Geochemistry and geochronology of HP mélanges from Tinos and Andros,cycladic blueschist belt,Greece

U–Pb zircon geochronology, Sr–Nd isotope and bulk-rock geochemistry have been applied to meta-igneous and meta-sedimentary rocks from high-pressure metamorphic mélanges exposed on the Cycladic islands of Tinos, Syros and Andros. Ion microprobe (SHRIMP) U–Pb zircon dating of 7 samples representing meta-igneous blocks (Tinos), a blackwall zone (Tinos) and chlorite–talc schists from block-matrix contacts (Syros and Tinos) yielded Cretaceous ages of c. 80 Ma. Many of the criteria commonly used to distinguish between magmatic or metamorphic zircon genesis (internal structure, Th/U ratio, REE characteristics, Ti-in zircon thermometry, enclosed mineral phases) do not provide unambiguous constraints for the mode of formation. However, a magmatic origin for Cretaceous zircon of meta-gabbros and eclogites is considered likely. Supporting evidence for a previously suggested metamorphic origin for c. 80 Ma zircon in eclogite has not been found. Zircon of the same age occurring in chlorite–talc schists is presumably related to non-magmatic processes. Well-defined Cretaceous age groups clustering at c. 79 Ma also occur in the detrital zircon populations of 2 quartz mica schists representing the mélange matrix on Tinos, and suggest a much later time for sediment accumulation than previously assumed. The importance of c. 57 Ma zircon ages remains unclear, but may record either HP metamorphic processes or a post-57 Ma depositional age. The youngest age group in a third quartz mica schist from Tinos, collected outside the main mélange occurrences, clusters at c. 226–238 Ma. In all clastic metasediments from Tinos, most data points plot along the concordia between c. 300 and 900 Ma; single data points indicate concordant ages of c. 2.5 Ga, 2.3 Ga and 1 Ga, respectively. The youngest ²⁰⁶Pb/²³⁸U age group that has been recognized in a felsic paragneiss from Andros indicates an age of 163.1 ± 3.9 Ma, and mostly represents overgrowths around zircon with ages in the range from ～ 272 to ～ 289 Ma. Single data points of other inherited cores provided ²⁰⁶Pb/²³⁸U ages of c. 630 and c. 930 Ma. Meta-gabbros from Tinos show a large compositional variability and were found at 4 locations, each with distinct compositional characteristics, suggesting different crystallization histories, different sources and/or significant post-magmatic disturbance. The geochemistry of mélange blocks and the identical U–Pb zircon ages suggest that the block-matrix associations on Tinos and Syros can be grouped together. On a broader regional scale, there seem to be similarities between some meta-igneous rocks from Tinos and Evvia. Field relationships indicate that the mélanges occurring in southern Andros and northern Tinos can be correlated, but supporting geochemical and/or geochronological evidence for this interpretation could not be established. Previously published Jurassic ages for mafic and felsic mélange blocks from Andros suggest a genetic relationship to the ophiolite occurrences exposed in the larger Balkan region. A similar regional correlation is also considered likely for the Cretaceous meta-gabbros from Tinos and Syros, but cannot be documented with certainty.     

Postglacial to Holocene landscape evolution and process rates in steep alpine catchments

