Volatile halocarbons released from Arctic macroalgae

Twenty-two different species of Arctic brown, red and green macroalgae, collected in the Kongsfjord at Ny-Ålesund (Spitsbergen), were incubated under polar conditions and investigated for their release of volatile halogenated organic compounds (VHOC). Bromoform, dibromomethane, dibromochloromethane, bromodichloromethane, 1,2-dibromoethane, diiodomethane and chloroiodomethane have been identified and their net releases during incubations were determined. Generally, brown and green macroalgae showed higher VHOC release, while red macroalage had only low release. Bromoform was released in relatively large quantities from all species studied, with the highest release observed from the brown algae Dictyosyphon foeniculaceus (0.3 μg g⁻¹ wet algal weight day⁻¹) and Laminaria saccharina (0.15 μg g⁻¹ wet algal weight day⁻¹), and from the green algae Monostroma arcticum (0.3 μg g⁻¹ wet algal weight day⁻¹) and Blidingia minima (0.27 μg g⁻¹ wet algal weight day⁻¹). Dibromomethane, diiodomethane, dibromochloromethane and 1,2-dibromoethane showed lower net release during the incubations. The net release of chloroiodomethane and bromodichloromethane was very low for the most algae species investigated. Based on the distribution of these algae in the Arctic environment, Dictyosiphon foeniculaceus and Laminaria saccharina may be important sources for VHOC because of high release and high biomass. Release of VHOC could be detected from all parts of the thallus of the macroalga. This may provide some evidence for a possible role of VHOC production as a chemical protection mechanism in algae.     

A global heat and freshwater forcing dataset for ocean models

A global dataset based on the ECMWF Re-Analyses (ERA) is presented that can be used as surface boundary conditions for ocean models with sea-ice components. The definition of these conditions is based on bulk formulae. To study the mean ocean circulation, a mean annual cycle on a daily basis was constructed from ERA for all relevant parameters including wind stress. Continental runoff is considered by using information about the catchment areas of the rivers and about the main drainage basins. The bulk formulae were extended by using sea ice concentration.To estimate meridional heat transports (MHT) and to avoid any drift in ocean model simulations, the heat and fresh water budgets have been closed by applying an inverse procedure to fine-tune the fluxes towards observed transports. To improve the MHTs on the Southern Hemisphere the winds and the short wave radiation at southern higher latitudes should be corrected. Furthermore, tests were performed concerning short wave radiation which was increased in the tropics and decreased in the subsidence zones.The heat and fresh water fluxes are assessed by using a scheme of Macdonald and Wunsch based on hydrographic sections. The net heat fluxes of ERA and of the forcing dataset are consistent with the heat flux divergences and convergences estimated by this scheme except for parts of the South Atlantic and the Indian Ocean sector of the Southern Ocean where none of these datasets is consistent with these estimates. In the subtropical South Indian Ocean the forcing dataset is consistent with these estimates while ERA are not. The flux components of ERA and the forcing dataset were compared to several observational datasets (SRB, SOC, HOAPS, GPCP, and CMAP). For each component, at least one of these datasets (especially HOAPS) supports the effects of the inverse procedure and the bulk formulae almost globally with some regional exceptions: short wave radiation in the tropical oceans and the subtropical North Atlantic, latent heat flux at higher latitudes, and precipitation in the northern North Atlantic.Comparisons to the NCAR/NCEP Re-Analyses (NRA) (versions 1 and 2) and the ECHAM model in place of ERA lead to similar results. In the North Atlantic the net heat fluxes of the model based datasets approach the hydrographic estimate with increasing resolution. Applied to any ocean/sea-ice model and compared to ERA, the forcing dataset would induce only a relative small net sea-surface buoyancy loss.A comparison of the forcing dataset to measurements made using one buoy deployed in the western Pacific warm pool and five buoys deployed in the subduction region of the Northeast Atlantic shows that at the site of the first buoy the net heat fluxes of the forcing dataset are in poorer agreement than those of ERA. At the sites of two subduction buoys both datasets show the same level of agreement within the error bars specified. At the sites of the three remaining subduction buoys the forcing dataset shows a marginal improvement on ERA.     

The Meteoritical Bulletin,No. 74, 1993 March.*

Abstract— The Meteoritical Bulletin, Number 74, contains listings for 190 meteorites, including 112 from North Africa, 63 from Antarctica and eight from Australia and six from the U.S. Among the meteorites described are 15 type 3 ordinary chondrites, most notably Roosevelt County 075 which is the lowest petrologic type H chondrite known to date, two very similar ureilites (Nova 1 and Nullarbor 010), a howardite (Old Homestead 001), a CK3 chondrite (Camel Donga 003), a CV3 chondrite (Denman 002) and a major new CR chondrite (Acfer 311 and 10 meteorites with which it is paired).     

