Thermal radiation from cloudless skies in Granada

Summary Data on thermal radiation from clear skies obtained at Granada from May to November 1983 were utilized to carry out a detailed comparison between measured and calculated values of longwave radiation with several analytical and empirical equations. The goal of this work is to check the aplicability of these equations to Granada conditions. The results obtained for all the equations are quite satisfactory. Nevertheless, Idso's formula significantly overestimates our experimental results, probably as a consequence of the differences in atmospheric dust conditions between our test area and the location for which that equation was originally derived. A reduction in the independent coefficient, in accordance with previous results of other authors, provides a better fit to our data set and clearly shows the climatological dependence of the constants in the estimation equations.

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Zusammenfassung Die von Mai bis November 1983 in Granada gesammelten Daten über Wärmestrahlung bei klarem Himmel wurden dazu verwendet, um einen detaillierten Vergleich zwischen gemessenen und errechneten Werten der langwelligen Strahlung aus verschiedenen analytischen und empirischen Gleichungen durchzuführen. Das Ziel dieser Arbeit ist es, die Anwendbarkeit dieser Gleichungen auf die Verhältnisse in Granada zu überprüfen. Die gewonnenen Ergebnisse sind für alle diese Gleichungen ganz zufriedenstellend. Idsos Formel überschätzt jedoch deutlich unsere experimentellen Ergebnisse, möglicherweise als Folge der unterschiedlichen atmosphärischen Staubbedingungen in unserem Testgebiet und dem Standort, für den die Gleichung ursprünglich abgeleitet wurde. Eine Reduktion des unabhängigen Koeffizienten, in Übereinstimmung mit früheren Ergebnissen anderer Autoren, bietet eine bessere Anpassung an unseren Datensatz und zeigt deutlich die klimatologische Abhängigkeit der Konstanten in Schätzungsgleichungen.

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With 3 Figures     

Diabatic wind and temperature profiles obtained from a 100 m tower: A statistical comparison of model performances

More than 8000 10-min profiles of wind and temperature obtained during an extensive field experiment have been analyzed. The study was carried out in the environs of Valladolid (Spain) where a 100-m and a 6-m meteorological tower are located. Less than 20% of data were discarded due to equipment failure. Because of its exceptional flatness, the site is almost ideal for model performance comparisons.Predicted profiles of wind speed and potential temperature at 12, 26, 51, and 100 m heights were obtained using the methods proposed by Berkowicz and Prahm (1982) and San José (1983) based on values observed on a 6 m tower. Statistical t, F, and R tests were used to determine bias, scatter and correlation. The data were classified according to atmospheric stratification and height above ground. Finally, a determination was made of the predicted wind speeds and potential temperatures that fell within the 1 and 20% confidence ranges centered at the measured value. San José's method performed better than did that of Berkowicz and Prahm for the temperature profiles in both unstable and stable conditions. However, no significant differences were found for the wind speed profiles.     

Changes in current regime and turbidity in response to a freshwater pulse in the eastmain estuary

In September 1984, the freshwater input to the Eastmain River (James Bay, Canada) was increased by a factor of 50 over a 6-d period during a controlled reservoir discharge. Changes to the current, salinity and turbidity regimes were monitored during the peak runoff. Estuarine salinity values fell rapidly with increasing mean flow, as did the amplitude of the semi-diurnal tidal currents. A large increase in bottom shear stress dispersed the settled suspension layer into the water column, raising concentrations of suspended matter in the estuary by a factor of 4 in 3 d. The peak values exceeded 150 mg I^?1. This led to erosion of the river silt deposits, with the export of an estimated 6 × 10⁴ metric tons of sediments. After the reduction of discharge, current values returned to their normal range within a day, whereas upstream salinity intrusion occurred at a slower rate. Horizontal diffusivities of about 100 m² s^?1 were required to match the observed lag.     

Seasonal control of the Saint-Lawrence maximum turbidity zone by tidal-flat sedimentation

The core of the turbidity maximum zone in the Saint-Lawrence Estuary is located in the North Channel and oscillates in front of the large (3×10⁶ m²) intertidal flats and marshes of Cap Tourmente. It is shown that seasonal fluctuations in the intensity and the position of this core are mainly determined by suspended sediment exchanges between the channel and the marshes. Fine sediments, most of them found 20 km downstream in the channel off Cap Maillard in late winter and early spring, are advected upstream over the flats during the summer months by the tide. The deposition, favored by marsh plant growth, reaches 5×10⁵ metric tons in three months. A period of intense erosion, at a mean rate of 4,500 metric tons per tide, coincides with the destruction of the plant cover by migratory geese. The material removed fills up the Chenal de l’Île d’Orléans upstream and is flushed back into the water column during the next spring freshette. This rotating seasonal sediment circulation, although very localized, exerts a major influence on the distribution and storage time of suspended particles in the upper estuary.     

