Synthesis of a spinifex‐textured basalt as an analog to Gusev crater basalts,Mars

Abstract– Analyses by the Mars Exploration Rover (MER), Spirit, of Martian basalts from Gusev crater show that they are chemically very different from terrestrial basalts, being characterized in particular by high Mg‐ and Fe‐contents. To provide suitable analog basalts for the International Space Analogue Rockstore (ISAR), a collection of analog rocks and minerals for preparing in situ space missions, especially, the upcoming Mars mission MSL‐2011 and the future international Mars‐2018 mission, it is necessary to synthesize Martian basalts. The aim of this study was therefore to synthesize Martian basalt analogs to the Gusev crater basalts, based on the geochemical data from the MER rover Spirit. We present the results of two experiments, one producing a quench‐cooled basalt (<1 h) and one producing a more slowly cooled basalt (1 day). Pyroxene and olivine textures produced in the more slowly cooled basalt were surprisingly similar to spinifex textures in komatiites, a volcanic rock type very common on the early Earth. These kinds of ultramafic rocks and their associated alteration products may have important astrobiological implications when associated with aqueous environments. Such rocks could provide habitats for chemolithotrophic microorganisms, while the glass and phyllosilicate derivatives can fix organic compounds.     

Palaeoecological,archaeological and historical data and the making of Devon landscapes. I. The Blackdown Hills

This paper presents the first systematic study of the vegetation history of a range of low hills in SW England, UK, lying between more researched fenlands and uplands. After the palaeoecological sites were located bespoke archaeological, historical and documentary studies of the surrounding landscape were undertaken specifically to inform palynological interpretation at each site. The region has a distinctive archaeology with late Mesolithic tool scatters, some evidence of early Neolithic agriculture, many Bronze Age funerary monuments and Romano‐British iron‐working. Historical studies have suggested that the present landscape pattern is largely early Medieval. However, the pollen evidence suggests a significantly different Holocene vegetation history in comparison with other areas in lowland England, with evidence of incomplete forest clearance in later‐Prehistory (Bronze?Iron Age). Woodland persistence on steep, but poorly drained, slopes, was probably due to the unsuitability of these areas for mixed farming. Instead they may have been under woodland management (e.g. coppicing) associated with the iron‐working industry. Data from two of the sites also suggest that later Iron Age and Romano‐British impact may have been geographically restricted. The documented Medieval land management that maintained the patchwork of small fields, woods and heathlands had its origins in later Prehistory, but there is also evidence of landscape change in the 6th–9th centuries AD. We conclude that the Blackdown Hills area was one of many ‘distinctive subregions’, which due to a combination of edaphic, topographic and cultural factors could qualify as an eco‐cultural region or ‘pays’. It is argued that the use of such eco‐culturally distinctive regions or pays can provide a spatial and archaeological framework for palaeoecology, which has implications for landscape research, designation and heritage management.     

Temporal variability of dimethylsulfide and dimethylsulfoniopropionate in the Sargasso Sea

Vertical profiles of dimethylsulfide (DMS) and β-dimethylsulfoniopropionate, particulate (pDMSP) and dissolved (dDMSP), were measured biweekly in the upper 140 m of the Sargasso Sea (32°10′N, 64°30′W) during 1992 and 1993. DMS and pDMSP showed strong, but different, seasonal patterns; no distinct intra-annual pattern was observed for dDMSP. During winter, concentrations of DMS were generally less than 1 nmol l⁻¹ at all depths, dDMSP was less than 3 nmol l⁻¹ and pDMSP was less than 8 nmol l⁻¹. In spring, concentrations of both dDMSP and pDMSP rose, on a few occasions up to 20 nmol l⁻¹ in the dissolved pool and up to 27 nmol l⁻¹ in the particulate pool. These increases, due to blooms of DMSP-containing phytoplankton, resulted in only minor increases in DMS concentrations (up to 4 nmol l⁻¹). Throughout the summer, the concentrations of DMS continued to increase, reaching a maximum in August of 12 nmol l⁻¹ (at 30 m depth). There was no concomitant summer increase in dDMSP or pDMSP. The differences among the seasonal patterns of DMS, dDMSP, and pDMSP suggest that the physical and biological processes involved in the cycling of DMS change with the seasons. There is a correlation between the concentration of DMS and temperature in this data set, as required by some of the climate feedback models that have been suggested for DMS. A full understanding of the underlying processes controlling DMS is required to determine if the temperature-DMS pattern is of significance in the context of global climate change.     

Deducing the source and composition of rare earth mineralising fluids in carbonatites: insights from isotopic (C,O, <Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr) data from Kangankunde,Malawi

