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21.
22.
Florian Einsiedl Norbert Hertkorn Moritz Frommberger Boris P. Koch 《Geochimica et cosmochimica acta》2007,71(22):5474-5482
The study of molecular transformation processes of dissolved organic carbon (DOC) in the environment significantly contributes to a better understanding of the global biogeochemical organic matter cycle. In an oxic karst groundwater system, in which the most powerful abiotic DOC degradative reactions, photodegradation and metal-mediated redox chemistry, are at best marginal contributors, a near complete turnover of fulvic acids (FAs) has been observed within decades (∼60 years). Depletion of oxygen for a very extensive range of aliphatic and aromatic carbon chemical environments has been confirmed as well as the formation of novel classes of compounds, suggesting a major contribution from biotic processes. From these results we infer that FAs must be perceived as a rather active participant in the global carbon cycle. Molecular-level alterations of such magnitude and rapidity on such short-time scales ought to be considered as widespread in the processing of “refractory” DOC in the environment. 相似文献
23.
Peter Brack Hans Rieber Roland Mundil Wolfgang Blendinger Florian Maurer 《Swiss Journal of Geoscience》2007,100(3):327-348
The depositional architecture and the geometric relationships between platform-slope deposits and basinal sediments along
with paleontological evidence indicate the time interval of the younger Anisian Reitziites reitzi ammonoid zone to largely represent the main stage of platform aggradation at the Cernera and Bivera/Clapsavon carbonate platforms.
Published and new U-Pb age data of zircons from volcaniclastic layers bracketing the stratigraphic interval of platform growth
constrain the duration of platform evolution to a time span shorter than 1.8±0.7m.y., probably in the order of 0.5-1m.y.,
reflecting fast rates of vertical platform aggradation exceeding 500 m/m.y. In the range of growth potentials for shallow-water
carbonate systems estimated in relation to the time span of observation, this high rate is in agreement with values for short
intervals of 105-106yrs (e.g., Schlager 1999).
After drowning, the platforms at Cernera and Bivera/Clapsavon were blanketed by thin pelagic carbonates. On the former platform
flanks the draping sediments in places comprise red nodular pelagic limestones (Clapsavon Limestone) similar in facies to
the Han Bulog Limestones occurring elsewhere in Middle Triassic successions of the Mediterranean Tethys. The drowning of vast
areas of former carbonate platforms possibly triggered the onset of bottom-water circulation in adjacent basins as suggested
by the abrupt transition from laminated to bioturbated pelagic nodular limestones in the Buchenstein Formation which occurred
close to the time of initial platform submergence. During the Late Ladinian the topographic features of the drowned platforms
were onlapped by rapidly deposited, predominantly clastic successions including coarse breccias and volcanic rocks sealing
and preserving the peculiar stratigraphic setting. 相似文献
24.
25.
Jeffrey Neal Guy Schumann Paul Bates Wouter Buytaert Patrick Matgen Florian Pappenberger 《水文研究》2009,23(25):3641-3649
River discharge is currently monitored by a diminishing network of gauges, which provide a spatially incomplete picture of global discharges. This study assimilated water level information derived from a fused satellite Synthetic Aperture Radar (SAR) image and digital terrain model (DTM) with simulations from a coupled hydrological and hydrodynamic model to estimate discharge in an un‐gauged basin scenario. Assimilating water level measurements led to a 79% reduction in ensemble discharge uncertainty over the coupled hydrological hydrodynamic model alone. Measurement bias was evident, but the method still provided a means of improving estimates of discharge for high flows. The study demonstrates the potential of currently available synthetic aperture radar imagery to reduce discharge uncertainty in un‐gauged basins when combined with model simulations in a data assimilation framework, where sufficient topographic data are available. The work is timely because in the near future the launch of satellite radar missions will lead to a significant increase in the volume of data available for space‐borne discharge estimation. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
26.
Groundwater warming below cities has become a major environmental issue; but the effect of distinct local anthropogenic sources of heat on urban groundwater temperature distributions is still poorly documented. Our study addressed the local effect of stormwater infiltration on the thermal regime of urban groundwater by examining differences in water temperature beneath stormwater infiltration basins (SIB) and reference sites fed exclusively by direct infiltration of rainwater at the land surface. Stormwater infiltration dramatically increased the thermal amplitude of groundwater at event and season scales. Temperature variation at the scale of rainfall events reached 3 °C and was controlled by the interaction between runoff amount and difference in temperature between stormwater and groundwater. The annual amplitude of groundwater temperature was on average nine times higher below SIB (range: 0·9–8·6 °C) than at reference sites (range: 0–1·2 °C) and increased with catchment area of SIB. Elevated summer temperature of infiltrating stormwater (up to 21 °C) decreased oxygen solubility and stimulated microbial respiration in the soil and vadose zone, thereby lowering dissolved oxygen (DO) concentration in groundwater. The net effect of infiltration on average groundwater temperature depended upon the seasonal distribution of rainfall: groundwater below large SIB warmed up (+0·4 °C) when rainfall occurred predominantly during warm seasons. The thermal effect of stormwater infiltration strongly attenuated with increasing depth below the groundwater table indicating advective heat transport was restricted to the uppermost layers of groundwater. Moreover, excessive groundwater temperature variation at event and season scales can be attenuated by reducing the size of catchment areas drained by SIB and by promoting source control drainage systems. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
27.