Zirconolite,allanite and hoegbomite in a marble skarn from the Bergell contact aureole: implications for mobility of Ti,Zr and REE

Zirconolite, allanite and hoegbomite are present as accessory phases in a metasomatically altered spinel-calcite-marble from the contact with the Bergell intrusives (Switzerland/Italy). Textural relationships indicate a step-wise alteration of spinel to 1) hoegbomite or corundum + magnetite, 2) margarite and 3) chlorite. Replacement of spinel by hoegbomite can be described by the substitution 1.94(Mg²⁺, Fe²⁺, Zn²⁺, Mn²⁺, Ca²⁺)Ti⁴⁺ +0.12(OH^–) where Al³⁺ and Fe³⁺ are held constant. The average composition of the Bergell hoegbomites is given by the formula Fe _0.97 ²⁺ Mg_0.69Zn_0.04Ti_0.17Al_3.94Fe _0.06 ³⁺ O_7.98(OH)_0.02 and seems to be imposed by the composition of pre-existing spinel. During the first two steps of spinel alteration, calcite was replaced by anorthite+phlogopite, and the rare earth element(REE)-bearing minerals zirconolite, allanite and sphene were formed. Allanites have characteristic chondrite-normalized REE patterns with enrichment in the light REE. The zirconolite patterns show a marked increase in concentration from La to Ce, followed by an almost constant section. Sphene lacks detectable La, and its REE patterns vary from grain to grain. Contemporaneous formation of phlogopite, REE-bearing minerals and hoegbomite during replacement of the spinel-calcite-marble indicates that the metamorphic fluid introduced potassium along with REE and other high valence cations (Ti⁴⁺, Zr⁴⁺, U⁴⁺, Th^4A3804265, Nb^5A3804265, Y^3A3804265) possibly as polynuclear complexes. The abundance of fluorine-bearing phlogopite and fluor-apatite as well as their close association with REE-bearing minerals and hoegbomite suggests F^– and PO ₄ ^3– as likely ligands for complexing of the above mentioned elements.     

The two-step shape and timing of the last deglaciation in Antarctica

The two-step character of the last deglaciation is well recognized in Western Europe, in Greenland and in the North Atlantic. For example, in Greenland, a gradual temperature decrease started at the Bölling (B) around 14.5 ky BP, spanned through the Alleröd (A) and was followed by the cold Younger Dryas (YD) event which terminated abruptly around 11.5 ky BP. Recent results suggest that this BA/YD sequence may have extended throughout all the Northern Hemisphere but the evidence of a late transition cooling is still poor for the Southern Hemisphere. Here we present a detailed isotopic record analyzed in a new ice core drilled at Dome B in East Antarctica that fully demonstrates the existence of an Antarctic cold reversal (ACR). These results suggest that the two-step shape of the last deglaciation has a worldwide character but they also point to noticeable interhemispheric differences. Thus, the coldest part of the ACR, which shows a temperature drop about three times weaker than that recorded during the YD in Greenland, may have preceded the YD. Antarctica did not experienced abrupt changes and the two warming periods started there before they started in Greenland. The links between Southern and Northern Hemisphere climates throughout this period are discussed in the light of additional information derived from the Antarctic dust record.     

A comparison of total precipitation values estimated from measurements and a 1D cloud model

The purpose of this study is to establish a relation between observed total precipitation values and estimations from a one-dimensional diagnostic cloud model. Total precipitation values estimated from maximum liquid water content, maximum vertical velocity, cloud top height, and temperature excess are also used to provide an equation for the total precipitation prediction. Data for this study were collected in Istanbul during the autumns of 1987 and 1988. The statistical models are developed with multiple regression technique and then comparatively verified with independent data for 1990. The multiple regression coefficients are in the range of 75% to 80% in the statistical models. Results of the test showed that total precipitation values estimated from the above techniques are in good agreement, with correlation coefficient between 40% and 46% based on test data for 1990.     

Turbulent heat fluxes by profile and inertial dissipation methods: analysis of the atmospheric surface layer from shipboard measurements during the SOFIA/ASTEX and SEMAPHORE experiments

Heat flux estimates obtained using the inertial dissipation method, and the profile method applied to radiosonde soundings, are assessed with emphasis on the parameterization of the roughness lengths for temperature and specific humidity. Results from the inertial dissipation method show a decrease of the temperature and humidity roughness lengths for increasing neutral wind speed, in agreement with previous studies. The sensible heat flux estimates were obtained using the temperature estimated from the speed of sound determined by a sonic anemometer. This method seems very attractive for estimating heat fluxes over the ocean. However allowance must be made in the inertial dissipation method for non-neutral stratification. The SOFIA/ASTEX and SEMAPHORE results show that, in unstable stratification, a term due to the transport terms in the turbulent kinetic energy budget, has to be included in order to determine the friction velocity with better accuracy. Using the profile method with radiosonde data, the roughness length values showed large scatter. A reliable estimate of the temperature roughness length could not be obtained. The humidity roughness length values were compatible with those found using the inertial dissipation method.     

Surface conductivity in rocks: a review

Electrical properties of rocks depend on composition (i.e. bulk properties of the constituents), micro structure (i.e. geometrical arrangement of the constituents) and interfacial effects. We consider here a rock as a three component system — grains, pores, and interfaces — in order to account for the observed behaviour. We review first the main results relative to DC. conductivity. Surface conductivity effects show up clearly in the case of shaly formations or at low salinities. Although Archies' law (1942) and Waxman and Smits model (1968) are widely used, a more physically based model is that of Johnson and Sen (1988). We review also the variable frequency conductivity (complex conductivity) data and models. The important effect in that case is the enhancement of the dielectric constant at low frequencies (Knight and Nur, 1987) which can be interpreted as a geometrical effect although electrochemical interactions may also play an important role at low frequencies, depending on the rock type.