Anomalous Diffuse CO2 Emission prior to the January 2002 Short-term Unrest at San Miguel Volcano, El Salvador, Central America

On January 16, 2002, short-term unrest occurred at San Miguel volcano. A gas-and-steamash plume rose a few hundred meters above the summit crater. An anomalous microseismicity pattern, about 75 events between 7:30 and 10:30 hours, was also observed. Continuous monitoring of CO₂ efflux on the volcano started on November 24, 2001, in the attempt to provide a multidisciplinary approach for its volcanic surveillance. The background mean of the diffuse CO₂ emission is about 16 g m^-2 d^-1, but a 17- fold increase, up to 270 g m^-2 d^-1, was detected on January 7, nine days before the January 2002 short-term unrest at San Miguel volcano. These observed anomalous changes on diffuse CO₂ degassing could be related to either a sharp increase of CO₂ pressure within the volcanic-hydrothermal system or degassing from an uprising fresh gas-rich magma within the shallow plumbing system of the volcano since meteorological fluctuations cannot explain this observed increase of diffuse CO₂ emission.     

Functional diversity of fish and invertebrates in coral and rocky reefs of the Eastern Tropical Pacific

To define the functional groups of fish and macroinvertebrates in the Eastern Tropical Pacific (ETP), visual censuses were performed in 18 areas of four biogeographic provinces: Cortés, Mexican, Panamic and Oceanic Islands. A total of 257 fish and macroinvertebrate species were recorded, and from them, 27 morpho‐functional groups (MFGs) were constructed on the basis of trophic level, maximum size, taxonomy and morphology. Biomass, richness, diversity and evenness of MFGs were calculated for each province and compared statistically; a regression analysis between taxonomic and functional diversity was conducted to observe the relationship between these two indicators. There were significant differences in all ecological indices (p < .002), highlighting the high biomass and richness of MFGs in the Cortés and Oceanic Islands provinces (>400 g/m²), associated with the influence of cold currents in the northernmost region and less fishing pressure in protected areas. A decreasing pattern of MFG richness towards the tropics was observed, which demonstrates that in the ETP, the relationship between habitat heterogeneity and species diversity has been translated into functional complexity. The Mexican province was the most functionally diverse (biomass well distributed in the MFG; H′ = 0.46 ± 0.009). Related to this, it is predicted that biomass is biased towards certain functional groups (i.e., large carnivores), which shows that the H′ index of the MFG is not a good indicator of the conservation status of ETP reefs. Finally, regression analysis suggests that functional diversity increases at low species diversity but eventually reaches an asymptote (almost all possible functions are represented).     

Fluid circulation in a complex volcano-tectonic setting,inferred from self-potential and soil CO2 flux surveys: The Santa María–Cerro Quemado–Zunil volcanoes and Xela caldera (Northwestern Guatemala)

The region encompassing Santa María, Cerro Quemado, and Zunil volcanoes, close to Quetzaltenango, the second largest city of Guatemala, is volcanically and tectonically complex. In addition, the huge Xela caldera, about 20 km in diameter, crosses this area and links up to the important Zunil fault zone located between the three volcanoes. Two highly active geothermal sites, named Zunil-I and Zunil-II, are also located between these three volcanic edifices at the southeastern boundary of Xela caldera. In order to determine the permeability variations and the main structural discontinuities within this complex volcano-tectonic setting, self-potential and soil CO₂ flux measurements have been coupled, with a step of 20 m, along a 16.880 km-long profile crossing the entire area. Two shallow hydrothermal systems, with maximum lateral extensions of 1.5 km in diameter, are indicated by positive self-potential/elevation gradients below Santa María and Cerro Quemado volcanoes. Such small hydrothermal systems cannot explain the intense geothermal manifestations at Zunil-I and Zunil-II. Another minor hydrothermal system is indicated by self-potential measurements on the flank of Santa María along the edge of the Xela caldera. CO₂ flux measurements display slight variations inside the caldera and decreasing values crossing outside the caldera boundary. We hypothesize the presence of a magmatic body, inside the southeastern border of Xela caldera, to explain the deeper and more intense hydrothermal system manifested by the Zunil-I and the Zunil-II geothermal fields. This magmatic system may be independent from Santa María and Cerro Quemado volcanoes. Alternatively, the hypothesized Xela magmatic system could have a common magmatic origin with the Cerro Quemado dome complex, consistent with previous findings on regional gas emissions. Sectors bordering the Cerro Quemado dome complex also have high amplitude minima-short wavelength anomalies in self-potential, interpreted as preferential rain water infiltration along faults of major permeability, probably related with the most recent stages of Cerro Quemado dome growth.     

