The effect of titanium and phosphorus on ferric/ferrous ratio in silicate melts: an experimental study

The effect of TiO₂ and P₂O₅ on the ferric/ferrous ratio in silicate melts was investigated in model silicate melts at air conditions in the temperature range 1,400–1,550 °C at 1-atm total pressure. The base composition of the anorthite–diopside eutectic composition was modified with 10 wt % Fe₂O₃ and variable amounts of TiO₂ (up to 30 wt %) or P₂O₅ (up to 20 wt %). Some compositions also contained higher SiO₂ concentrations to compare the role of SiO₂, TiO₂, and P₂O₅ on the Fe³⁺/Fe²⁺ ratio. The ferric/ferrous ratio in experimental glasses was analyzed using a wet chemical technique with colorimetric detection of ferrous iron. It is shown that at constant temperature, an increase in SiO₂, TiO₂, and P₂O₅ content results in a decrease in the ferric/ferrous ratio. The effects of TiO₂ and SiO₂ on the Fe³⁺/Fe²⁺ ratio was found to be almost identical. In contrast, adding P₂O₅ was found to decrease ferric/ferrous ratio much more effectively than adding silica. The results were compared with the predictions from the published empirical equations forecasting Fe³⁺/Fe²⁺ ratio. It was demonstrated that the effects of TiO₂ are minor but that the effects of P₂O₅ should be included in models to better describe ferric/ferrous ratio in phosphorus-bearing silicate melts. Based on our observations, the determination of the prevailing fO₂ in magmas from the Fe³⁺/Fe²⁺ ratio in natural glasses using empirical equations published so far is discussed critically.     

The Ultimate CCD for Laser Guide Star Wavefront Sensing on Extremely Large Telescopes

All of the extremely large telescopes (ELTs) will utilize sodium laser guide star (LGS) adaptive optics (AO) systems. Most of these telescopes plan to use the Shack-Hartmann approach for wavefront sensing. In these AO systems, the laser spots in subapertures at the edge of the pupil will suffer from spot elongation due to the 10 km extent of the sodium layer and the large separation from the projection laser. This spot elongation will severely degrade the performance of standard geometry wavefront sensing systems. In this paper, we present a CCD with custom pixel morphology that aligns the pixels of each subaperture with the radial extension of the LGS spot. This CCD design will give better performance than a standard geometry CCDs for continuous wave lasers. In addition, this CCD design is optimal for a pulsed sodium laser. The pixel geometry enables each subaperture to follow a laser pulse traversing the sodium layer, providing optimal sampling of a limited number of detected photons. In addition to novel pixel layout, this CCD will also incorporate experimental JFET sense amplifiers and use CMOS design approaches to simplify the routing of biases, clocks and video output. This CCD will attain photon-noise limited performance at high frame rates, and is being incorporated in the plans for the Thirty Meter Telescope (TMT).     

Towards bridging the gap between climate change projections and maize producers in South Africa

Theoretical and Applied Climatology - Multi-decadal regional projections of future climate change are introduced into a linear statistical model in order to produce an ensemble of austral...     

High‐resolution evolution of terrigenous sediment yields in the Provence Basin during the last 6 Ma: relation with climate and tectonics

Basin‐wide correlation of Messinian units and Plio‐Quaternary chronostratigraphic markers (5.3 Ma, 2.6 Ma, 0.9 Ma and 0.45 Ma), the mapping of total sediment thickness and the determination of overall sedimentary volumes enabled us to provide a high‐resolution quantitative history of sediment volumes for the last 6 Ma along the Gulf of Lions margin. The results point to (i) a dramatic increase in terrigenous sediment input during the Messinian Salinity Crisis. This increased sedimentation reflects enhanced regional fluvial erosion related to the dramatic fall of Mediterranean base‐level. Stronger weathering due to a regional wetter climate probably also increased erosional fluxes. (ii) A sediment input three times higher during the Plio‐Quaternary compared to the Miocene seems in agreement with published measurements from World's ocean. However, the timing of this increase being uncertain, it implies that the trigger(s) also remain(s) uncertain. (iii) A decrease in detrital volume around 2.6 Ma is attributed to a regional change in the drainage pattern of rivers in the northwestern Alps. (iv) This study also highlights the Mid‐Pleistocene Revolution around 0.9 Ma, which resulted in an almost doubling of sediment input in the Provencal Basin.     