Carbonatites host some of the largest and highest grade rare earth element (REE) deposits but the composition and source of their REE-mineralising fluids remains enigmatic. Using C, O and ⁸⁷Sr/⁸⁶Sr isotope data together with major and trace element compositions for the REE-rich Kangankunde carbonatite (Malawi), we show that the commonly observed, dark brown, Fe-rich carbonatite that hosts REE minerals in many carbonatites is decoupled from the REE mineral assemblage. REE-rich ferroan dolomite carbonatites, containing 8–15 wt% REE₂O₃, comprise assemblages of monazite-(Ce), strontianite and baryte forming hexagonal pseudomorphs after probable burbankite. The ⁸⁷Sr/⁸⁶Sr values (0.70302–0.70307) affirm a carbonatitic origin for these pseudomorph-forming fluids. Carbon and oxygen isotope ratios of strontianite, representing the REE mineral assemblage, indicate equilibrium between these assemblages and a carbonatite-derived, deuteric fluid between 250 and 400 °C (δ¹⁸O + 3 to + 5‰_VSMOW and δ¹³C ? 3.5 to ? 3.2‰_VPDB). In contrast, dolomite in the same samples has similar δ¹³C values but much higher δ¹⁸O, corresponding to increasing degrees of exchange with low-temperature fluids (< 125 °C), causing exsolution of Fe oxides resulting in the dark colour of these rocks. REE-rich quartz rocks, which occur outside of the intrusion, have similar δ¹⁸O and ⁸⁷Sr/⁸⁶Sr to those of the main complex, indicating both are carbonatite-derived and, locally, REE mineralisation can extend up to 1.5 km away from the intrusion. Early, REE-poor apatite-bearing dolomite carbonatite (beforsite: δ¹⁸O + 7.7 to + 10.3‰ and δ¹³C ?5.2 to ?6.0‰; ⁸⁷Sr/⁸⁶Sr 0.70296–0.70298) is not directly linked with the REE mineralisation.     

The carbonate fraction in carbonatitic Italian lamprophyres

Alkaline and ultramafic lamprophyres represent the majority of pre-Pleistocene alkaline mafic magmatic activity in Italy and have been described from several localities. The age of magmatism ranges from Triassic to Lower Oligocene. Some contain appreciable amounts of carbonate. The primary carbonate of the Italian carbonatitic lamprophyres is mainly Sr- or Mn-rich calcite that occurs mostly as immiscible ocelli or as groundmass. Its textural occurrence, composition, and relationship with co-precipitating silicate phases is taken as evidence of an igneous origin. Low BaO and REE contents in the carbonate are explained by early crystallization of essential mica and subordinate apatite. Whole rock analyses and isotopic data (Rukhlov, A.S., Bell, K., Vichi, G., Stoppa, F., submitted for publication. The heterogeneous deep mantle: the Sr, Pb and Nd isotopic evidence from Early Cretaceous alkaline lamprophyres of Southern Tuscany, Italy. Lithos.) suggest a mantle origin for these rocks and rule out contamination in either high or low pressure regimes. The bulk compositions of the carbonatitic lamprophyres have high HFSE / LILE and LREE / HREE ratios and although the abundances of these elements are generally lower than for carbonatites s.s., they are comparable with the abundances in other ‘carbonate-free’ Italian lamprophyres and Italian carbonatites, suggesting similar mantle sources. Moreover, the age of the Italian lamprophyres, ranging from Middle Triassic to Lower Oligocene, is much greater than the Pleistocene age of Italian carbonatites and indicates that the source remained similar over a long time span.     

Ultraviolet-B radiation effects on natural phytoplankton assemblages of central San Francisco Bay

Since the discovery of a depletion of the stratospheric ozone layer over Antarctica in 1979, scientific attention has been directed towards the effects of increased doses of ultraviolet radiation on phytoplankton in other ecosystems. Little is known about the effects of ultraviolet-B (280–320 nm) radiation (UVBR) on temperate estuarine phytoplankton. Freshly collected phytoplankton samples from Central San Francisco Bay were exposed to ambient UVBR in quartz bottles and monitored for biomass and nutrient uptake rates for comparison with phytoplankton dispensed into bottles made of polycarbonate that effectively filtered out the UVBR to evaluate response to natural UVBR exposure. Short-term (10–12 h) exposure experiments were carried out monthly from October 1998 to October 1999. No significant effect of UVBR on chlorophylla concentrations was found but a clear deleterious effect of UVBR on nutrient uptake was observed.     

The role of organochlorines in cancer-associated mortality in California sea lions (Zalophus californianus)

Wild California sea lions (Zalophus californianus) have an unusually high prevalence of neoplasms (18% of stranded dead adults) and high levels of contaminants. The contribution of organochlorine (OC) tissue burdens to the probability of sea lions dying from carcinoma was explored using a logistic regression model. Levels of PCBs and DDTs were determined in blubber of sea lions diagnosed with metastatic carcinoma and animals that had died from non-carcinoma-related incidents (e.g., gunshot, domoic acid poisoning). Animals with carcinoma had higher mean concentrations (based on wet weight) of PCBs and DDTs (more than 85% and 30% higher, respectively) in blubber than did sea lions without carcinoma; the highest concentrations of OCs in the sea lions affected with carcinoma were measured in the males. Blubber thickness was significantly different between the two groups of sea lions, but after controlling for this difference, there was still a significant effect of PCBs, but not DDTs, on the probability of sea lions dying with carcinoma. Age, sex, mass and length did not affect the probability of dying from carcinoma.     

The two types of flare-associated filament eruptions

Using 15 years of high-resolution solar film obtained at Big Bear Solar Observatory we studied flare-associated filament eruptions. In addition to the classical type eruption consisting of expansion and breakup, we find evidence of another type where a layer is shed from the filament and erupts while the inversion line filament below (or, what is left of it) remains in place. Both types of eruptions are presented in the paper. It is hoped that the new evidence will shed new light on the understanding of the role of filaments in flares.