The magnificent seven: magnetic fields and surface temperature distributions

Presently seven nearby radio-quiet isolated neutron stars discovered in ROSAT data and characterized by thermal X-ray spectra are known. They exhibit very similar properties and despite intensive searches their number remained constant since 2001 which led to their name “The Magnificent Seven”. Five of the stars exhibit pulsations in their X-ray flux with periods in the range of 3.4 s to 11.4 s. XMM-Newton observations revealed broad absorption lines in the X-ray spectra which are interpreted as cyclotron resonance absorption lines by protons or heavy ions and/or atomic transitions shifted to X-ray energies by strong magnetic fields of the order of 10¹³ G. New XMM-Newton observations indicate more complex X-ray spectra with multiple absorption lines. Pulse-phase spectroscopy of the best studied pulsars RX J0720.4-3125 and RBS 1223 reveals variations in derived emission temperature and absorption line depth with pulse phase. Moreover, RX J0720.4-3125 shows long-term spectral changes which are interpreted as due to free precession of the neutron star. Modeling of the pulse profiles of RX J0720.4-3125 and RBS 1223 provides information about the surface temperature distribution of the neutron stars indicating hot polar caps which have different temperatures, different sizes and are probably not located in antipodal positions.     

Spectral analyses of solar photospheric fluctuations

Successful subtraction of instrumental background variations has permitted spectral analyses of two-dimensional measurement arrays of granulation brightness fluctuations at the center of the disk, arrays obtained from Stratoscope I, 1959B-flight, high-resolution frames B1551 and B3241.

1. RMS's, uncorrected for instrumental blurring, are 0.0850 of mean intensity for B1551 and 0.0736 for B3241, somewhat higher than other determinations. These between-frame and between-investigation differences probably result from a combination of calibration errors, frame resolution differences, and, most likely, granulation pattern differences.
2. Significant variations over each array of mean intensities and RMS's, determined for sub-arrays with dimensions in the 2500–10000 km range, indicate spatial brightness and RMS variations larger than the ‘scale’ of the granulation pattern, supporting a turbulent interpretation of photospheric convection.
3. One-dimensional power-spectra shapes provide objective and discriminating criteria for determining granulation pattern differences and, possibly, frame resolution.
4. Two-dimensional power spectra show small, essentially random deviations from axial symmetry which lie almost entirely within the 50% confidence limits.
5. Spectral densities and fluctuation power spectra, computed from the two-dimensional power spectra and corrected for instrumental blurring, noise, and blemishes, have a useable radial wavenumber range nearly double that of earlier Stratoscope I analyses.
6. Corrected RMS's obtained from the corrected fluctuation power spectra, 0.145 ± 0.046 for B1551 and 0.136 ± 0.048 for B3241, depend critically on the accuracy of the correction.
7. The spectra's wavenumber range includes the granulation-fluctuation-producing domain but not the Kolmogoroff domain of turbulence spectra.

     

Observations of the inner F and K coronas below λ2220

The inner coronal continuum has been observed and measured below 2220 on the slitless spectra obtained by Speer et al. (1970) at the 7 March 1970 eclipse. These observations set some constraints on the brightness of the inner F corona and hence on the scattering efficiency of the inner interplanetary dust cloud particles in the far ultraviolet. They neither confirm nor reject the possibility that the inner dust cloud has the same sharp upturn in scattering efficiency below 2000 observed in the zodiacal light and in the interstellar medium.On leave from Imperial College, London.This work was supported in part by NASA grant NGL 12-001-011. An I.A.U. travelgrant to one of us (R.J.S.) is gratefully acknowledged.     

High oxidation state during formation of Martian nakhlites

Abstract– The oxygen fugacities recorded in the nakhlites Nakhla, Yamato‐000593 (Y‐000593), Lafayette, and NWA998 were studied by applying the Fe,Ti‐oxide oxybarometer. Oxygen fugacities obtained cluster closely around the FMQ (Fayalite–Magnetite–Quartz) buffer (NWA998 = FMQ ? 0.8; Y‐000593 = FMQ ? 0.7; Nakhla = FMQ; Lafayette = FMQ + 0.1). The corresponding equilibration temperatures are 810 °C for Nakhla and Y‐000593, 780 °C for Lafayette and 710 °C for NWA998. All nakhlites record oxygen fugacities significantly higher and with a tighter range than those determined for Martian basalts, i.e., shergottites whose oxygen fugacities vary from FMQ ? 1 to FMQ ? 4. It has been known for some time that nakhlites are different from other Martian meteorites in chemistry, mineralogy, and crystallization age. The present study adds oxygen fugacity to this list of differences. The comparatively large variation in fO₂ recorded by shergottites was interpreted by Herd et al. (2002) as reflecting variable degrees of contamination with crustal fluids that would also carry a light rare earth element (REE)‐enriched component. The high oxygen fugacities and the large light REE enrichment of nakhlites fit qualitatively in this model. In detail, however, it is found that the inferred contaminating phase in nakhlites must have been different from those in shergottites. This is supported by unique ¹⁸²W/¹⁸⁴W and ¹⁴²Nd/¹⁴⁴Nd ratios in nakhlites, which are distinct from other Martian meteorites. It is likely that the differences in fO₂ between nakhlites and other Martian meteorites were established very early in the history of Mars. Parental trace element rich and trace element poor regions (reservoirs) of Mars mantle ( Brandon et al. 2000 ) must have been kept isolated throughout Martian history. Our results further show significant differences in closure temperature among the different nakhlites. The observed range in equilibration temperatures together with similar fO₂ values is attributable to crystallization of nakhlites in the same cumulate pile or lava layer at different burial depths from 0.5 to 30 m below the Martian surface in agreement with Mikouchi et al. (2003) and is further confirmed by similar crystallization ages of about 1.3 Ga ago (e.g., Misawa et al. 2003 ).