On the Effect of Surface Heat-Flux Heterogeneities on the Mixed-Layer-Top Entrainment 总被引:1,自引:1,他引:0
Matthias Sühring Björn Maronga Florian Herbort Siegfried Raasch 《Boundary-Layer Meteorology》2014,151(3):531-556
We used a set of large-eddy simulations to investigate the effect of one-dimensional stripe-like surface heat-flux heterogeneities on mixed-layer top entrainment. The profiles of sensible heat flux and the temporal evolution of the boundary-layer depth revealed decreased entrainment for small heat-flux amplitudes and increased entrainment for large heat-flux amplitudes, compared to the homogeneously-heated mixed layer. For large heat-flux amplitudes the largest entrainment was observed for patch sizes in the order of the boundary-layer depth, while for significantly smaller or larger patch sizes entrainment was similar as in the homogeneous case. In order to understand the underlying physics of this impact, a new approach was developed to infer local information on entrainment by means of the local flux divergence. We found an entrainment maximum over the centre of the stronger heated surface patch, where thermal energy is accumulated by the secondary circulation (SC) that was induced by the surface heterogeneity. Furthermore, we observed an entrainment maximum over the less heated patch as well, which we suppose is to be linked to the SC-induced horizontal flow convergence at the top of the convective boundary layer (CBL). For small heat-flux amplitudes a counteracting effect dominates that decreases entrainment, which we suppose is the horizontal advection of cold air in the lower, and warm air in the upper, CBL by the SC, stabilizing the CBL and thus weakening thermal convection. Moreover, we found that a mean wind can reduce the heterogeneity-induced impact on entrainment. If the flow is aligned perpendicular to the border between the differentially-heated patches, the SC and thus its impact on entrainment vanishes due to increased horizontal mixing, even for moderate wind speeds. However, if the flow is directed parallel to the border between the differentially-heated patches, the SC and thus its impact on entrainment persists. 相似文献
28.
Brittle fracture processes were hypothesized by several researches to cause a damage zone around an underground excavation in sulfate-rich clay rock when the stress exceeds the crack initiation threshold, and may promote swelling by crystal growth in newly formed fractures. In this study, laboratory experiments such as unconfined and confined compression tests with acoustic emission monitoring, and microstructural and mineralogical analyses are used to explain brittle fracture processes in sulfate-rich clay rock from the Gipskeuper formation in Switzerland. This rock type typically shows a heterogeneous rock fabric consisting of distinct clayey layers and stiff heterogeneities such as anhydrite layers, veins or nodules. The study showed that at low deviatoric stress, the failure behavior is dominated by the strength of the clayey matrix where microcracks are initiated. With increasing deviatoric stress or strain, growing microcracks eventually are arrested at anhydrite veins, and cracks develop either aligned with the interface between clayey layers and anhydrite veins, or penetrate anhydrite veins. These cracks often link micro-fractured regions in the specimen. This study also suggest that fracture localization in sulfate-rich clay rocks, which typically show a heterogeneous rock fabric, does not take place in the pre-peak range and renders unstable crack propagation less likely. Sulfate-rich clay rocks typically contain anhydrite veins at various scales. At the scale of a tunnel, anhydrite layers or veins may arrest growing fractures and prevent the disintegration of the rock mass. The rock mass may be damaged when the threshold stress for microcrack initiation is exceeded, thus promoting swelling by crystal growth in extension fractures, but the self-supporting capacity of the rock mass may be maintained rendering the possibility for rapidly propagating instability less likely. 相似文献
29.
Hilary McMillan Jim Freer Florian Pappenberger Tobias Krueger Martyn Clark 《水文研究》2010,24(10):1270-1284
In order to quantify total error affecting hydrological models and predictions, we must explicitly recognize errors in input data, model structure, model parameters and validation data. This paper tackles the last of these: errors in discharge measurements used to calibrate a rainfall‐runoff model, caused by stage–discharge rating‐curve uncertainty. This uncertainty may be due to several combined sources, including errors in stage and velocity measurements during individual gaugings, assumptions regarding a particular form of stage–discharge relationship, extrapolation of the stage–discharge relationship beyond the maximum gauging, and cross‐section change due to vegetation growth and/or bed movement. A methodology is presented to systematically assess and quantify the uncertainty in discharge measurements due to all of these sources. For a given stage measurement, a complete PDF of true discharge is estimated. Consequently, new model calibration techniques can be introduced to explicitly account for the discharge error distribution. The method is demonstrated for a gravel‐bed river in New Zealand, where all the above uncertainty sources can be identified, including significant uncertainty in cross‐section form due to scour and re‐deposition of sediment. Results show that rigorous consideration of uncertainty in flow data results in significant improvement of the model's ability to predict the observed flow. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
30.
ZHANG Letian YE Gaofeng JIN Sheng WEI Wenbo Martyn UNSWORTH Alan G. JONES JING Jianen DONG Hao XIE Chengliang Florian LE PAPE Jan VOZAR 《《地质学报》英文版》2015,89(1):90-104
Project INDEPTH (InterNational DEep Profiling of Tibet and the Himalaya) is an interdisciplinary program designed to develop a better understanding of deep structures and mechanics of the Tibetan Plateau. As a component of magnetotelluric (MT) work in the 4th phase of the project, MT data were collected along a profile that crosses the eastern segment of the Altyn Tagh fault on the northern margin of the plateau. Time series data processing used robust algorithms to give high quality responses. Dimensionality analysis showed that 2D approach is only valid for the northern section of the profile. Consequently, 2D inversions were only conducted for the northern section, and 3D inversions were conducted on MT data from the whole profile. From the 2D inversion model, the eastern segment of the Altyn Tagh fault only appears as a crustal structure, which suggests accommodation of strike slip motion along the Altyn Tagh fault by thrusting within the Qilian block. A large-scale off-profile conductor within the mid-lower crust of the Qilian block was revealed from the 3D inversion model, which is probably correlated with the North Qaidam thrust belt. Furthermore, the unconnected conductors from the 3D inversion model indicate that deformations in the study area are generally localized. 相似文献