Climate change and high magnitude mass wasting events pose adverse societal effects and hazards, especially in alpine regions. Quantification of such geomorphic processes and their rates is therefore critical but is often hampered by the lack of appropriate techniques and the various spatiotemporal scales involved in these studies. Here we exploit both in situ cosmogenic beryllium-10 (¹⁰Be) and carbon-14 (¹⁴C) nuclide concentrations for deducing exposure ages and tracing of sediment through small alpine debris flow catchments in central Switzerland. The sediment cascade and modern processes we track from the source areas, through debris flow torrents to their final export out into sink regions with cosmogenic nuclides over an unprecedented five-year time series with seasonal resolution. Data from a seismic survey and a 90 m core revealed a glacially overdeepened basin, filled with glacial and paraglacial sediments. Surface exposure dating of fan boulders and radiocarbon ages constrain the valley fill from the last deglaciation until the Holocene and show that most of the fan existed in early Holocene times already. Current fan processes are controlled by episodic debris flow activity, snow (firn) and rock avalanches. Field investigations, digital elevation models (DEMs) of difference and geomorphic analysis agree with sediment fingerprinting with cosmogenic nuclides, highlighting that the bulk of material exported today at the outlet of the subcatchments derives from the lower fans. Cosmogenic nuclide concentrations steadily decrease from headwater sources to distal fan channels due to the incorporation of material with lower nuclide concentrations. Further downstream the admixture of sediment from catchments with less frequent debris flow activity can dilute the cosmogenic nuclide signals from debris flow dominated catchments but may also reach thresholds where buffering is limited. Consequently, careful assessment of boundary conditions and driving forces is required when apparent denudation rates derived from cosmogenic nuclide analysis are upscaled to larger regions. © 2018 John Wiley & Sons, Ltd.     

Where could catch shares prevent stock collapse?

In a widely received study Costello and his colleagues found that catch shares give better stock persistence and higher catch for fishermen. The conclusions made by Costello et al. were further supported by Grafton and McIlgorm where they suggested a framework in order to determine the costs and benefits of separate ITQ management in seven Australian commonwealth fisheries, and what the alternatives should be if the net benefits do not justify ITQs. This raises the question why we do not see catch shares being used more often. We explore at a global scale which countries would have the potential to, and indeed do, fulfil the conditions necessary to implement such a management strategy.     

Calcium isotope fractionation in calcite and aragonite

Calcium isotope fractionation was measured on skeletal aragonite and calcite from different marine biota and on inorganic calcite. Precipitation temperatures ranged from 0 to 28°C. Calcium isotope fractionation shows a temperature dependence in accordance with previous observations: 1000 · ln(α_cc) = −1.4 + 0.021 · T (°C) for calcite and 1000 · ln(α_ar) = −1.9 + 0.017 · T (°C) for aragonite. Within uncertainty the temperature slopes are identical for the two polymorphs. However, at all temperatures calcium isotopes are more fractionated in aragonite than in calcite. The offset in δ^44/40Ca is about 0.6‰. The underlying mechanism for this offset may be related to the different coordination numbers and bond strengths of the calcium ions in calcite and aragonite crystals, or to different Ca reaction behavior at the solid-liquid interface. Recently, the observed temperature dependence of the Ca isotope fractionation was explained quantitatively by the temperature control on precipitation rates of calcium carbonates in an experimental setting (Lemarchand et al., 2004). We show that this mechanism can in principle also be applied to CaCO₃ precipitation in natural environments in normal marine settings. Following this model, Ca isotope fractionation in marine Ca carbonates is primarily controlled by precipitation rates. On the other hand the larger Ca isotope fractionation of aragonite compared to calcite can not be explained by different precipitation rates. The rate control model of Ca isotope fractionation predicts a strong dependence of the Ca isotopic composition of carbonates on ambient CO₃²⁻ concentration. While this model is in general accordance with our observations in marine carbonates, cultured specimens of the planktic foraminifer Orbulina universa show no dependence of Ca-isotope fractionation on the ambient CO₃²⁻ concentration. The latter observation implies that the carbonate chemistry in the calcifying vesicles of the foraminifer is independent from the ambient carbonate ion concentration of the surrounding water.     

Beitrag zur Kenntnis der Cordillera Claudio Gay (Nordchile)

Zusammenfassung Die wenig bekannte Cordillera Claudio Gay ist ein Teil der Vorkordillere in Nordchile. Ihr Unterbau besteht aus Tiefengesteinskörpern des PalÄozoikums und einer Sedimentserie, die von sauren Ergu\gesteinen durchbrochen wird. Die petrologische Zusammensetzung der Sedimente und ihre metamorphe überprÄgung werden speziell behandelt. Da keine Fossilien vorliegen, kann das Alter der Sedimente nur auf eine Zeitspanne zwischen Devon und Perm eingeengt werden.

