range 3<P<30 kbar and 1,100°<T<1,650 °C. A series of CO₂ isopleth diagrams for a wide range of T and P are drawn for andesitic, tholeiitic and alkalic melts.