Reproductive patterns of the abyssal asteroid Styracaster elongatus from the N.E. Atlantic Ocean

We analysed the reproductive biology of the asteroid species Styracaster elongatus based on time-series samples from a 5000-m-deep site on the Porcupine Abyssal Plain (N.E. Atlantic). The ratio of males to females, the gonadosomatic index (GI), and pyloric caecum index (PCI) were determined and the results were corroborated by histological examination of the gonads. Fecundity and oocyte-size distribution were determined by histological and image analyses. Styracaster elongatus is a gonochoric asteroid and the ratio of males to females was not significantly different throughout the year. Oogenesis was asynchronous. The previtellogenic oocytes grew to a size of ～230 μm before undergoing vitellogenesis. Maximum oocyte size was ～620 μm. The ovary volume was mainly occupied by small previtellogenic oocytes (100–150 μm) at any one time. Mean GI was 6.38±3.30 for females and 9.04±4.1 for males. Mean PCI was 7.44±1.66 for females and 7.66±1.46 for males. Mean fecundity was 16,373±5988 oocites per female. There were no seasonal variations in GI and fecundity. There was evidence of a pyiloric caecum seasonal development for females and males. For S. elongatus there is no direct relationship among seasonal primary production at the surface and production of vitellogenic oocytes. Nevertheless, this species takes advantage of the pulse of phytodetritus to the seabed by increasing the storage of nutrients in the pyloric caecum in order to maintain a constant production of eggs and sperm.     

Source and evolution of ore-forming hydrothermal fluids in the northern Iberian Pyrite Belt massive sulphide deposits (SW Spain): evidence from fluid inclusions and stable isotopes

A fluid inclusion and stable isotopic study has been undertaken on some massive sulphide deposits (Aguas Teñidas Este, Concepción, San Miguel, San Telmo and Cueva de la Mora) located in the northern Iberian Pyrite Belt. The isotopic analyses were mainly performed on quartz, chlorite, carbonate and whole rock samples from the stockworks and altered footwall zones of the deposits, and also on some fluid inclusion waters. Homogenization temperatures of fluid inclusions in quartz mostly range from 120 to 280 °C. Salinity of most fluid inclusions ranges from 2 to 14 wt% NaCl equiv. A few cases with T _h=80–110 °C and salinity of 16–24 wt% NaCl equiv., have been also recognized. In addition, fluid inclusions from the Soloviejo Mn–Fe-jaspers (160–190 °C and ˜6 wt% NaCl equiv.) and some Late to Post-Hercynian quartz veins (130–270 °C and ˜4 wt% NaCl equiv.) were also studied. Isotopic results indicate that fluids in equilibrium with measured quartz (d ¹⁸O _fluid ˜–2 to 4‰), chlorites (d ¹⁸O _fluid ˜8–14‰, dD _fluid ˜–45 to –27‰), whole rocks (d ¹⁸O _fluid ˜4–7‰, dD _fluid ˜–15 to –10‰), and carbonates (d ¹⁸O _ankerite ˜14.5–16‰, d ¹³C _fluid =–11 to –5‰) evolved isotopically during the lifetime of the hydrothermal systems, following a waxing/waning cycle at different temperatures and water/rock ratios. The results (fluid inclusions, d ¹⁸O, dD and d ¹³C values) point to a highly evolved seawater, along with a variable (but significant) contribution of other fluid reservoirs such as magmatic and/or deep metamorphic waters, as the most probable sources for the ore-forming fluids. These fluids interacted with the underlying volcanic and sedimentary rocks during convective circulation through the upper crust.     

Using ichnofossils to characterize chert tools: A preliminary study from Southern Iberia

Characterizing raw material of stone tools used by Late Neolithic and Copper Age communities is important for interpreting access to available sources and establishing regional routes of distribution. Ichnological analysis may be used to help characterize lithic material and determine the source of artifacts. Here we report for the first time the existence of trace fossils in artifacts from the Late Neolithic and Copper Age of southern Spain. Ichnological analysis indicates a trace fossil assemblage consisting of relatively scarce small‐sized Chondrites and abundant Phycosiphon. A regional survey of natural outcrops and chert quarries indicates the presence of discrete trace fossils only in the samples from geological formations that are part of the Campo de Gibraltar Complex. Ichnological composition in these samples is similar to that discerned in the artifacts and suggests that this was the probable source of the chert used in tool manufacture. © 2010 Wiley Periodicals, Inc.