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The little-known Cordillera Claudio Gay is part of the Pre-Cordillera in Northern Chile. Its basement consists of plutonic rocks of the Paleozoics and of a sediment series which is penetrated by acid effusive rocks. The petrological composition of low grade metamorphosed sediments is separately dealt with. No fossils being available, the age of the sediments can only be defined as belonging to the period between Devonian and Permian time.

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Resumen La poco conocida Cordillera Claudio Gay es una parte de la Precordillera en Chile septentrional. Su base se compone de masas intrusivas paleozóicas y de una serie sedimentaria cortada por rocas efusivas ácidas. La composición petrológica de los sedimentos y su cambio metamórfico son investigados en forma especial. La edad de los sedimentos solo puede ser calculada por la falta de fósiles entre el Devónico y el Pérmico.

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Landslides and increased debris-flow activity: A systematic comparison of six catchments in Switzerland

An increase in debris-flow frequency is expected in steep Alpine catchments after the occurrence of a large landslide, such as a rock avalanche. Herein we describe changes in debris-flow activity following increases in sediment availability due to landslides, or accelerated rock-glacier movement, for five catchments in the Swiss Alps, the Spreitgraben, Schipfenbach, Bondasca, Riascio, and Dorfbach catchments. Documentation on debris-flow activity is available from both before and after the landslide that generated the new sediment deposits. Data from nearby meteorological stations were used to explore possible changes in rainfall activity, and how the intensity and duration of rainfall events may have changed. In all cases there was a considerable increase in debris-flows frequency for one to eight years following the landslide. The annual number of days with debris-flow activity following the landslide was similar to that observed for the Illgraben catchment, where many such landslides occur annually. No clear change in precipitation totals preceding debris flows was apparent for the Riascio catchment, suggesting that the increase in frequency of debris flows is related to the increase in the amount of sediment that can be readily mobilized. In the two cases where rainfall data were available on an hourly basis, no systematic changes in the intensity or duration of rainfall related to debris-flow triggering were apparent, as shown by the close-clustering of storms on the intensity-duration plots. Following the sediment-generating event, an initial and sudden increase of the sediment yield was observed, followed by a decrease over time towards pre-disturbance values. The response of the catchments appears to be related to the amount of debris-flow activity prior to the landslide: sediment yield from catchments with frequent debris flows prior to the landslide activity did not increase as dramatically as in catchments where debris-flow activity was less common prior to the landslide. © 2018 John Wiley & Sons, Ltd.     

Probabilistic collocation and lagrangian sampling for advective tracer transport in randomly heterogeneous porous media

The Karhunen-Loeve (KL) decomposition and the polynomial chaos (PC) expansion are elegant and efficient tools for uncertainty propagation in porous media. Over recent years, KL/PC-based frameworks have successfully been applied in several contributions for the flow problem in the subsurface context. It was also shown, however, that the accurate solution of the transport problem with KL/PC techniques is more challenging. We propose a framework that utilizes KL/PC in combination with sparse Smolyak quadrature for the flow problem only. In a subsequent step, a Lagrangian sampling technique is used for transport. The flow field samples are calculated based on a PC expansion derived from the solutions at relatively few quadrature points. To increase the computational efficiency of the PC-based flow field sampling, a new reduction method is applied. For advection dominated transport scenarios, where a Lagrangian approach is applicable, the proposed PC/Monte Carlo method (PCMCM) is very efficient and avoids accuracy problems that arise when applying KL/PC techniques to both flow and transport. The applicability of PCMCM is demonstrated for transport simulations in multivariate Gaussian log-conductivity fields that are unconditional and conditional on conductivity measurements.