A complex diagnostic of solar prominences

We use the polarimetric and intensity measurements of H and HeI D₃ lines in solar prominences to derive the true geometrical thickness for several quiescent prominences. The electron densities, derived from the collisional depolarization in H by Bommier et al. (1994), are used to evaluate the thickness from the emission measure. The emission measure was obtained from the theoretical correlation with the H integrated intensity, according to Gouttebroze, Heinzel, and Vial (1993). Theoretical electron densities obtained by latter authors are also compared with those of Bommier et al. (1994) and we find a very good agreement between them. The prominence geometrical thickness exhibits a relatively large range of values from about 100 km up to a few 10⁴ km. The plasma densities vary by almost two orders of magnitude in the observed structures, but the total column mass in the direction perpendicular to the prominence sheet seems to be fairly constant for the set of prominences studied.     

The UV cameras on the High Energy Transient Experiment (HETE)

The High Energy Transient Experiment (HETE), scheduled for launch this year, is a small satellite dedicated to multiwavelength observations of -ray and X-ray bursts. The HETE spacecraft will be equipped with gamma-ray detectors, X-ray detectors with a coded mask, and ultraviolet-sensitive CCD cameras. The UV cameras on HETE are wide-field imagers which will a) provide UV images of the regions in which -ray or X-ray bursts are detected, before, duringand after the burst, b) detect UV transients, whether associated with a high-energy transient or not, c) monitor the brightnesses of field stars for variability over a wide range of timescales, and d) serve as star trackers for HETE. In this poster, we describe the HETE UV instrumentation, control software, and data products.     

FORMATION OF Ca II LINES IN SOLAR PROMINENCES

We compute the profiles of the resonance lines and infrared triplet of ionized calcium emitted by some representative models of prominences. These models consist of plane-parallel slabs of different temperatures, pressures and thicknesses, standing vertically above the solar surface. These slabs are assumed to be observed at the limb, and to be perpendicular to the line of sight. They are irradiated by the Sun on both sides, and the incoming intensities, at every relevant wavelength, are taken from observations. The model atom includes 3 stages of ionization (Cai, Caii and Caiii) with 5 discrete levels for Caii. We study the relations between emitted intensities and physical properties of the slabs, and compare the intensities emitted in Caii and hydrogen lines for the same set of models. As a result of ionization, the intensity decreases more rapidly with temperature in Caii lines than in Hi lines, so that the ratio of Caii to Hi line intensities may be used as a temperature indicator. The intensity ratio between resonance and infrared lines of Caii depends principally on the optical thickness of the structure. At high pressure and low temperature, the ratio Caii 8542Å/H is found to increase with pressure. This behaviour, which is due to the saturation of H, is opposite to that found by Heasley and Milkey (1978) for low pressures (optically thin structures).     

Contextualizing vulnerability assessment: a support to geo-risk management in central Africa

European Union directives as well as national legislation are placing great emphasis on the inclusion of stakeholder perspectives in the governance of risks from natural hazards. This should help decision makers formulate better policies. However, to date, there is little information on stakeholders’ perspectives with respect to landslide risk governance. This paper addresses the gap by reporting on research in Nocera Inferiore, Italy. The research is based on a documentary analysis, 43 semi-structured interviews and a survey submitted to 373 residents. The political instability, the unfairness of national funding allocation across municipalities and the residents’ lack of knowledge about risk assessment and emergency planning are some of the main barriers to effective risk governance. Moreover, there are divergent, sometimes even opposite, stakeholders’ views on several issues, such as the relevance of illegal development in risky areas. The results highlight the importance of addressing these divergent views and including the plurality of voices as a prerequisite for inclusive risk governance. The research provided essential background information for a participatory process, which was designed to support decisions on landslide risk mitigation measures in Nocera Inferiore (Linnerooth-Bayer et al. this issue). The methodology will be of more general interest to researchers and policymakers intent upon including stakeholder perspectives in natural risk governance.     

Lα, Lβ (of Hi), k and h (of Mgii), K and H (of Ca ii) observations in a quiescent prominence with the OSO-8 LPSP instrument

A sequence of images taken at different positions in the resonance lines of Ca ii, Mg ii, and H i was obtained over a quiescent prominence with the LPSP instrument on OSO-8. Ca ii K (and H) profiles are reconstructed at different locations in the prominence with a (10 × 5) arc sec² resolution. Significant variations of FWHM and line shifts are found: FWHM range from 0.14 Å to 0.5 Å; blue shifts reach about 14 km s^-1. The ratio of K to H absolute intensities shows a large spread around the average value of 1.2. The same ratio for the Mg ii lines in the whole prominence is higher (1.7), a fact already noticed at the edge of an active prominence (Vial et al., 1979). The ionization degree, as measured by the L/Ca K ratio, shows noticeable variations within the prominence. The L intensity is about 0.3 times the intensity measured in the quiet Sun, and the L/L ratio is less than one half the disk value. These results indicate important variations of the thermal conditions inside the prominence.DASOP, Observatoire de Paris, 92190 Meudon, France.